AAMC Practice Flashcards

1
Q

pH equation (given acid concentration)

A

ph = -log[H+]

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2
Q

solving log equations

A
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3
Q

determine molecular geometry: basic steps

A

determine the steric number

determine the geometry based on the number of bonds and lone pairs

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4
Q

steric number

A

the number of “electron dense areas” around a central atom

lone pairs or bonds (whether single, double, or triple)

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5
Q

molecular geometry: steric # 2, no lone pairs

A

linear

180° bond angle

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6
Q

molecular geometry: steric # 3, no lone pairs

A

trigonal planar

120° bond angle

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7
Q

molecular geometry: steric # 3, 1 lone pair

A

bent

<180° bond angle

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8
Q

molecular geometry: steric # 4, no lone pairs

A

tetrahedral

109.5° bond angle

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9
Q

molecular geometry: steric # 4, 1 lone pair

A

trigonal pyramidal

109.5° bond angle

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10
Q

molecular geometry: steric # 4, 2 lone pairs

A

bent

<109.5° bond angle

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11
Q

Boiling point

A

temperature at which the vapour pressure of the liquid equals the surface pressure

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12
Q

Red litmus paper

A

basic substance → turns blue

acidic or neutral substance → stays red

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13
Q

which ions are often responsible for colour in solution

A

complex ions containing transition metals (d block elements) are usually coloured, whereas the similar ions from non-transition metals aren’t

electrons in the lower energy d orbitals absorb visible light to move to the higher energy d orbitals

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14
Q

“carboxyl group”

A

the functional group COOH

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15
Q

carboxylic acid

A

a compound with a carboxyl group attached

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16
Q

hydrolysis

(to be hydrolyzed)

A

add water to break bonds

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17
Q

dehydration synthesis

A

bonds are formed as water is released

18
Q

Triglyceride

19
Q

ester

20
Q

how are esters formed

A

from a carboxylic and and alcohol

an ester bond is formed and a water molecule is released

21
Q

High retention factor (Rf) value = ____________

A

further distance travelled

22
Q

retention factor (Rf) formula

23
Q

silica gel is ________ (polar/nonpolar)

A

polar

(other polar substances ‘stick’ to it)

24
Q

mmol to mol conversion

A

1 mole = 1000 mol

25
Equilibrium constant (Keq) equation
26
equation for amount of heat gained or lost from a system
q = mc∆t
27
isopropyl group
28
tert butyl group
29
atomic radii trends on periodic table
bottom left = largest top right = smallest
30
of protons
determined by atomic number
31
of electrons
= atomic number *(same as # of protons)*
32
of neutrons
= atomic mass - # of protons *(atomic mass = protons + neutrons)*
33
ionic bonds usually occur between… (2)
metals and nonmetals usually between elements on the far left and far right of the periodic table
34
wedge and dash to chair conformation wedge = _______ (up/down) dash = _______ (up/down)
wedge = **UP** dash = **DOWN**
35
Metals are on the _____ (left/right) of the periodic table Nonmetals are on the _____ (left/right) of the periodic table
Metals are on the **LEFT** of the periodic table Nonmetals are on the **RIGHT** of the periodic table
36
electronegativity differences and bond type
37
Electronegativity trends in periodic table
38
Graphite is composed of which element?
carbon
39
negative delta S meaning
entropy decreases
40
positive delta S meaning
entropy increases
41
Gibb's Free energy equation
42
2 characteristics of ideal gases
molecules have **no intermolecular forces** and occupy **no volume**