AS2 2.5 Quantum Physics Flashcards
(44 cards)
What is a photon?
A photon is an indivisible packet of electromagnetic energy.
What did Einstein theorise about light?
Light is made up of photons
What does the energy of a photon depend on?
The frequency of the photon, NOT the intensity
What is photon energy proportional to?
Light energy
What is the equation for energy per photon?
E = hf
E = energy per photon (J)
f = frequency of light (Hz)
h = Plank’s constant (6.63 x 10^-34) (Js)
what is the equation for frequency? (Quantum Physics)?
f = V/ λ
f = frequency (Hz)
V = speed of light (3 x 10^8) (m/s)
λ = wavelength (m)
What is an electron volt and what is it equal to in joules?
It is another way of writing energy
1 electron volt = 1.6 x 10^-19 Joules
What observations can’t be explained using the energy of light?
- Emission of electrons from metal surface does NOT take place if the frequency of the EM radiation is below the threshold frequency?
- If the frequency is < threshold frequency, no matter how intense the radiation, no emissions will take place
- photoemission occurs without delay (provided f > threshold frequency)
What is the photoelectric effect?
When light is incident on a metal surface, an electron volt at the surface absorbs a single photon from the incident light , and therefore gains energy equal to hf, where hf is the energy of a light photo
When can an electron leave the metal surface in the photoelectric effect?
An electron can leave the metal surface if the energy gained from a single photon exceeds the work function of the metal
What is the work function?
The minimum energy a photon must have to cause the emission of electrons?
What is the threshold frequency?
The minimum frequency a photon must have to cause the emission of electrons?
What is the equation for the energy of a photon?
E(photon)= Φ + Ek
1/2mv^2(max) = hf - hfo
Ek = E(photon) - Φ
Φ = work function
How can the number of electrons released can be increased (assuming f >fo) ?
- increase the intensity of the radiation - if we visualize more photons landing per unit area, clearly more photons will be released.
- increase the frequency of the radiation - work function is the energy required to free electrons from the surface. Φ increases, fo increases with depth. increasing frequency increases the energy allowing the photons to go deeper.
2 conditions required for photoelectrons to be emitted from the surface of metal?
- The photons must be absorbed b y the electrons
- Photons must have energy greater than or equal to the work function of the metal.
what are the characteristics of energy levels?
- Electrons exist in energy levels
- Energy levels are said to be discrete. this means they have exact values
- Typically, electrons exist in the ground state
- The energy of an electron shell is constant.
What is the ground state?
the lowest possible energy level or most stable energy level
An orbit with an energy where an electron can remain
What is excitation?
when an electron moves up an energy level by absorbing energy.
What are the two ways that excitation can occur?
- When the atom collides with another particle
- When the electron absorbs a photon with the exact amount of energy it needs to jump a level.
What is relaxation (De-Excitation)?
- The electron configuration in an excited atom is unstable. The vacancy is filled by an electron from an outer shell.
- When an electron falls, it loses energy and the atom emits a photon. The energy of the photon is the exact energy that is lost.
What is the Absorption Spectra?
- white light is a mixture of photons on different colour “frequencies”. When the light is viewed after passing through the gas we can see black absorbed lines. These lines represent the frequency of photons which have been absorbed to excite electrons.
What is the Emission Spectra?
Each possible drop between energy levels in an atom corresponds to the emission of one specific frequency of photon. This results in one line in an element’s emission spectrum.
What does Line Emission mean?
The emission of light from elements proves that there are discrete energy levels in that atom.
What are the 6 energy levels of hydrogen?
0 : n = ∞
- 0.54 : n = 5
- 0.85 : n = 4
- 1.51 : n = 3
- 3.40 : n = 2
- 13.59 : n = 1