Glossary Flashcards

1
Q

acid

A

a species that releases H+ ions in aqueous solution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

acid dissociation constant Ka

A

the equilibrium constant that shows the extent of

dissociation of a weak acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

acid–base pair

A

a pair of two species that transform into each other by gain or loss of a proton

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

activation energy

A

the minimum energy required to start a reaction by the breaking of bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

actual yield

A

the amount of product obtained from a reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

addition polymerisation

A

formation of a very long molecular chain, by repeated addition reactions of many unsaturated alkene molecules (monomers)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

addition reaction

A

a reaction in which a reactant is added to an unsaturated molecule to make a one saturated molecule

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

adsorption

A

the process that occurs when a gas or liquid or solute is held to the surface of a solid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

alicyclic

A

containing carbon atoms joined together in a ring that is not aromatic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

aliphatic

A

containing carbon atoms joined together in straight or branched chains

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

alkali

A

a type of base that dissolves in water forming hydroxide ions, OH–(aq) ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

alkanes

A

the hydrocarbon homologous series with single carbon-to-carbon bonds and the general formula: CnH2n+2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

alkenes

A

the hydrocarbon homologous series with at one double carbon-to-carbon bonds and the general formula: CnH2n

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

alkyl group

A

a side chain formed by removing a hydrogen atom removed from an alkane parent chain, for example, CH3, C2H5; any alkyl group is often shown as R

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

alkynes

A

the hydrocarbon homologous series with one triple carbon-to-carbon bonds and the general formula: CnH2n–2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

amount of substance

A

the quantity whose unit of the mole, used as a means of counting any species such as atoms, ions and molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

anhydrous

A

containing no water molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

anion

A

a negatively charged ion with more electrons than protons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

aromatic

A

containing one or more benzene rings

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

atom economy

A

(sum of molar masses of desired products)/(sum of molar masses of all products) Å~100%

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

atomic (proton) number

A

the number of protons in the nucleus of an atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

atomic orbital

A

a region around the nucleus that can hold up to two electrons, with opposite spins

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

average bond enthalpy

A

the average enthalpy change that takes place when breaking by homolytic fission 1 mol of a given type of bond in the molecules of a gaseous species

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

Avogadro constant NA

A

the number of atoms per mole of the carbon-12 isotope. (6.02 × 1023 mol–1)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
25
Q

base

A

a compound that neutralises an acid to form a salt

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
26
Q

binary compound

A

a compound containing two elements only

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
27
Q

bond angle

A

the angle between two bonds at an atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
28
Q

bond dissociation enthalpy

A

the enthalpy change that takes place when breaking by homolytic fission 1 mol of a given bond in the molecules of a gaseous species.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
29
Q

bonded pait

A

a pair of electrons shared between two atoms to make a covalent bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
30
Q

Brønsted–Lowry acid

A

a species that is a proton, H+, donor

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
31
Q

Brønsted–Lowry base

A

a species that is a proton, H+, acceptor

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
32
Q

buffer solution

A

a system that minimises pH changes on addition of small amounts of an acid or a base

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
33
Q

carbocation

A

an ion that contains a positively charged carbon atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
34
Q

catalyst

A

a substance that increases the rate of a chemical reaction without being used up in the process; a catalyst provide an alternative route for the reaction with lower activation energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
35
Q

cation

A

a positively charged ion with fewer electrons than protons

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
36
Q

chain reaction

A

a reaction in which the propagation steps release new radicals that continue the reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
37
Q

chemical shift δ

A

a scale, in ppm, that compares the frequency of an NMR absorption with the frequency of the reference TMS at δ = 0 ppm

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
38
Q

chiral carbon

A

a carbon atom attached to four different atoms or groups of atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
39
Q

chromatogram

A

a visible record showing the result of separation of the components of a mixture by chromatography

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
40
Q

cis–trans isomerism

A

a special type of E/Z isomerism in which there are two non-hydrogen groups and two hydrogen atoms around the C=C double bond: the cis isomer (Z isomer) has H atoms on each carbon on the same side; the trans isomer (E isomer) has H atoms on each carbon on different sides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
41
Q

closed system

A

a system isolated from its surroundings

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
42
Q

collision theory

A

two reacting particles must collide for a reaction to occur, and must be in the correct orientation and have sufficient energy to overcome the activation energy of the reaction

