Atomic Absorption Spectroscopy Flashcards
(12 cards)
Systematic error
- consistently higher or lower than actual value
- flaws in method/instrument or human error
How to fix systematic error
use the correct technique and properly calibrated instruments
Reliability
a measure of how an experiment can be repeated with consistent results
- affected by random error
Precision
how close data values are
- affected by random error
Random error
- inconsistently higher or lower than actual value
Random error fix
more trials to get a clearer average
Systematic error example
- measuring meniscus consistently wrong
- weight isn’t calibrated properly
Random error example
- qualitative observations (differences in human observations)
- reading from ruler or thermometer isn’t exactly precise
Atomic Absorption Spectroscopy
identifies amount of element present by measuring absorbed light
QUANTITATIVE
AAS Process
- sample goes through hollow cathode lamp (made of same elements so emitted light will be same wavelengths for elements to absorb)
- sample is sprayed onto burner -> makes it into a gas (atomiser)
- light is passed through sample, then goes through slit
- defraction grating monochromoter - light defracts through prism or light filter -> filters out other wavelengths
- Detector - measures intensity of light
- Output display spectra - gives absorbance spectra (like an inverted emission spectrum)
Accuracy
how close the data values are to true value
- affected by systematic error
Validity
the accuracy of a measurement - the degree to which an instrument, statistical technique or a test measures what it’s supposed to measure