alkenes Flashcards

(43 cards)

1
Q

What are alkenes?

A

Alkenes are unsaturated hydrocarbons.

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2
Q

What is the general formula for alkenes?

A

The general formula for alkenes is CnH2n.

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3
Q

What does it mean for alkenes to be unsaturated?

A

It means there is at least one double covalent bond.

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4
Q

What types of elements do alkenes contain?

A

Alkenes contain hydrogen and carbon only.

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5
Q

What is the significance of double bonds in alkenes?

A

Double bonds have a high electron density, making alkenes fairly reactive.

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6
Q

How do cycloalkenes differ from their straight-chain counterparts?

A

Cycloalkenes have 2 fewer hydrogens than their straight-chain version.

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7
Q

Why are alkenes attacked by electrophiles?

A

Alkenes are attacked by electrophiles due to their double bond having a high density of electrons.

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8
Q

What role does an electrophile play in reactions with alkenes?

A

An electrophile is an electron pair acceptor that is attracted to the double bond.

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9
Q

What is a test for alkenes involving bromine?

A

A test for alkenes is the decolouration of bromine water.

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10
Q

What color change indicates the presence of an alkene when bromine water is added?

A

The color changes from brown-orange to colorless.

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11
Q

What happens when bromine is added to an alkene?

A

Bromine, as the electrophile, adds to the alkene forming a dibromoalkane (colorless).

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12
Q

What are allenes?

A

Allenes are monomers which join to form addition polymers.

Allenes can participate in polymerization reactions to create complex structures.

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13
Q

What are the two types of polymers?

A

Polymers can be classified as:
* Natural
* Synthetic

Natural polymers include proteins and natural rubber, while synthetic polymers include poly(ethene) and poly(propene).

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14
Q

What are examples of natural polymers?

A

Natural polymers include:
* Proteins
* Natural rubber

These polymers are derived from natural sources and play critical roles in biological systems.

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15
Q

What are examples of synthetic polymers?

A

Synthetic polymers include:
* Poly(ethene)
* Poly(propene)

These polymers are manufactured through chemical processes and are widely used in various industries.

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16
Q

What are alkenes?

A

Alkenes are monomers which join to form addition polymers.

Alkenes contain at least one carbon-carbon double bond, making them reactive in polymerization.

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17
Q

What is Addition polymerisation?

A

A process where small molecules join together to make polymers

It involves the formation of long chain molecules from monomers.

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18
Q

Define Monomer.

A

A small molecule that can join together to form a polymer

Monomers are the building blocks of polymers.

19
Q

What is a Polymer?

A

A long chain molecule made from many small molecules joined together

Polymers can have various properties depending on their monomers.

20
Q

What is Condensation polymer?

A

A polymer formed by the joining of small molecules with the release of another small molecule (e.g., water)

This process often involves the formation of covalent bonds.

21
Q

What characterizes an Addition polymer?

A

Formation of long chain molecules from small molecules joining together without any other products

This process typically does not release small molecules like water.

22
Q

Fill in the blank: A _______ is a small molecule that can join together to form a polymer.

23
Q

Fill in the blank: A _______ is a long chain molecule made from many small molecules.

24
Q

True or False: Addition polymerisation produces other small molecules as byproducts.

25
What happens during the process of condensation in polymer formation?
Small molecules join together, releasing another small molecule, such as water ## Footnote This is a key difference from addition polymerisation.
26
What is the main difference between Addition and Condensation polymerisation?
Addition polymerisation does not produce byproducts, while condensation does ## Footnote This distinction is crucial for understanding different polymerization methods.
27
What is needed to make poly(propene)?
The monomer propene and a few of these bonded together to form poly(propene) ## Footnote Poly(propene) is a polymer derived from the monomer propene
28
What happens to the double bond in propene when forming the polymer?
The double bond opens up to form the polymer ## Footnote This process is known as polymerization
29
What type of forces are present between most polyalkene chains?
Van der Waals forces ## Footnote These forces are weak intermolecular interactions
30
How do van der Waals forces relate to the length of polymer chains?
The longer the chain and the closer they are to each other, the more van der Waals forces you have ## Footnote This affects the physical properties of the polymer
31
What characteristics do shorter polymer chains with a lot of branching tend to have?
More flexible and weaker ## Footnote Branching affects the packing and overall strength of the polymer
32
What characteristics do polymers with little or no branching and long chains tend to have?
More rigid and stronger ## Footnote The structure allows for better alignment and packing
33
What is an example of a polymer that can have halogens, such as chlorine?
PVC (polyvinyl chloride) ## Footnote PVC is widely used in construction and plumbing due to its properties
34
What type of forces can polymers with halogens form?
Stronger permanent dipole-dipole forces ## Footnote These forces lead to different properties compared to non-polar polyalkenes
35
True or False: Most polyalkenes are polar.
False ## Footnote Most polyalkenes are non-polar
36
What are plasticisers?
Plasticisers are added to polymers to change their properties ## Footnote Plasticisers make polymers more flexible by sliding between the polymer chains, pushing them apart.
37
How do plasticisers affect polymer chains?
Plasticisers weaken the intermolecular forces between the chains, allowing them to slide over each other more easily ## Footnote This makes the polymer easier to bend.
38
Which polymer is commonly modified by plasticisers?
PVC - poly (vinyl chloride) ## Footnote PVC is made from long, closely packed polymer chains that are hard but brittle.
39
What is the effect of adding plasticisers to PVC?
It makes PVC more flexible ## Footnote Flexible PVC is used for applications like electrical cable insulation and clothing.
40
Fill in the blank: Plasticisers are commonly used to change the properties of _______.
PVC
41
True or False: Plasticisers make polymers more rigid.
False
42
What is the structural formula for chloroethene?
C=C ## Footnote Chloroethene is also known as vinyl chloride.
43
What is one application of flexible PVC?
Electrical cable insulation ## Footnote Flexible PVC is preferred for applications requiring bendability.