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
43
Q

complex ion

A

a transition metal ion bonded to ligands by coordinate bonds (dative covalent bonds)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
44
Q

concentration

A

the amount of solute, in moles, dissolved in 1 dm3 (1000 cm3) of solution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
45
Q

condensation reaction

A

a reaction in which two small molecules react together to form a larger molecule with elimination of a small molecule such as water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
46
Q

conjugate acid

A

a species that releases a proton to form a conjugate base

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
47
Q

conjugate base

A

a species that accepts a proton to form a conjugate acid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
48
Q

coordinate bond

A

a shared pair of electrons in which the bonded pair has been provided by one of the bonding atoms only; also called a dative covalent bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
49
Q

coordination number

A

the total number of coordinate bonds formed between a central metal ion and ligands

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
50
Q

covalent bond

A

the strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
51
Q

dative covalent

A

a shared pair of electrons in which the bonded pair has been provided by one of the bonding atoms only; also called a coordinate bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
52
Q

dehydration

A

an elimination reaction in which water is removed from a saturated molecule to make an unsaturated molecule

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
53
Q

delocalised electrons

A

electrons that are shared between more than two atoms

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
54
Q

desorption

A

release of an adsorbed substance from a surface

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
55
Q

dipole

A

a separation in electrical charge so that one atom of a polar covalent bond, or one end of a polar molecule, has a small positive charge δ+ and the other has a small negative charge δ–.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
56
Q

displacement reaction

A

a reaction in which a more reactive element displaces a less reactive element from an aqueous solution of its ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
57
Q

displayed formula

A

a formula showing the relative positioning of all the atoms in a molecule and the bonds between them

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
58
Q

disproportionation

A

a redox reaction in which the same element is both oxidised and reduced

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
59
Q

dynamic equilibrium

A

the equilibrium that exists in a closed system when the rate of the forward reaction is equal to the rate of the reverse reaction and concentrations do not change

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
60
Q

E/Z isomerism

A

a type of stereoisomerism in which different groups attached to each carbon of a C=C double bond may be arranged differently in space because of the restricted rotation of the C=C bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
61
Q

electron configuration

A

a shorthand representation that shows how electrons occupy sub-shells in an atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
62
Q

electronegativity

A

a measure of the attraction of a bonded atom for the pair of electrons in a covalent bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
63
Q

electrophile

A

an atom (or group of atoms) which is attracted to an electron-rich centre or atom, where it accepts a pair of electrons to form a new covalent bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
64
Q

electrophilic addition

A

an addition reaction in which the first step is attack by an electrophile on a region of high electron density

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
65
Q

electrophilic substitution

A

a type of substitution reaction in which an electrophile is attracted to an electron-rich centre or atom, where it accepts a pair of electrons to form a new covalent bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
66
Q

elimination reaction

A

the removal of a molecule from a saturated molecule to make an unsaturated molecule

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
67
Q

empirical formula

A

the formula that shows the simplest whole-number ratio of atoms of each element present in a compound

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
68
Q

enantiomers

A

stereoisomers that are nonsuperimposable mirror images of each other; also called optical isomers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
69
Q

end point

A

the point in a titration where the indicator changes colour; the end point indicates when the reaction is just complete

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
70
Q

endothermic reaction

A

a reaction in which the enthalpy of the products is greater than the enthalpy of the reactants, resulting in heat being taken in from the surroundings (ΔH is positive)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
71
Q

enthalpy H

A

the heat content that is stored in a chemical system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
72
Q

enthalpy change ΔH

A

the difference between the enthalpy of the products and the enthalpy of the reactants.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
73
Q

enthalpy cycle

A

a diagram showing alternative routes between reactants and products which allows the indirect determination of an enthalpy change from other known enthalpy changes using Hess’s law

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
74
Q

enthalpy profile diagram

A

a diagram for a reaction to compares the enthalpy of the reactants with the enthalpy of the products

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
75
Q

entropy

A

the used for the dispersal of energy and disorder within the chemicals making up the chemical system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
76
Q

equilibrium constant Kc

A

a measure of the position of equilibrium; the magnitude of an equilibrium constant indicates whether there are more reactants or more products in an equilibrium system

