All Mechanisms + reactants + conditions (A2) Flashcards

1
Q

Alkene to Haloalkane

A

Mechanism: Electrophilic Addition
Reagent: HBr, HCl, Br2 or Cl2

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2
Q

Alkene to Alkyl hydrogen-sulfate

A

Mechanism: Electrophilic Addition
Reagent: H2SO4

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3
Q

Alkane to Haloalkane

A

Mechanism: Free-Radical Substitution
Reagent: Br2 or Cl2
Condition: UV light

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4
Q

Alkane to CO2 + H2O

A

Reagent: O2
Reaction type: Combustion

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5
Q

Haloalkane to Alkene

A

Mechanism: Elimination
Reagent: KOH
Condition: Ethanol, reflux

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6
Q

Haloalkane to Alcohol

A

Mechanism: Nucleophilic Substitution
Reagent: NaOH
Condition: Aqueous, heat under reflux

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7
Q

Haloalkane to Amine

A

Mechanism: Nucleophilic Substitution
Reagent: Excess NH3
Condition: Ethanol, heat and pressure

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8
Q

Haloalkane to Nitrile

A

Mechanism: Nucleophilic Substitution
Reagent: KCN
Condition: Water and Ethanol

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9
Q

Nitrile to Amine

A

Reagent: H2
Condition: Nickel [catalyst]

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10
Q

Amine to 2°/3° Amine Or Ammonium Quaternary Salt

A

Mechanism: Nucleophilic Substitution Reagent: Excess Haloalkane

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11
Q

Alkene to Alcohol

A

Reagent: Steam
Condition: H3PO4 [catalyst]
Reaction type: Direct Hydration

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12
Q

Alcohol to Alkene

A

Mechanism: Elimination
Reagent: Hot Conc H2SO4 OR Al2O3 [catalysts]
Condition: 600K

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13
Q

Alkyl Hydrogen-Sulphate to Alcohol

A

Reagent: H2O

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14
Q

Glucose to Alcohol

A

Conditions: Yeast, 35°C, no O2
Reaction type: Fermentation

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15
Q

1° Alcohol to Carboxylic Acid

A

Reagent: H2SO4 and K2Cr2O7
Conditions: Reflux, excess oxidising agent
Reaction type: Oxidation

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16
Q

1° Alcohol to Aldehyde

A

Reagent: H2SO4 and K2Cr2O7
Conditions: Distillation
Reaction type: Oxidation

17
Q

2° Alcohol to Ketone

A

Reagent: H2SO4 and K2Cr2O7
Conditions: Reflux or Distillation
Reaction type: Oxidation

18
Q

Aldehyde to Carboxylic Acid

A

Reagent: H2SO4 and K2Cr2O7
Conditions: Reflux
Reaction type: Oxisation

19
Q

Aldehyde to Hydroxyl Nitrile

A

Reagent: KCN
Conditions: Aqueous, ethanolic

20
Q

Carboxylic Acid to Ester

A

Reagent: Alcohol
Conditions: H2SO4 [catalyst]

21
Q

Acid Anhydride to Ester

A

Reagent: Alcohol OR Phenol

22
Q

Acyl Chloride to Ester

A

Mechanism: Nucleophilic Addition- Elimination
Reagent: Alcohol

23
Q

Aldehyde OR Ketone to Alcohol

A

Mechanism: Nucleophilic addition
Reagent: NaBH4
Conditions: Acidic Solvent
Reaction type: Reduction

24
Q

Ester to Salt (COOH) + Alcohol

A

Reagent: NaOH and H2O
Reaction type: Base Hydrolysis

25
Ester to Carboxyl and Alcohol
Reagent: H+ and H2O Reaction type: Acid Hydrolysis
26
Acyl Chloride to Amide
Reagent: NH3I
27
Benzene to Acyl Benzene
Mechanism: Electrophilic Substitution Reagent: Acyl group (RC=O) Conditions: AlCl4+ (catalyst) and RCO+ (electrophile) Reaction type: Acylation
28
Benzene to Nitrobenzene
Reagent: Conc HNO3 Conditions: Conc H2SO4
29
Nitrobenzene to Phenyl Amine
Reagent: HCl Conditions: Sn catalyst Reaction type: Reduction
30
Long Chain Carboxylic Acid (Fatty acid) to Ester
Reagent: Glycerol
31
Biodiesel to Methyl Esthers
Reagent: Methanol Other Product: Glycerol
32
Acid Anhydride reacts with Water
Products: 2 Carboxylic acids
33
Acid Anhydride reacts with Alcohol
Products: Carboxylic Acid and Esther
34
Acid Anhydride reacts with Ammonia
Products: Carboxylic Acid and Amide Note: + Excess Ammonia = Salt of COOH
35
Acid Anhydride reacts with 1° Amine
Products: Carboxylic Acid and 2° Amide
36
Dicarboxylic Acid reacts with Diol
Products: Polyester and H20 - Ester bond
37
Dicarboxylic Acid reacts with Diamine
Products: Polyamide and H2O - Peptide bond