C6 - Global Challenges Flashcards
what are the 3 essential elements needed by plants
- nitrogen
- phosphorus
- potassium
> plants don’t grow well if these are limited
what are some symptoms of mineral deficiencies in plants
- poor growth
- discoloured leaves
what are fertilisers
- substances that replace the essential elements used by plants as they grow
what conditions must fertilisers be in, so that plant roots can easily absorb them
- ions in water soluble form
what ions are commonly found in fertilisers containing all 3 essential elements
- Nitrogen: nitrate ions (NO 3-) and ammonium ions (NH4+)
- Phosphorous: phosphate ions (PO4 3-)
- Potassium: potassium ions (K+)
what are NPK fertilisers
- fertilisers that provide all 3 essential elements in the form of water soluble compounds
what are some examples of NPK fertilisers
- ammonium nitrate NH4NO3
- ammonium sulfate (NH4)2 SO4
- ammonium phosphate (NH4)3 PO4
- potassium nitrate KNO3
name the raw materials needed to make ammonium sulfate
- sulfur (makes sulfuric acid)
- natural gas
- air (all 3 make ammonia)
- water
> ammonia + sulfuric acid —> ammonium sulfate
name the raw materials needed to make ammonium phosphate
- phosphate rock
- sulfur —–> phosphoric acid
- natural gas
- air —–> ammonia
- water
> ammonia + phosphoric acid —> ammonium phosphate
how can potassium sulfate be made in the lab
- pour dilute potassium hydroxide into conical flask + add phenolphthalein indicator
- add dilute sulfuric acid from a burette until neutralised
- add activated charcoal to remove indicator, then filter out to remove
- warm filtrate to leave crystals behinds (don’t heat to dryness)
how can ammonium sulfate be made in the lab
- pour dilute ammonia solution into conical flask + add methyl orange indicator
- add dilute sulfuric acid from burette until neutralised
- at the end-point add a little extra ammonia solution to ensure the reaction is complete
- add activated charcoal to remove indicator + filter to remove
- warm the filtrate leaving crystals behind (don’t heat to dryness)
what is a batch process
- when you make a small amount of substance at a time and once it’s made you stop the reaction
what is a continuous process
- when large amounts of substances are made and go on continuously without the reaction being stopped
what is the Haber Process
- produces ammonia from nitrogen and hydrogen
what is the equation for the Haber process
Ns(g) + 3H2(g) <—–> 2NH3(g)
what conditions are used to carry out the Haber Process
- temp of 450 degrees Celsius
- pressure of 200 atmospheres (20 MPa)
- iron catalyst
why is the pressure in Haber process considered to be a compromise
- it’s high enough to produce a reasonable equilibrium yield
> as equilibrium shifts to the right side because there’s less moles of gas so more product - however it’s not too high for it to be hazardous and expensive
why is the temperature in Haber process considered to be a compromise
- it’s low enough for a reasonable equilibrium yield
> because forward reaction is exothermic so to counteract equilibrium shifts to the left, decreasing ammonia yield - however it’s high enough for a reasonable rate of reaction + for the catalyst to work efficiently
what are the raw materials for the Haber Process
- natural gas
- air
- steam
how is nitrogen manufactured to be used in the Haber process
- nitrogen is manufactured by the fractional distillation of liquefied air
> air is 78% nitrogen
how is hydrogen manufactured to be used in the Haber Process
- hydrogen is manufactured by reacting natural gas (mostly methane) with steam
what other conditions are chosen for Haber process
- liquefying ammonia (letting gas cool + turn to liquid)
> conc of NH3 decrease so to counteract equilibrium shifts to right to increase NH3 yield - recycling the unreacted hydrogen + nitrogen
- both of these improves the yield to around 97%
what is the contact process
- an important process in the formation of sulfuric acid
what is sulfuric acid used for
- making fertilisers
- oil refining
- metal extraction
- making paints + polymers