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
77
Q

equivalence point

A

the point in a titration at which the volume of one solution has reacted exactly with the volume of the second solution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
78
Q

esterification

A

a reaction in which a carboxylic acid reacts with an alcohol to form an ester and water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
79
Q

exothermic reaction

A

a reaction in which the enthalpy of the products is smaller than the enthalpy of the reactants, resulting in heat loss to the surroundings (ΔH is negative)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
80
Q

fingerprint region

A

an area of an infrared spectrum below 1500 cm–1 that gives a characteristic pattern for different compounds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
81
Q

first electron affinity

A

the enthalpy change that takes place when one electron is added to each atom in one mole of gaseous atoms to form one mole of gaseous 1– ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
82
Q

first ionisation energy

A

the energy required to remove one electron from each atom in one mole of gaseous atoms of an element to form one mole of gaseous 1+ ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
83
Q

fractional distillation

A

the separation of components in a liquid mixture by their different boiling points into fractions with different compositions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
84
Q

fragment ions

A

ions formed from the breakdown of the molecular ion in a mass spectrometer

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
85
Q

fragmentation

A

the process in mass spectrometry that causes a positive ion to spilt into smaller pieces, one of which is a positive fragment ion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
86
Q

free energy change ΔG

A

the balance between enthalpy, entropy and temperature for a process given by ΔG = ΔH − TΔS. A process is feasible when ΔG < 0

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
87
Q

functional group

A

the part of the organic molecule responsible for its chemical reactions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
88
Q

general formula

A

the simplest algebraic formula of a member of a homologous series

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
89
Q

giant covalent lattice

A

a three-dimensional structure of atoms, bonded together by strong covalent bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
90
Q

giant ionic lattice

A

a three-dimensional structure of oppositely charged ions, bonded together by strong ionic bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
91
Q

giant metallic lattice

A

a three-dimensional structure of positive ions and delocalised electrons, bonded together by strong metallic bonds

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
92
Q

group

A

a vertical column in the periodic table. Elements in a group have similar chemical properties and their atoms have the same number of outer shell electrons

93
Q

half-life

A

the time taken for the concentration of a reactant to decrease by half

94
Q

Hess’ law

A

if a reaction can take place by more than one route and the initial and final conditions are the same, the total enthalpy change is the same for each route

95
Q

heterogeneous catalysis

A

a reaction in which the catalyst has a different physical state from the reactants; frequently reactants are gases whilst the catalyst is a solid.

96
Q

heterogeneous equilibrium

A

an equilibrium in which the species making up the reactants and products have different physical states

97
Q

heterolytic fission

A

the breaking of a covalent bond with both of the bonded electrons going to each atom, forming a cation (positive ion) and an anion (negative ion)

98
Q

homogeneous catalysis

A

a reaction in which the catalyst and reactants are in the same physical state, which is most frequently the aqueous or gaseous state

99
Q

homogeneous equilibrium

A

an equilibrium in which all the species making up the reactants and products have the same physical state

100
Q

homologous series

A

a series of organic compounds with the same functional group but with each successive member differing by CH2

101
Q

homolytic fission

A

the breaking of a covalent bond with one of the bonded electrons going to each atom, forming two radicals

102
Q

hydrated

A

a crystalline compound containing water molecules

103
Q

hydrocarbon

A

a compound of hydrogen and carbon only

104
Q

hydrogen bond

A

a strong dipole-dipole attraction between an electron-deficient hydrogen atom of −NH, −OH or HF on one molecule and a lone pair of electrons on a highly electronegative atom containing N, O or F on a different molecule

105
Q

hydrolysis

A

a reaction with water that breaks a chemical compound into two compounds, the H and OH in a water molecule becomes incorporated into the two compounds

106
Q

induced dipole–dipole interaction

A

attractive forces between induced dipoles in different molecules – also called London Forces

107
Q

infrared spectroscopy

A

an instrumentation method of analysis that identifies bonds from absorption of the infrared radiation of different wavelengths

108
Q

initial rate of reaction

A

the change in concentration of a reactant or product per unit time at the start of the reaction: t = 0.

