Kinetics (I and II) Flashcards

1
Q

How does increase in concentration affect rate of reaction?

A

High conc= more particles in a particular volume

Increases the frequency of successful collisions per second

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2
Q

How does increase in surface area increase rate of the reaction?

A

Larger surface area means more reactants can attach and react to the surface

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3
Q

X and Y axis of MaxWell Boltzmann graph

A

X axis- energy

Y axis- fraction of molecules with energy, E

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4
Q

Define steric hinderance

A

Where atoms are too large and they prevent attaching molecules by getting in the way

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5
Q

Define activation energy

A

Min energy needed for particles to collide in order for them to react together

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6
Q

Define collision theory

A

In order for two reactants with each other they must have enough energy and must react with correct orientation

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7
Q

Define rate of reaction

A

Change in concentration of reactant or product divided by Change in time

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8
Q

why would some reactants be added in excess

A

so their concertation would remain constant so only the concertation of one reactant would vary

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9
Q

why would the volumes need to remain the same

A

as the concentrations is proportional to volume

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10
Q

how to determine whether a kinetic mechanism is correct?

A

state if the reagents in the rate equation are in the rate determining step
if they are, state if a reagent which is zero order is involved before or after the rate determining step

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