C2: Bonding Flashcards

Class 2 (38 cards)

1
Q

what is STP?
- what is the volume of 1 mol of gas at STP?

A

T= 273K or 0 degrees C, P= 1atm
- 1 mol of gas = 22.4L

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

what are standard state conditions for temperature and pressure?

A

T= 298K or 25 degrees C, P= 1 atm

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

metals tend to form ____ and usually have ____ oxidation states

A

cation; positive

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

are metals…
- ductile
- malleable
- good/bad thermal conductors
- good/bad electrical conductors

A
  • yes
  • yes
  • good
  • good
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

nonmetals have a ____ melting point than metals and form ____

A

lower; anions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

metalloids have characteristics of ….

A

metals and nonmetals

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

what is an intramolecular bond?
- intermolecular bond?
- which of the 2 is stronger?

A

a bond within a molecule
- a bond between 2 molecules
- intramolecular bonds are much stronger

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

what is an ionic bond?
- a big difference in ____ is needed for these types of bonds

A

when a metal gives electrons to a nonmetal
- electronegativity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

what is a covalent bond?
- if electronegativity is different, it is a…

A

(nonmetal + nonmetal)
nonmetals SHARE valence electrons to get an octet
- polar bond with a dipole moment

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

what is a polar bond?

A

when electron density between 2 nuclei is uneven (electronegativity difference) and a dipole moment exists

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

the greater the electronegativity difference, the greater the …

A

dipole moment

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

what is a coordinate covalent bond?

A

when one atom donates both of the electrons in a bond (lewis base) and another atom atom accepts electrons (lewis acid)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

what happens when a coordinate covalent bond breaks?

A

the electrons that come from the lewis base will leave with that lewis base

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

if dipole exists on a molecule, the molecule must be ….

A

polar

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

what is an ion dipole bond?
- does this bond show a permanent or weak dipole?

A

a bond between an ion and a polar molecule
- permanent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

what is a dipole- dipole bond?
- does this bond show a permanent or weak dipole?

A

a bond between 2 polar molecules
- permanent

17
Q

what is a dipole induced dipole bond?
- does this bond show a permanent or weak dipole?

A

a bond between a polar molecule and a non polar molecule
- both

18
Q

what is a london dispersion force bond?
- does this bond show a permanent or weak dipole?
- LDF is a ____ force
- ____ only experience LDF

A

a bond between 2 non- polar molecules
- weak
- default
- nonpolar

19
Q

sort the following bonds from strongest to weakest:
- dipole induced dipole
- ion dipole
- LDF
- dipole dipole

A

from strongest to weakest:
- ion dipole
- dipole dipole
- dipole induced dipole
- LDF

20
Q

what kinds of bonds are considered van der Waal forces?

A

dipole dipole, dipole induced dipole, LDF

21
Q

____ bonding is the strongest type of intermolecular force between neutral molecules. these types of bonds only occur between ….

A

hydrogen; N, O, F

22
Q

for N, O or F…
- they donate ____ charges from their lone electrons
- are weak lewis ____
- are hydrogen bond ____

A
  • negative
  • bases
  • acceptors
23
Q

for a hydrogen bound to N, O or F…
- it has a partial ____ charge and accepts a ____ charge
- is a weak lewis ____
- is a hydrogen bond ____

A
  • positive; negative
  • acid
  • donor
24
Q

within a strong intermolecular force is it ….
- harder/easier to separate molecules during phase transitions
- higher/lower melting point
- higher/lower boiling point
- greater/smaller viscosity
- higher/lower vapor pressure

A
  • harder
  • higher
  • higher
  • greater
  • lower
25
what is the formula for calculating the formal charge of an atom?
FC = V - 1/2B - L V= # of valence electrons B= # of bonding electrons L= # of lone paired electrons
26
what is an ionic solid? - are they strong/ weak?
held together by interactions between cations and anions - strong
27
what is a network solid? - are they strong/ weak?
atoms are connected by covalent bonds - strong
28
what is a metallic solid? - are they strong/ weak?
atoms are connected by covalent bonds and have sea of electrons called conduction electrons - vary in stength
29
what is a molecular solid? - are they strong/ weak?
held together by 3 types of intermolecular interactions: hydrogen bonding, dipole dipole forces, or LDF - weak
30
what periodic trend (or trends) increases from left to right and bottom to top?
ionization energy and electronegativity
31
what periodic trend increases as it goes from right to left and top to bottom?
atomic radius
32
what periodic trend is the same as that of atomic radius?
nuclear shielding
33
what periodic trend becomes more negative from left to right and bottom to top?
electron affinity
34
what are the following groups called in the periodic table? - group 1 - group 2 - group 7 - group 8
- alkali metals - alkaline earth metals - halogens - noble gases
35
in regard to lewis structures, - elements that are to the right of carbon on the PT.... - elements that are to the left of carbon on the PT....
- go by the octet rule - give away/ share their valence electrons
36
formal charge is helpful for knowing if a ____ is correct
lewis dot structure
37
most lewis dot structures will give you a ____ of zero on each element, but sometimes it is not ____
formal charge; possible
38
STUDY VSEPR CHART
STUDY VSEPR CHART