Alkanes Flashcards

1
Q

what are alkanes

A

saturated hydrocarbons

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2
Q

what is a hydrocarbon

A

contains hydrogen and carbon only

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3
Q

what does it mean by saturated

A

each carbon is bonded 4 times with the maximum number of hydrogens possible

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4
Q

what do cycloalkanes have

A

2 hydrogens per carbon
saturated
functional group isomer of alkenes

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5
Q

where are alkanes found

A

in crude oil which is a mixture of different length of hydrocarbons

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6
Q

how is crude oil vapourised

A

using a furnace to 350 degrees

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7
Q

what does the vapourised oil do once it enters the column

A

it rises through the trays
the longest hydrocarbons don’t vaporise and run down to the bottom

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8
Q

describe the temperature gradient in a fractioning column

A

cooler at the top
as the vapour rises parts of the mixture condense at different temperatures
due to the different chain lengths = different bp
fractions are drawn at different levels

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9
Q

what happens to shortest hydrocarbons

A

they don’t condense at 20 degrees so come off as a gas at the top of the column

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10
Q

what is cracking

A

breaking longer chain alkane into shorter hydrocarbons

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11
Q

what are the two types of cracking

A

thermal and catalytic

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12
Q

what are the conditions for thermal cracking

A

high temperature of 1000 degrees and 70 atm pressure

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13
Q

what is the main products of thermal cracking

A

alkenes

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14
Q

what are alkenes used to make

A

polymers
e.g. plastic

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15
Q

what are the conditions for catalytic cracking

A

slight pressure
high temperature of 450 degrees
a zeolite catalyst is used to help lower the temperature needed

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16
Q

what are the products of catalytic cracking

A

aromatic hydrocarbons
useful for fuel in vehicles

17
Q

what does a zeolite catalyst do

A

lowers temperature and pressure so cracking can occur
lowers costs and speeds up process

18
Q

complete combustion of alkanes

A

burn in oxygen completely to form co2 and h2o

19
Q

what is the incomplete combustion of alkanes

A

alkanes burn with a limited 02 supply it produces carbon monoxide (CO) and carbon (soot)

20
Q

why is carbon monoxide dangerous

A

-poisonous
-it binds to haemoglobin in the blood preventing oxygen bonding
-carbon monoxide can be removed using a catalytic converter

21
Q

what does burning fossil fuels do

A

produces co2 = greenhouse gas

22
Q

what is the greenhouse effect

A

co2 absorbs infrared radiation (heat) from the sun
but it emits some of it back to earth = greenhouse effect

23
Q

what does ozone cause

A

photochemical smog which harms the respiratory system

24
Q

where does ozone occur

A

in the lowest levels of the atmosphere
exists as sunlight, hydrocarbon and nitrogen dioxide and mixes to form ozone (toxic)

25
when are oxides of nitrogen made
when oxygen and nitrogen are found in the air combine under high pressure and temperature
26
what do catalytic converters do
reduce the amount of unburnt hydrocarbons and oxides of nitrogen going into the atmosphere
27
what is wet scrubbing
it helps remove so2 from flue gases this is where an alkali is used to neutralise sulphur dioxide from flue gases
28
what does a chain reaction involve
initiation propagation termination
29
what is initiation
radicals produced normally using visible light or ultraviolet = photochemical reactions / photodissociation the bond breaks equally producing 2 highly reactive radicals
30
what is propagation
when a radical reacts with a non radical molecule new radicals are created and then go on to react with other non-radicals = chain reaction
31
what is termination
when 2 radicals react to form a stable non radical molecule this ends the chain reaction hence termination