Oxidations Flashcards

1
Q

Primary alcohol –> aldehyde

A

Swern (oxalyl chloride, DMSO, Et3N)
OR
DMP

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2
Q

Primary alcohol –> acid

A

Jones (CO3, H2SO4)

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3
Q

Secondary alcohol –> ketone

A

Swern (oxalyl chloride, DMSO, Et3N)
OR
DMP

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4
Q

Aldehyde –> acid

A

Pinnick (NaClO2, NaH2PO4, 2-methyl-2-butene)

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5
Q

Ketone –> ester

A

Baeyer-Villiger (mCPBA)

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6
Q

Alkene to aldehyde/ketone

A

(i) O3

(ii) Me2S

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7
Q

Alkene to anti-Markovnikov alcohol

A

(i) BH3

(ii) H2O2

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8
Q

Alkene to Markovnikov alcohol

A

(i) Hg(OAc)2

(ii) NaBH4

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9
Q

Alkene to epoxide

A

mCPBA

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10
Q

Alkene to diol

A

OsO4

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