Carbohydrates Flashcards

(50 cards)

1
Q

What is a polymer

A

Long molecule consorting of monomers

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2
Q

List polymers

A

Carbohydrates
Proteins
Nucleic acids

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3
Q

How are monomers made from polymers

A

Polymers ate dissembled to monomers by hydrolysis

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4
Q

How are polymers made from monomers

A

Dehydration reaction
2 monomers bind tighter through the loss of a water molecule

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5
Q

Monosaccharides

A

the simplest carbohydrates, small, monomeric molecules

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6
Q

Oligosaccharide

A

only a few monomer units are involved

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7
Q

Polysaccharide

A

long polymers of monosaccharides

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8
Q

What is maltose made of

A

Glucose ans glucose

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9
Q

Formula of monosaccharides

A

(CH2O)n

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10
Q

How are monosaccharides categorised

A

-location of the carbonyl group
-number of carbons in the skeleton

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11
Q

Trioses

A

Aldehyde such as glyceraldehyde
Ketone such as dihydorxyacetone

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12
Q

Aldose-ketone interconversion

A

Addition of water to form an endiol
Addition of another water molecule

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13
Q

Examples of pentoses

A

Aldose such as ribose
Ketose such as ribulose

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14
Q

Examples of hexoses

A

Aldoses such as glucose or galactose
Ketose such as fructose

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15
Q

Enantiomers of glyceraldehyde

A

-D-glyceraldehyde which has an oh on the right and L glyceraldehyde that has the oh on the left
-they are mirror images hence called enantiomers
-middle carbon is a chiral carbon

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16
Q

Enantiomers of glucose

A

D glucose (oh on the right)
L glucose(oh on the left)

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17
Q

Structure of alpha glucose

A

Draw it

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18
Q

Differences between alpha and beta glucose

A

In alpha the oh on carbon one is at the bottom

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19
Q

Examples of phosphate esters of monosaccharides

A

B-d-glucose-1-phosphate
D-glyceraldehyde-3- phosphate
B-d-glucose-6-phosphate
A-d-fructose-6-phosphate

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20
Q

Abbreviations of glucose

A

Glc

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21
Q

Abbreviation of glucosamine

22
Q

Abbreviation of N-acetylglucosamine

23
Q

Abbreviations of galactose

24
Q

Abbreviation of Galactosamine

25
Abbreviation of N-acetylgalactosamine
GalNAc
26
Abbreviation of gluconic acid
GlcA
27
Abbreviation of N-acetylneuraminic acid (sialic acid)
NeuNAc
28
Role of trioses
The 3-phosphate is an intermediate in glycolysis The 1-phosphate is an intermediate in glycolysis
29
Role of pentoses
Constituent of ribonucleic acid (RNA) Constituent of deoxyribonucleic acid (DNA)
30
Role of hexoses
A major energy source for animal metabolism; structural role in cellulose As part of lactose (milk); structural polysaccharides A major plant sugar; part of sucrose; intermediate in glycolysis
31
How is maltose formed
Removal of water between two molecules of alpha glucose and the formation of glycosidic bond
32
How is sucrose formed
Removal of water between glucose and fructose forming a glycosidic bond
33
Examples of Polysaccharides
Starch Glycogen
34
Starch
astoragepolysaccharideofplants,consists entirely of glucose monomers
35
Glycogen
a storage polysaccharide in animals
36
What monomer is found in cellulose
Beta glucose
37
Bonds in amylose
1-4 glycosidic bonds
38
Bonds in cellulose
1-4 glycosidic bonds
39
Structure of starch
-found in plastids -amyloses is unbranched -amylopectin is branched
40
Structure of glycogen
-extensively branched
41
Role of Amylase
-Amylase is an enzyme that breakdown starch (amylose and amylopectin) into disaccharides and trisaccharides. -Amylases act on α-1,4-glycosidic bonds.
42
Structure of cellulose
-beta glucose monomers -microfibrils which provide strength in lathe number -many weak hydrogen bonds which provide strength and rigidity
43
What is chitin
-found in the exoskeleton of arthropods and is used in medicine for surgical thread as it decomposes
44
Hyaluronic acid
It is a structural component in cartilage and is present synovial fluid of joints and in the vitreous humour of the eye.
45
What can polysaccharides play a vital role in
Cell recognition as they act as cell markers
46
Function of carbohydrates
▪ Energy storage and generation (starch, glycogen) ▪ Biological structural materials (cellulose, chitin, etc) ▪ Polysaccharide on cell surface or attached to proteins aid in molecular recognition
47
Gram staining test
Gram-positive organisms have a thicker peptidoglycan cell wall compared with gram- negative bacteria. It is a 20 to 80 nm thick polymer while the peptidoglycan layer of the gram-negative cell wall is 2 to 3 nm thick and covered with an outer lipid bilayer membrane.
48
Function of polysaccharides
-strengthens plant cell walls -stores glucose for energy -strengthens exoskeletons and fungal cell walls
49
What is found in bovine cartilage
Proteoglycan
50
Role of heparin
Anti cougalant