Alkenes Flashcards

1
Q

What is stereoisomerism?

A

Compounds with the same structural formula but the atoms are pointing in a different direction in space

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What is E/Z isomerism?

A

A type of isomerism and a type of stereoisomerism that occurs in alkenes due to no rotation in a double carbon bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

In which type of compounds does E/Z isomerism occur?

A

Alkenes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Why can’t alkenes rotate like alkanes?

A

There is no rotation in a double carbon bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What is the Z isomer?

A

Isomer where both atoms are on the ‘same’ side of the carbon

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

How do you determine if an isomer is Z?

A

If the atoms bonded to the carbon with the highest priority (highest atomic number) are on the same side

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is the E isomer?

A

The isomer where the highest priority atoms are on opposite sides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

How do you name an E/Z isomer?

A

Put a ‘Z’ or ‘E’ at the front when naming the alkene, treating E or Z like a number with a dash (-) after it

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Provide an example of an alkene that can exist as E/Z isomers.

A

But-2-ene can exist as Z-but-2-ene or E-but-2-ene

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

What condition must be met for E/Z isomers to occur?

A

Both carbons in the double carbon bond must have two different atoms or groups attached

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

True or False: All alkenes have E/Z isomers.

A

False

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

What is addition polymerisation?

A

Addition polymerisation is the process where monomers are joined together to form a polymer.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

What is a polymer?

A

A polymer is a large molecule made up of many repeating units called monomers.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What happens during the formation of an addition polymer?

A

During the formation of an addition polymer, the double bonds in alkenes break and the alkenes join together in a chain.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What is represented by the notation C=C?

A

C=C represents the double bond between carbon atoms in alkenes.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

What does the symbol ‘n’ signify in the context of polymers?

A

‘n’ signifies the number of alkenes that are joined together to form the polymer.

17
Q

How do you denote a polymer made from an alkene?

A

To denote a polymer made from an alkene, you write the name of the polymer in front of the alkene.

18
Q

What is the environmental impact of recycling polymers?

A

Recycling reduces the environmental impact of discarded polymers by preventing them from ending up in landfills.

19
Q

What are the steps involved in recycling polymers?

A

Discarded polymers are sorted, chopped, washed, dried, and then melted.

20
Q

What happens to recycled polymers after processing?

A

The recycled polymer is then sold for further use.

21
Q

What is a hazard associated with recycling PVC?

A

Recycling PVC can release hydrogen chloride, a corrosive gas.

22
Q

Why are some polymers difficult to recycle?

A

Some polymers are difficult to recycle because they are derived from petroleum.

23
Q

What is one method of waste management for non-recyclable polymers?

A

Non-recyclable polymers can be incinerated to produce heat and generate steam.

24
Q

What can be generated from incinerating waste polymers?

A

Incinerating waste polymers can generate electricity for the national grid.

25
What is feedstock recycling?
Feedstock recycling is a chemical and thermal process that reclaims monomers, gases, or oil to reuse and make new products from waste polymers.
26
How can feedstock recycling benefit crude oil production?
The materials reclaimed through feedstock recycling can be used as raw materials for the production of new polymers in refineries.
27
What is a major advantage of feedstock recycling?
A major advantage of feedstock recycling is that it is able to handle unsorted and unmixed polymers.
28
What are biodegradable polymers?
Biodegradable polymers are broken down by microorganisms into water, carbon dioxide, and organic compounds.
29
What are biodegradable polymers typically made from?
They are usually made from starch or cellulose, or contain additives that alter the structure of traditional polymers.
30
What are compostable polymers?
Compostable polymers leave no toxic residue and are based on polylactic acid.
31
What are some examples of products made from compostable polymers?
Examples include plates and cups made of sugar cane fiber, which are replacing traditional plastic products.
32
What are photo degradable polymers?
Photo degradable polymers are plant-based polymers that can degrade when exposed to light.
33
How do photo degradable polymers start degradation?
They contain bonds that are weakened by absorbing light to start degradation.
34
What are light-absorbing additives used for?
Light-absorbing additives are used in the development of photo degradable polymers.
35
What are the four reactions that occur with alkenes
Hydrogenation, Halogenation, Hydrogenation, Hydration reactions
36
What conditions do you need for hydrogenation, what does this make
Needs to be passed through a nickel catalyst at a temperature of 150°C. It is used to make saturated oil (margarine)
37
What are the conditions needed for the hydration of alkenes
Alkenes react with steam. In the presence of a phosphoric acid (H₃PO₄)with high temp of 300°C and 60atm
38
What are the dangers of consuming saturated fats
They cause heart disease