Chapter 4 Flashcards

(39 cards)

1
Q

What is the name of the theory that says acids release H= ions and bases release OH- ions, and the cation from the base and anion from the acid make a salt?

A

Arrhenius theory

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2
Q

What does the Bronsted-Lowry theory say about acids?

A

An acid donates an H+ ion

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3
Q

What does the Bronsted-Lowry theory say about bases?

A

A base accepts an H+ ion.

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4
Q

In a Bronsted-Lowry equilibrium, acids and bases can be found on which sides of the formula?

A

Both

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5
Q

What do you call the H3O+ ion?

A

Hydronium

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6
Q

What is a conjugate acid/base pair?

A

Two substances on opposite sides of the formula that differ by an H+ ion.

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7
Q

What do you call a chemical species that can act as both an acid and a base?

A

Amphiprotic

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8
Q

Are uncharged substances usually amphiprotic?

A

No.

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9
Q

What charge are amphiprotic species usually?

A

negative

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10
Q

Does the strength of an acid or base depend on concentration?

A

No.

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11
Q

What is the strength of an acid/base?

A

The ability to produce ions in solution (dissociate)

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12
Q

What do you call an acid that completely ionizes in solution?

A

Strong acid.

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13
Q

What do you call an acid that only partially ionizes in solution?

A

Weak acid.

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14
Q

Is an equilibrium an indicator of a strong or weak acid/base?

A

WEAK

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15
Q

What do you call a base that completely dissociates in solution?

A

Strong base

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16
Q

What do you call a base that partially dissociates in solution?

17
Q

What does the acid/base ionization constant not include?

18
Q

What is the acid ionization constant equation? (Ka)

A

Ka = [product] [H3O] / [reactant]

19
Q

What is the base ionization constant equation? (Kb)

A

Kb = [product] [OH-] / [reactant]

20
Q

If Keq > 1 then the reaction favours the

21
Q

If Keq < 1 then the reaction favours the

22
Q

What levels the strength of strong acid/bases?

23
Q

What do you call it when two water molecules automatically exchange an H+ ion between them?

A

The autoionization of water

24
Q

What is the ionization constant for water? (Kw)

A

Kw = [H3O+] [OH-] = 1.00x10^-14 = 25 degrees

25
What happens when you add strong acids and bases to each other?
They neutralize each other
26
What do you get when you multiply Kb and Ka?
Kw
27
How to find the Kb value?
divide Kw (10^-14) by the Ka of the conjugate acid
28
What is the equation to determine pH?
pH= -log [H3O+]
29
What is the pH of acidic solutions?
less than 7
30
What is the pH of basic solutions?
more than 7
31
Every unit decrease in pH represents a decrease in how much [H3O+]?
a factor of 10
32
What is the equation to calculate [H3O+] from pH?
[H3O+] = 10^-pH
33
what does the lowercase "p" represent?
-log10 (10 is subscript)
34
What do you get when you add pH and pOH?
pH + pOH = pKw
35
For metal oxides we do not include what in our ionization equation?
Equilibrium arrows
36
What are the steps for calculating whether a solution is acidic or basic when a strong acid is mixed with a strong base?
1: net reaction equation (neutralization) 2: calculate # of mol present before and after reaction 3: From excess reactant, calculate pH
37
How do you determine the pH of weak acids?
Use the Ka expression, as well as an ice table.
38
How do you determine the pH of weak bases?
Use an ice table and Kb expression
39
How do you calculate the [weak base] necessary to produce a certain pH?
1: equilibrium equation + ice table 2: calculate [OH-] 3: compute Kb 4: solve