Alkane & Alkene Flashcards

(29 cards)

1
Q

What is the main product of this reaction ?

A
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2
Q

What is the main product of this reaction ?

A
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3
Q

What is the main product of this reaction ?

A

all bonds break

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4
Q

What is the main product of this reaction ?

A

cis :)

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5
Q

What is the main product of this reaction ?

A
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6
Q

What is the main product of this reaction ?

A

epoxide and cis

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7
Q

What is the main product of this reaction ?

A

Markovinko, most sub of all !!

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8
Q

What is the main product of this reaction ?

A

anti markovniko, least sub

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9
Q

What is the main product of this reaction ?

A

H goes on the least sub and OH on the most sub of sp2

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10
Q

What is the main product of this reaction ?

A

H on the least and OH on the most forms an ester

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11
Q

What is the main product of this reaction ?

A

trans, non polar, forms bromine ion bridge

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12
Q

What is the main product of this reaction ?

A

OH on the most sub and Br on the least

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13
Q

What is the main product of this reaction ?

A
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14
Q

What is the main product of this reaction ?

A

forms ketone and aldehyde depending on the starting material (H) or not

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15
Q

What is the main product of this reaction ?

A

Forms carbo acids depending on the starting material (H) can form a ketone and a carbo acid

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16
Q

What is the main product of this reaction ?

A

boring Br goes to the less sub
halogen is added to the least sub
anti markovinko

17
Q

What is the main product of this reaction ?

A

allylic bromo one carbon away from double bond.

18
Q

What is the main product of this reaction ?

19
Q

What is the main product of this reaction ?

20
Q

What is the formula for Alkane, Alkene, and Alkyne?

A

Alkane: all sings bonds - CnH2n+2 (Sp3)
Alkene: double bond- CnH2n (sp2)
Alkyne: Triple bond- Cn H2-2 (Sp)

21
Q

What is the difference between Amide and Amine?

A

Amide has an oxygen Nh2O
Amine has Nh2

22
Q

What is the higher BP?

A
  1. (Network solid - Ionic- H- Dipole dipole- Van der Waals )
  2. Longer the chain the higher the BP
  3. If comparing isomers , then Less branched means decrease boiling point.
    (amide - carbo acid- alcohol- amine - aldehyde- ketone -alkane
23
Q

Stability of Radicals rank?

A

Allylic - 3-2-1

24
Q
A

14 sigma and 4 pi bonds
sigma bonds are every bond (1) including hydrogens
pi bonds are double and triple bonds (1-2

25
What is a enolate, radical, and intermediate look like?
enolate - in aldol condensations radical . intermediate +
26
If its more polar then the R f is ?
smaller RF if its non polar the larger the RF (Based on functional group and electronegativity ) alkane and alkene are non polar and benzene
27
what does optically active mean?
has at least 1 chiral center and no symmetry if it doesn't have a chiral center it is optically inactive.
28
what are the deactivating groups ?
NO2- CN- Carbo acid -halogens
29
what are the activating groups?
NH2- OH - OR - R