book 83 fire chemistry Flashcards
(44 cards)
Liquids having a flash point at or above 100 degrees F.
Combustible liquids
Rapid oxidation of a substance accompanied by the release of energy usually in the form of heat and light.
Fire
The lowest temperature of a liquid in an open container at which vapors evolve fast enough to support continuous combustion.
Fire Point
The term lower flammable limits (LFL) describes the minimum concentration of vapor -to -air below which propagation will not occur in the presence of an ignition source. The “upper flammable limit” (UFL) is the maximum vapor-to-air concentration above which propagation of flame will not occur.
Flammable limits
Liquids having a flash point below 100 degrees F.
Flammable liquids
The minimum temperature at which a liquid gives off vapors in sufficient concentrations to form an ignitable mixture with air near the surface of the liquid.
Flash point
A form, of energy associated with the motion of atoms and molecules.
Heat
The amount of heat released during the complete oxidation of a substance.
Heat of combustion
The minimum temperature to which a substance must be heated in air in order to initiate or cause combustion, independent of the heating element or source. The ignition temperature of ordinary combustibles is between 300 and 1000 degrees. F
Ignition temperature
As a substance burns, it mixes with oxygen and produces heat.
Oxidation
The ratio of the weight of a solid or liquid substance to the weight of an equal volume of water.
Specific gravity
The quantity of heat concentration. The intensity of heat is measured in degrees (Fahrenheit or Celsius).
Temperature
The weight per unit volume of a pure gas or vapor. In fire protection, vapor density is reported in terms of the ratio of the relative weight of a volume of vapor to the weight of an equal volume of air under the same conditions of temperature and pressure.
Vapor density
A vapor denisty less than 1.0 indicates a vapor is ____ than air.
lighter
A vapor density more than 1.0 indicates a vapor ______ than air.
heavier
Heat , fuel, oxygen equals?
The fire triangle
Heat , Fuel , Oxygen and Uninhibited chain reaction among all parts of the ________
Fire tetrahedron
The Chemical decomposition of matter through the action of heat.
Pyrolysis
The transfer of heat from one object to another through direct physical contact.
Conduction
The transfer of heat by some circulating medium (liquid or gas). This is the form of heat transfer most RESPONSIBLE for fire spread in structural fires.
convection
Example; The spreading of fire from lower to upper structural areas when upper areas become heated to their ignition temperature is ____.
Convection
The transfer of heat as energy traveling through space or materials as waves.
Radiation
example: exposure problems in large fires…
Although actual flame temperatures can reach 1000 degrees F. temperatures in the surrounding area are not greatly increased. There is free burning with open flame. Oxygen in the area remains new 21%. Thermal updrafts causes heat to accumulate at the higher portions of the area.
Incipient phase (growth)
Fully developed
air from surrounding atmosphere is drawn into the fire fire.
Mushrooming may take place and flame is present. Oxygen content of area is usually reduced to 16%-18% Fire gases which may be present are carbon, carbon monoxide, carbon dioxide, water, sulfur dioxide,
Flashover frequently occurs during this phase.
Free burning phase.