Bonding And Structure Flashcards

(37 cards)

1
Q

Why are ionic compounds hard?

A

Strong electrostatic attraction between the cations and anions which hold the ions in fixed positions

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2
Q

What is the definition of ionic bonding?

A

An ionic bond is the strong electrostatic attraction between anions and cations

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3
Q

Why do ionic compounds not conduct electricity when solid?

A

The ions are fixed in a giant lattice. They cannot move and carry charge

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4
Q

What are ionic compounds?

A

Ionic compounds are giant structures with strong electrostatic attraction between cations and anions which are held in place in a fixed structure by these forces

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5
Q

Why do ionic compounds conduct electricity when molten or in solution?

A

The ionic bonds are broken and the ions are free to move and carry charge

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6
Q

What is the definition of covalent bonding?

A

The strong electrostatic attraction between a shared pair of electrons and the nuclei of bonded atoms

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7
Q

Why do ionic compound solids have high melting and boiling points?

A

Strong electrostatic attraction between cations and anions which needs a lot of energy to overcome

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8
Q

Why does non polar simple covalent not dissolve in water?

A

Water is polar. There is no attraction between polar water molecules and non polar molecules

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9
Q

Why does polar simple covalent dissolve in water?

A

The delta H+ water is attracted to the delta - of polar molecule and visa versa

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10
Q

Why do covalent compounds not conduct electricity?

A

No electrons or ions that are free to move

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11
Q

Why do ionic compounds dissolve in water?

A

Water is polar the slightly positive part of a water molecule attracts anions and the slightly negative part attracts cations

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12
Q

Why do simple covalent molecules have a low mp and Bp?

A

The intermolecular forces between molecules are weak and not much energy is needed to overcome them

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13
Q

What is dative covalent bonding?

A

A special form of covalent bonding where both electrons come from only one atom and none come from the other

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14
Q

How do you predict the shape of a molecule?

A

Total number of pairs on central atom
How many bonding
How many lone

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15
Q

What is the bond angle and shape of SF6?

A

90 degrees octahedral

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16
Q

Why are giant covalent solids with a very high mp?

A

There are many strong covalent bonds throughout the 3D lattice which require a lot of energy to break

17
Q

How much does a lone pair reduce bond angle by?

18
Q

What is the bond angle and shape of NH3?

A

107 degrees pyramidal

19
Q

Why are metallic bonded items strong?

A

Strong electrostatic attraction between delocalised electrons and positive ions holds the ions in a fixed positions in the lattice

20
Q

What is the bond angle and shape of Bf3?

A

120 degrees and triginal planar

21
Q

Name three giant covalent structures

A

Silicon dioxide diamond graphite

22
Q

What is a permanent dipole dipole?

A

Polar molecules will attract each other

23
Q

What is the bond angle and shape of BeCl2v?

A

180 degrees linear

25
Q

What is the definition of electronegativity?

A

The ability of an atom to attract the bonding pair electrons in a covalent bond

26
What is the two things needed to be a polar molecule?
Non symmetrical | Dipoles
27
Where do intermolecular forces occur?
Simple covalent
28
Why are metallically bonded items melleable/ductile?
When the ions move the delocalised electrons move with them and maintain the electrostatic attraction between them
29
What is ionic bonding between?
Metal and non metal ions
29
What is the shape and bond angle of H2O?
104.5 v shaped/non linear
30
What molecules does Van Der Waals occur between?
Non polar
32
What is the bond angle and shape of Ch4?
109.5 degrees tetrahedral
33
How does Van Der Waals forces arise?
There is a higher electron density at one side creating an instantaneous dipole The instantaneous dipole induces a dipole in a neighbouring molecule The instantaneous dipole and induced dipole attract each other
34
What is the definition of metallic bonding?
Strong electrostatic attraction between delocalised electrons and positive cations
35
What molecules does hydrogen bonding occur between?
Polar hydrogen atom and F O N
36
How does hydrogen bonding affects the properties of water?
Solid ice is less dense than water-hydrogen bonds hold water apart in open lattice structure giving it lower density Relatively high MP BP-energy is required to break bonds and it takes more energy to break hydrogen bonds as it is the strongest intermolecular force
36
Why do metallically bonded substances have high MP BP
Strong electrostatic attraction between delocalised electrons and positive ions requires a lot of energy to overcome
37
Why do metallically bonded items conduct electricity?
delocalised electrons can move and carry charge