109
Q

initiation

A

the first stage in a radical reaction in which radicals starts when a covalent bond is broken by homolytic fission of a covalent bond

110
Q

intermediate

A

a species formed during a reaction that reacts further and is not present in the final products

111
Q

intermolecular force

A

an attractive force between molecules. Intermolecular forces can be London forces, permanent dipole-dipole interactions or hydrogen bonding

112
Q

ion

A

a positively or negatively charged atom or a (covalently bonded) group of atoms (a polyatomic ion), where the number of electrons is different from the number of protons

113
Q

ionic bonding

A

the electrostatic attraction between positive and negative ions

114
Q

ionic product of water Kw

A

the product of the ions formed in the partial dissociation of water, given by Kw = [H+(aq)] [OH−(aq)]

115
Q

isotopes

A

atoms of the same element with different numbers of neutrons and different masses

116
Q

lattice enthalpy

A

the enthalpy change that accompanies the formation of one mole of an ionic compound from its gaseous ions under standard conditions

117
Q

Le Chatelier’s principle

A

when a system in dynamic equilibrium is subjected to a external change, the system readjusts itself to minimise the effect of the change and to restore equilibrium

118
Q

ligand

A

a molecule or ion that can donate a pair of electrons to the transition metal ion

119
Q

ligand substitution

A

a reaction in which one or more ligands in a complex ion are replaced by different ligands

120
Q

limiting reagent

A

the reactant that is not in excess, which will be used up first and stop the reaction.

121
Q

lone pair

A

an outer shell pair of electrons that is not involved in chemical bonding

122
Q

mass number

A

the sum of the number of protons and neutrons in the nucleus – also known as nucleon number

123
Q

metallic bond

A

the electrostatic attraction between positive metal ions and delocalised electrons

124
Q

mobile phase

A

the phase that moves in chromatography

125
Q

molar gas volume Vm

A

the volume per mole of gas molecules at a stated temperature and pressure

126
Q

molar mass M

A

the mass per mole of a substance, in units of g mol−1

127
Q

mole

A

the amount of any substance containing as many elementary particles as there are carbon atoms in exactly 12 g of the carbon-12 isotope, that is, 6.02 × 10 to the power of 23 particles

128
Q

molecular formula

A

a formula that shows the number and type of atoms of each element present in a molecule

129
Q

molecular ion

A

the positive ion formed in mass spectrometry when a molecule loses an electron

130
Q

molecule

A

the smallest part of a covalent compound that can exist while retaining its chemical identity, consisting of two or more atoms covalently bonded together

131
Q

monomer

A

a small molecule that combines with many other monomers to form a polymer

132
Q

neutralisation

A

a chemical reaction in which an acid and a base react together to produce a salt

133
Q

nomenclature

A

a system of naming compounds

134
Q

non-polar

A

with no charge separation across a bond or in a molecule

135
Q

nucleophile

A

an atom (or group of atoms) which is attracted to an electron- deficient centre or atom, where it donates a pair of electrons to form a new covalent bond

136
Q

nucleophilic substitution

A

a reaction in which a nucleophile is attracted to an electron-deficient carbon atom, and replaces an atom or group of atoms on the carbon atom

137
Q

optical isomers

A

stereoisomers that are nonsuperimposable mirror images of each other; also called ‘enantiomers’

138
Q

order

A

the power to which the concentration of a reactant is raised in the rate equation

139
Q

overall order

A

the sum of the individual orders of reactants in the rate equation: m + n

140
Q

oxidation

A

loss of electrons or an increase in oxidation number

141
Q

oxidation number

A

a measure of the number of electrons that an atom uses to bond with atoms of another element. Oxidation numbers are derived form a set of rules

142
Q

oxidation state

A

the oxidation number

143
Q

oxidising agent

A

a reagent that oxidises (takes electrons from) another species

144
Q

π-bond

A

a bond formed by the sideways overlap of two p-orbitals, with the electron density above and the plane of the bonding atoms

145
Q

partial dissociation

A

the splitting of some of a species in solution into aqueous ions.

146
Q

Pauling electronegativity value

A

a value assigned as a measure of the relative attraction of a bonded atom for the pair of electrons in a covalent bond

147
Q

percentage yield

A

% yield =
(actual amount, in mol, of product / theoretical amount, in mol, of product)
× 100

148
Q

period

A

a horizontal row of elements in the periodic table. Elements show trend in properties across a period

149
Q

periodicity

A

a repeating trend in properties of the elements across each period of the periodic table

150
Q

permanent dipole

A

a small charge difference that does not change across a bond, with δ+ and δ− partial changes on the bonded atoms: the result of the bonded atoms having different electrongativities

151
Q

permanent dipole–dipole interaction

A

an attractive force between permanent dipoles in neighbouring polar molecules

152
Q

pH

A

the expression, pH = −log[H+(aq)].

