Transition Elements Flashcards

1
Q

What are transition elements?

A

D-block elements that form at least 1 ion with a partially filled d-orbital

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2
Q

3 main properties of transition metals

A

1) varying oxidation states
2) form coloured compounds
3) used as catalysts

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3
Q

Ligand

A

Molecules that can donate a pair of electrons to a central metal ion to form a dative covalent bond

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4
Q

Complex ion

A

An ion formed when 1 or more molecules w/ a -ve charge/lone pair bond to a central metal ion

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5
Q

Examples of square planar complexes

A

Platinum, palladium + gold

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6
Q

[Cu(H2O)6]colour and charge

A

Pale blue

2+

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7
Q

[Cr(H2O)6]

A

Violet

3+

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8
Q

[Cr(H2O)5SO4]

A

Green

+

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9
Q

Cu2+

Colour in sol and ppt

A

Blue

Blue

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10
Q

Fe2+

Colour in sol and ppt

A

Green

Green

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11
Q

Fe3+

Colour in sol and ppt

A

Yellow sol

Orange/brown

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12
Q

Mn2+

Colour in sol and ppt

A

Pink

Brown

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13
Q

Cr3+

Colour in sol and ppt

A

Green

Grey green

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14
Q

Half eqt for MnO4-/Fe2+

A

MnO4- + 5e + 8H -> Mn2+ + 4H2O

Fe2+ -> Fe3+ + e

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15
Q

Ni2+

A

Green

Green

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16
Q

Where do square planar shapes occur in complex ions?

A

Transition metals with 8 d-electrons