bonding Flashcards

(78 cards)

1
Q

ionic compounds contain..

A

a metal and non metal

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2
Q

what happens when ionic compounds form

A

electron transfer

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3
Q

what us a single covalent bond

A

a shared pair of electrons

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4
Q

what does the number of unpaired electrons indicate?

A

the number of covalent bonds that can be made

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5
Q

how many covalent bonds can carbon make

A

4

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6
Q

what is an ion?

A

a charged particle

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7
Q

what are cations?

A

positive ions

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8
Q

what are anions?

A

negative ions

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9
Q

what is an ionic bond?

A

the elctrostatic attraction between oppositely charged ions

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10
Q

what do elements lose/gain electrons to achieve?

A

nobel gas configuration

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11
Q

what is different about transition metals?

A

do not always achieve nobel gas configuration

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12
Q

what is an ionic lattice?

A

regular, repeated 3D framework of ions

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13
Q

what is each:

1) Na+ ion sureounded by in NaCl

2) Cl- ion sureounded by in NaCl

A

1) 6 Cl- ions

2) 6 Na+ ions

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14
Q

what tyoe of crystal structure is NaCl?

A

cubic

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15
Q

what is decrepitation?

A

cracking sounds made when an ionic crystalline structure breaks up upon heating

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16
Q

why does ionic solids have high melting points?

A

strong electrostatic attractions between oppositely charged ions require alot of energy to break

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17
Q

what increases the strength of ionic bonds?

A

smaller ions and higher charge

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18
Q

why are positive ions smaller than their atoms

A

losing an electron from an outer shell inscreases the effective nuclear charge pulling electrons closer to the nucleus

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19
Q

why are negative ions larger than their atoms?

A

effective nuclear charge decreases and increases electron repulsion

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20
Q

wht are ionic compounds usually soluble in water?

A

water is a polar solvent

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21
Q

why are some ionic compounds not soluble in water

A

the electrostatic attraction is so strong, water cannot break the lattice apart

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22
Q

why can ionic compounds conduct electrocity when molten or dissolved?

A

charges are free to move and transport a current

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23
Q

how is a single covalent bond represented

A

a line

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24
Q

how is a double covalent bond represented

A

a double line

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25
what is a lone pair
a pair of electrons not involved in bonding
26
whoch orbitals are used if bonding results in more than 8 calence electrons?
d orbitals
27
what is another name for a dative covalent bond
coordinate bond
28
what is a dative covalent bond?
a lone pair is donated into an empty orbital on another atom
29
what is different about a dative covalent bond?
both electrons come from one atom
30
how do you represent a dative covalent bond?
an arrow
31
what is different about the properties of a dative covalent bond and a standard covalent bond?
nothing
32
define metallic bonding
electrostatic forces between delocalised electrons and positive metal ions in a lattice
33
why can metals conduct electricity?
delocalised electrons can transport a current
34
why can metals conduct heat?
delocalised electrons can transfer energy
35
why are metals malleable/ductile?
laters of metal ions can slide over eachother without distrupting the bonding
36
why do metals have high boiling points?
requires a lot of energy to break strong electrostatic atteaction between delocalised electrons and positive metal ions
37
why do transition metals have higher boiling points?
large number of d subshell, electrons delocalise forming stronger bonds
38
what is another name for a giant covalent structure?
macromolecular
39
what are crystal structures of simple covalent compounds called?
molecular covalent crystals
40
give an example of a molecular covalent crystal
ice
41
name three properties of molecular covalent crystals:
low melting point brittle do not conduct electricity
42
what is an allotrope?
different forms of the same element in the same physicao state
43
give two allotropes of carbon
diamond graphite (graphene)
44
give three properties of diamond
hard high melting point does not conduct electricity
45
give three properties of graphite
lubricant high melting point does conduct electricity
46
what is sublimination?
change of state from solid to gas
47
why do lone pairs cause more repulsion?
held closer to the nucleus
48
2 bonding pairs 0 lone pairs: name angle
linear 180•
49
3 bonding pairs 0 lone pairs: name angle
trigonal planar 120•
50
4 bonding pairs 0 lone pairs: name angle
tetrahederal 109.5•
51
3 bonding pairs 1 lone pair: name angle
pyramidal 107•
52
2 bonding pairs 2 lone pairs: name angle
bent 104.5•
53
5 bonding pairs 0 lone pairs: name angles
trigonal bypyramid 90• and 120•
54
3 bonding pairs 2 lone pairs: name angle
T shaped 86•
55
2 bonding pairs 3 lone pairs: name
linear
56
6 bonding pairs 0 lone pairs: name angle
octahederal 90•
57
4 bonding pairs 2 lone pairs: name angle
square planar 90•
58
4 bonding pairs 1 lone pair: name angles
sawhorse 86• and 117•
59
what is electronegativity?
the power of an atom to attract electron density towards itself
60
wht is the most electronegative element?
fluorine
61
what does electronegativity depend on?
atomic radius- smaller=stronger attraction nuclear charge- more protons=stronger attraction shielding- more e-=more shielding=less attraction
62
what is the trend in electronegativity?
increases across a period and up a group /^
63
what dies a delta +ve charge represent?
electron efficient
64
what does a delta -ve charge represent?
electron rich
65
why is BF3 non-polar
it is symmetrical
66
what is another word for polar?
permenant dipole moment
67
what is an intermolecular force?
a force between molecules
68
what is an intramolecular force?
a force within molecules
69
name theee types if intermolecular force
Van dee Waal dipole-dipole Hydrogen bond
70
how do VDW forces occur?
random movement of electrons causes a temporary dipole which induces a dipole in a neighbouring atom, the resulting opposite delta charges attract
71
what are teo other names for VDW forces?
induced dipole-dipole london forces
72
what happens to VDW attraction as atomic radius increases
gets stronger
73
what is a permenant dipole-dipole force?
interaction between teo permenant dipoles due to the attraction of opposite delta charges
74
which theee bonds can form hydrogen bonds?
N-H O-H F-H
75
which intermolecular force is the strongest?
hydrogen bonds
76
why is ice less dense than water?
hudrogen bonds form an open crystalline structure
77
what sort of molecules dissolve in polar solvents?
polar molecules
78
what sort if molecules dissolve in non-polar solvents?
non-polar molecules