153
Q

polar (molecule)

A

with δ+ and δ− charges at different ends of the molecule

154
Q

polar covalent bond

A

a bond with a permanent dipole, having δ+ and δ− partial changes on the bonded atoms

155
Q

polar molecule

A

a molecule with an overall dipole, having taken into account any dipoles across bonds and the shape of the molecule

156
Q

polyatomic ion

A

an ion containing more than one atom

157
Q

polymer

A

an large molecule formed from many thousands of repeat units of smaller molecules known as monomers

158
Q

position of equilibrium

A

the relative quantities of reactants and products, indicating the extent of a reversible reaction at equilibrium

159
Q

precipitation reaction

A

the formation of a solid from a solution during a chemical reaction. Precipitates are often formed when two aqueous solutions are mixed together

160
Q

primary

A

on a carbon atom at the end of a chain

161
Q

primary alcohol

A

an alcohol in which the OH group is attached to a carbon atom that is attached to two or three hydrogen atoms

162
Q

principal quantum number n

A

a number representing the relative overall energy of each orbital, which increases with distance from the nucleus. The sets of orbitals with the same n-value are referred to as electron shells or energy levels

163
Q

propagation

A

the steps that continue a free radical reaction, in which a radical reacts with a reactant molecule to form a new molecule and another radical, causing a chain reaction

164
Q

proton number

A

the number of protons in the nucleus of an atom; also known as atomic number

165
Q

radical

A

a species with an unpaired electron

166
Q

rate constant k

A

the constant that links the rate of reaction with the concentrations of the reactants raised to the powers of their orders in the rate equation

167
Q

rate equation

A

for a reaction: A + B → C with orders m for A and n for B, the rate equation is given by: rate = k[A]m[B]n

168
Q

rate of reaction

A

the change in concentration of a reactant or a product in a given time

169
Q

rate-determining step

A

the slowest step in the reaction mechanism of a multi-step reaction

170
Q

reaction mechanism

A

the sequence of bond breaking and bond-forming steps that shows the path taken by electrons during a reaction

171
Q

redox reaction

A

a reaction involving reduction and oxidation

172
Q

reducing agent

A

a reagent that reduces (adds electron to) another species

173
Q

reduction

A

gain of electrons or a decrease in oxidation number

174
Q

reflux

A

the continual boiling and condensing of a reaction mixture back to the original container to ensure that the reaction takes place without the contents of the flask boiling dry

175
Q

relative atomic mass Ar

A

the weighted mean mass of an atom of an element compared with one-twelfth of the mass of an atom of carbon-12

176
Q

relative formula mass

A

the weighted mean mass of the formula unit of a compound compared with one-twelfth of the mass of an atom of carbon-12

177
Q

relative isotopic mass

A

the mass of an atom of an isotope compared with one-twelfth of the mass of an atom of carbon-12

178
Q

relative molecular mass Mr

A

the weighted mean mass of a molecule of a compound compared with one-twelfth of the mass of an atom of carbon-12

179
Q

repeat unit

A

a specific arrangement of atoms that occurs in the structure over and over again. Repeat units are included in brackets outside of which is the symbol n.

180
Q

retention time

A

in gas chromatography. The time for a component to pass from the column inlet to the detector

181
Q

reversible reaction

A

a reaction that takes place in both forward and reverse directions

182
Q

Rf value

A

Rf =

distance moved by component / distance moved by solvent

183
Q

σ-bond

A

a bond formed by the overlap of one orbital from each bonding atom, consisting of two electrons and with the electron density centred around a line directly between the nuclei of the two atoms

184
Q

salt

A

the product of a reaction in which the H− ions from the acid are replaced by metal or ammonium ions

185
Q

saturated

A

containing single bonds only

186
Q

saturated hydrocarbon

A

a hydrocarbon with single bonds only

187
Q

second electron affinity

A

the enthalpy change that takes place when one electron is added to each ion in one mole of gaseous 1− ions to form one mole of gaseous 2− ions

188
Q

second ionisation energy

A

the energy required to remove one electron from each ion in one mole of gaseous 1+ ions of an element to form one mole of gaseous 2+ ions.

