Acids And Bases Flashcards

1
Q

Conjugate acid

A

Species produced when a base gains a proton.

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2
Q

Conjugate base

A

Species produced when an acid loses a proton

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3
Q

Conjugate acid-base pair

A

Two species related to another by the presence of a hydrogen ion or its absence

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4
Q

Amphoteric

A

Substance that can act as both an acid and a base

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5
Q

Why should you not mix acid based cleaners with bleach based cleaners?

A

They produce toxic chlorine gas

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6
Q

If [H+] = [OH-] what does it tell you about the pH of the solution?

A

It’s neutral

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7
Q

Strong acid

A

Acid that fully dissociates in water

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8
Q

Why does the expression for Kw not include the concentration for water?

A

So little water is ionised at any one time, that it’s concentration remains relatively constant.

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9
Q

Why does the value of Kw increase as the temperature increases?

A

The forward reaction is endothermic, and absorbs the heat supplied to charge this reaction. As a result equilibrium moves the the left and Kw increases.

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10
Q

Strong acid

A

Fully ionises in solution

E.g. HCl, H2SO4, HNO3

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11
Q

Buffer solution

A

A solution which resits changes in pH when small quantities of an acid or an alkali are added to it.

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12
Q

Acidic buffer

A

A buffer with a pH less than 7

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13
Q

What a common acidic buffer solution?

A

Ethanoic acid and sodium ethanoate

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14
Q

How would you change the pH of a buffer solution?

A

By changing the ratio of acid to salt or by choosing a different acid and specific salt

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15
Q

How does an acidic buffer solution resist changes in pH when an acid is added?

A

The newly introduced H+ combine with the ethanoate ions to make enthanoic acid.
This moves the equilibrium position to the left.

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16
Q

How does an acidic buffer solution resist changes in pH when an alkali is added?

A

1) removal by reacting with HA
This is more like to happen
pH unlikely to change

2) removal by reacting with H+
OH- combine with these to make water
However this moves equilibrium to the right in order to make up for lost H+

17
Q

In the acid dissociation constant, [H+] =

A

Ka x ([HA]/[A-])

18
Q

Why does the expression for Kw not include the concentration for water?

A

So little water is ionised at any one time, that it’s concentration remains relatively constant.

19
Q

Why does the value of Kw increase as the temperature increases?

A

The forward reaction is endothermic, and absorbs the heat supplied to charge this reaction. As a result equilibrium moves the the left and Kw increases.

20
Q

Strong acid

A

Fully ionises in solution

E.g. HCl, H2SO4, HNO3

21
Q

Buffer solution

A

A solution which resits changes in pH when small quantities of an acid or an alkali are added to it.

22
Q

Acidic buffer

A

A buffer with a pH less than 7

23
Q

What a common acidic buffer solution?

A

Ethanoic acid and sodium ethanoate

24
Q

How would you change the pH of a buffer solution?

A

By changing the ratio of acid to salt or by choosing a different acid and specific salt

25
How does an acidic buffer solution resist changes in pH when an acid is added?
The newly introduced H+ combine with the ethanoate ions to make enthanoic acid. This moves the equilibrium position to the left.
26
How does an acidic buffer solution resist changes in pH when an alkali is added?
1) removal by reacting with HA This is more like to happen pH unlikely to change 2) removal by reacting with H+ OH- combine with these to make water However this moves equilibrium to the right in order to make up for lost H+
27
In the acid dissociation constant, [H+] =
Ka x ([HA]/[A-])