C12-alkanes Flashcards

(59 cards)

1
Q

what is a hydrocarbon

A

compound containing only hydrogens and carbons

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2
Q

what is a saturated hydrocarbon

A

only contains single bonds between carbon atoms

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3
Q

what is the general formula for an alkane

A

Cn+H2n+2

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4
Q

name the first 4 alkanes

A

methane
ethane
propane
butane

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5
Q

what si the trend in boiling points in alkanes

A

as chain length increases the boiling point increases

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6
Q

why are hydrocarbons non polar

A

the electronegativity difference between carbon and hydrogen is very small

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7
Q

what tyoe of IMF exists between hydrocarbon chains

A

van der waals

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8
Q

why do branched chains have lower melting points

A

smaller surface areaso fewer VDW attractions

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9
Q

how are mixtures of hydrocarbon seperated

A

feactional distillation

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10
Q

what dies the word immisible mean

A

does not mix

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11
Q

what is crude oil

A

a mixture of different hydrocarbons

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12
Q

what is a fraction?

A

a group of compounds woth similar boiling points that are removed at the same lvl of the fractionatijg column

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13
Q

where are smaller hydrocarbons collected

A

near the too of the fractionating column

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14
Q

why do small chains have lower boiling points

A

less atoms in the chain so less VDW forces between then

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15
Q

what happens in cracking?

A

long hydrocarbons are converted into smaller hydrocarbons

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16
Q

why is cracking useful

A

shorter hydrocarbons are more useful

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17
Q

name two tyoes of cracking

A

thermal and catalytic cracking

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18
Q

gove the conditions for thermal cracking

A

1000-1200 K and upto 70 atm

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19
Q

what is the time frame for thermal cracking

A

1s

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20
Q

why is thermal cracking so short

A

to orevent complete decomposition of the hydrocarbon

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21
Q

what catalyst is used in catalytic cracking

A

a zeolite

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22
Q

what is a zeolite

A

an acidic mineral with a honeycomb structure made from aluminium oxide and silicon dioxide

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23
Q

what are the conditions for catalytic cracking

A

800-1000 K 1-2 atm zeolite catalyst

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24
Q

what is the purpose of the honeycomb structure

A

to increase surface area and so rate if reaction

25
whats the time frame for catalytic cracking
2-4s
26
what is produced in thermal cracking
high percentage of alkenes and some shirt alkanes
27
what is peoduced in catalytic cracking
mainly aromatic hydrocarbons and motor fuels
28
what is required for complete combustion
excess amount of oxygen
29
what is a major component of natural gas
methane
30
what is the major component of liquid petroleum gas
butane
31
what is formed in incomplete combustion
carbon monoxide and water
32
give three properties of carbon monoxide
toxic colourless odourless
33
why is carbon minoxide toxic
binds to heamoglobin in red blood cells preventing them from carrying oxygen
34
what is soot
carbon particulates
35
what are the four stages of internal combustion engine
intake compression combustion exhaust
36
how is the fuel ignited in an internal combustion engine
extreme temperature spark
37
what tyoe of pollution is caused by CO
toxic gas
38
what pollution is caused by C
particles exacerbate asmaa
39
what pollution is caused by SO2
acid rain
40
what pollution is caused by NOx
acid rain and photochemical smog
41
what pollution is caused by hydrocarbons
react woth NOx to form geound lvl ozone which leads to resporatory problems
42
why is greenhouse effect so important
wothout it, earth would be too cold to support life
43
how is the CO2 in the atmosphere produced
respiration and combustion
44
gow is the methane in the atmosphere produced
byproduct of sheep and cattle farming
45
ph of normal rainy water
5.5
46
why is rain water a weak acid
CO2 present in the atmosphere
47
what pH is acid rain
lower than 5.5
48
what problems does acod rain have
destroys trees and vegetation corrodes buildings and kills fishes in lakes
49
what causes photochemical smog
toxic gases and minute solid oarticles suspended in air
50
when is smog formed
when NOx, SO2 or unburnt hydrocarbons react with sunlight
51
what health problems are associated with smog
irritated eyes nasal congestion emphysema
52
what is the purpose of a catalytic converter
converts toxic compounds from the internal conbustion engine into kess harmful products
53
what is a catalytic converter made of
a cermaic honeycomb covered in a thin layer of platinum and rhodium
54
what is the process used to remove sulfur compounds from combustion emmisions called
flue gas desulfurisation
55
what happens in flue gas desulfurisation
gasses are passed theough a wet slurry of CaO or CaCO3
56
what do the CaO or CaCO3 do in flue gas desulfurisation
neutralise the acidic SO2
57
1) what is the products of flue gas desulfurisation 2) what are they converted into
1) calcium (IV) sulfate (calcium sulphite) 2) calcium (VI) sulfate
58
what is calcium (VI) suldate used for
construction
59
what does [0] represent
oxygen from an oxidising agent