Acids and Bases Flashcards

1
Q

Arrhenius Theory of Acids and Bases

A

a substance that donates a H+ is an acid and a substance that donates a OH- is a base

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2
Q

neutralization reaction

A

when an acid is mixed with a base, a salt and water forms

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3
Q

Bronsted-Lowry Acid

A

substance that donates a H+

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4
Q

Bronsted-Lowry Base

A

substance that accepts a H+

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5
Q

hydronium is a

A

pronated water molecule

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6
Q

conjugate acid/base pair

A

two substances that differ by 1 H+

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7
Q

amphiprotic substance

A

species that can act as an acid or a base

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8
Q

most common amphiprotic substance

A

water

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9
Q

titration

A

types of volumetric analysis where the concentration of a solution can be determined through stoichiometry using a standard solution

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10
Q

titrant

A

solution that is standardized of known concentration

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11
Q

analyte

A

solution tested of unknown concentration

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12
Q

equivalence point

A

point in the titration where the moles of the titrant are equal to the moles of the analyte

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13
Q

acid/base indicators

A

complex molecules that change in the presence of an acid or a base

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14
Q

bromothymol blue

A

green when neutral, blue when basic, yellow when acidic

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15
Q

phenolphthalein

A

turns pink in the presence of a base

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16
Q

What is the difference between a concentrated acid and a strong acid?

A

concentration refers to the amount of molecules in a solvent and strength refers to the extent of ionization

17
Q

strong acid

A

acid that ionizes completely

18
Q

6 strong acids

A

perchloric, hydroiodic, hydrobromic, hydrochloric, nitric, sulfuric

19
Q

weak acid

A

acid that only partially ionizes in water

20
Q

acid ionization constant

A

Ka; equilibrium constant for weak acids

21
Q

all weak acids have a

22
Q

strong base

A

base that ionizes completely

23
Q

strong bases include the OH- bound to a

A

group 1A or 2A element

24
Q

weak base

A

base that partially ionizes in water

25
base ionization constant
Kb; equilibrium constant for weak bases
26
binary acid(Hx)
the strength of a binary acid is determined by bond length
27
bond length
the distance between the H and its anion
28
binary acids: the larger the anion,
the longer the bond, the longer the bond the weaker the bond, the weaker the bond, the easier the H+ ionizes(stronger acid)
29
the more H+ on the binary acids,
the weaker the acid
30
hydrohalic acids are
the strongest acids
31
hydrohalic acids
acids made with halogens
32
ternary acids(oxo-acids, oxy-acids)
the strength of ternary acids are determined by the number of oxygens and the electronegativity of the center atom
33
ternary acids: the stronger acid has
more oxygens; if oxygens are the same, the acid with the more electronegative center atom is stronger
34
carboxyllic acids
the strength of a carboxyllic acid is determined by the polarization of the -O-H- bond
35
carboxyllic acid: the fewer carbons in the base chain
causes increased polarization, making a stronger acid
36
the substance that has the higher Ka value will
act as the acid, the proton donor
37
shifts in equilibria for acid-base systems
the direction of strong acid and strong base forming the weak acid and base is favored
38
the strong acid and the strong base are
always on the same side of the equation
39
leveling effect
the effect that all strong acids ionize completely in water gives the impression that they are all the same strength