189
Q

secondary

A

on a carbon atom to which two carbon chains are attached

190
Q

secondary alcohol

A

an alcohol in which the −OH group is attached to a carbon atom that is attached to two carbon chains and one hydrogen atom

191
Q

shell

A

a group of atomic orbitals with the same principal quantum number, n. Also known as a main energy level

192
Q

shielding effect

A

the repulsion between electrons in different inner shells. Shielding reduces the net attractive force between the positive nucleus on the outer shell electrons

193
Q

simple molecular lattice

A

a three-dimensional structure of molecules, bonded together by weak intermolecular forces

194
Q

skeletal formula

A

a simplified organic formula, with hydrogen atoms removed from alkyl chains, leaving just a carbon skeleton and associated functional groups

195
Q

specific heat capacity c

A

the energy required to raise the temperature of 1 g of a substance by 1 °C

196
Q

spectator ions

A

ions that are present but take no part in a chemical reaction

197
Q

spin-spin coupling

A

in an NMR spectrum, the interaction between spin states of non-equivalent nuclei that results in the splitting of a signal

198
Q

standard conditions

A

a pressure of 100 kPa, a stated temperature, usually 298 K (25 °C) and a concentration of 1 mol dm−3 (for reactions with aqueous solutions).

199
Q

standard electrode potential Eɵ

A

the e.m.f. of a half-cell compared with a standard hydrogen half-cell, measured at 298 K with solution concentrations of 1 mol dm−3 and a gas pressure of 100 kPa

200
Q

standard enthalpy change of atomisation

A

the enthalpy change that takes place when one mole of gaseous atoms forms from the element in its standard state

201
Q

standard enthalpy change of combustion ΔcHɵ

A

the enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions, all reactants and products being in their standard states

202
Q

standard enthalpy change of formation ΔfHɵ

A

the enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard states under standard conditions.

203
Q

standard enthalpy change of hydration

A

the enthalpy change that takes place when one mole of isolated gaseous ions is dissolved in water forming one mole of aqueous ions under standard conditions

204
Q

standard enthalpy change of neutralisation ΔneutHɵ

A

the enthalpy change that accompanies the reaction of an acid by a base to form one mole of H2O(l), under standard conditions, with all reactants and products in their standard states

205
Q

standard enthalpy change of reaction ΔrHɵ

A

the enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions, all reactants and products being in their standard states

206
Q

standard enthalpy change of solution

A

the enthalpy change that takes place when one mole of a compound is completely dissolved in water under standard conditions

207
Q

standard solution

A

a solution of known concentration

208
Q

standard state

A

the physical state of a substance under standard conditions of 100 kPa and a stated temperature (usually 298 K).

209
Q

stationary phase

A

the phase that does not moves in chromatography

210
Q

stereoisomers

A

compounds with the same structural formula but with a different arrangement of the atoms in space

211
Q

stoichiometry

A

the ratio of the amount, in moles, of each substance in a chemical equation (essentially the ratio of the balancing numbers)

212
Q

strong acid

A

an acid that dissociates completely in solution

213
Q

structural formula

A

a formula showing the minimal detail for the arrangement of atoms in a molecule

214
Q

structural isomers

A

molecules with the same molecular formula but with different structural formulae

215
Q

sub-shell

A

a group of orbitals of the same type within a shell

216
Q

substitution reaction

A

a reaction in which an atom or group of atoms is replaced with a different atom or group of atoms

217
Q

surroundings

A

everything that is not the chemical system

218
Q

system

A

the chemicals involved in the reaction

219
Q

termination

A

the step at the end of a radical substitution when two radicals combine to form a molecule

220
Q

tertiary alcohol

A

an alcohol in which the −OH group is attached to a carbon atom that is attached to three carbon atoms and no hydrogen atoms

221
Q

theoretical yield

A

the yield resulting from complete conversion of reactants into products

222
Q

thermal decomposition

A

the breaking up of a chemical substance with heat into at least two chemical substances

223
Q

titre

A

the volume added from the burette when the volume of one solution has exactly reacted with the other solution

224
Q

transition element

A

a d-block element which forms an ion with an incomplete d-sub-shell

225
Q

unsaturated

A

containing a multiple carbon-carbon bond

226
Q

volatility

A

the ease at which a liquid turns into a gas. Volatility increases as boiling point decreases

227
Q

water of crystallisation

A

water molecules that are bonded into a crystalline structure of a compound

228
Q

weak acid

A

an acid that dissociates only partially in solution