carbohydrates Flashcards

(55 cards)

1
Q

What are the most abundant class of bioorganic molecules on Earth?

A

Carbohydrates

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2
Q

What is a vital energy source for the cell and provides structural support?

A

Carbohydrates

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3
Q

What is the stoichiometric formula for carbohydrates?

A

(CH2O)n

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4
Q

What is the ratio of carbon to hydrogen to oxygen in carbohydrates?

A

1:2:1

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5
Q

How are carbohydrates classified?

A

Monosaccharides, disaccharides, polysaccharides.

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6
Q

What are carbohydrates also called?

A

Saccharides

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7
Q

What are the uses of carbohydrates?

A
  • Yield energy (ATP) to drive metabolic processes
  • Energy-storage molecules
  • Structural
  • Carbohydrate derivatives found in coenzymes (FAD) and nucleic acids
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8
Q

What are examples of energy-storage molecules?

A

Glycogen, starch

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9
Q

How can carbohydrates be classified?

A

By the number of monomers they contain

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10
Q

What are the classifications of carbohydrates?

A

Monosaccharides, oligosaccharides, polysaccharides, glycoconjugates.

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11
Q

What is a monosaccharide?

A

(CH2O)n where n = 3-6; one sugar molecule

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12
Q

What are oligosaccharides?

A

Polymers from 2-20

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13
Q

What are polysaccharides?

A

Polymers of greater than 20 sugar residues

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14
Q

What are glycoconjugates?

A

Derivatives; attached to proteins, lipids, peptide chains

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15
Q

What are monosaccharides also known as?

A

Polyhydroxy aldehydes or ketones

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16
Q

How are monosaccharides classified?

A

Based upon the type of carbonyl group

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17
Q

What is an aldose?

A

Sugar with aldehyde group

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18
Q

What is a ketose?

A

Sugar with ketone group

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19
Q

What process do both aldoses and ketoses engage in?

A

Intramolecular cyclization

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20
Q

What is formed when alcohol reacts with aldehyde?

A

Hemiacetal

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21
Q

What is formed when alcohol reacts with ketone?

A

Hemiketal

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22
Q

What can both 5 and 6 carbon monosaccharides form?

A

Hemiacetals

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23
Q

What are 5 membered hemiacetals called?

24
Q

What are 6 membered hemiacetals called?

25
What are monosaccharides (aldoses) with 3 carbons called?
Aldotriose
26
What are monosaccharides (aldoses) with 4 carbons called?
Aldotetroses
27
What are monosaccharides (aldoses) with 5 carbons called?
Aldopentoses
28
What are monosaccharides (aldoses) with 6 carbons called?
Aldohexoses
29
What is the most oxidized carbon in a monosaccharide called?
Anomeric carbon
30
C-1; attached to 2 oxygen atoms
anomeric carbon
31
What configurations can the anomeric carbon adopt?
a - OH group down; b - OH group up
32
Two monosaccharides joined by a covalent bond called a glycosidic linkage via a condensation reaction
disaccharides
33
a disaccharide is two monosaccharides joined by a ??? bond called a ??? linkage via a ???reaction
covalent; glycosidic; condensation
34
What is the bond created between in disaccharides?
C1 of one sugar and -OH of another
35
What is maltose also known as?
α-D-glucopyranosyl-(1,4)-β-D-glucopyranose
36
What is the plant polysaccharide?
Cellobiose
37
What is lactose composed of?
Galactose and glucose in β-glycosidic bond
38
What is formed when 2 glucose molecules are joined by α-glycosidic bond?
Maltose
39
What is formed when 2 glucose units are joined by β-glycosidic bond?
Cellobiose
40
What is the major carbohydrate in milk?
Lactose
41
What is sucrose composed of?
Glucose and fructose in 1-2 linkage
42
What is table sugar?
Sucrose
43
What bonds are between two sugars?
Glycosidic
44
What configurations can glycosidic bonds have?
a or b
45
glycosidic bonds can be linked through what linkages?
1-2 1-4 1-6
46
aldehyde group
CHO
47
What types of polysaccharides are composed of one monosaccharide?
Homoglycans
48
What types of polysaccharides are made of more than one type of monosaccharide?
Heteroglycans
49
What are examples of energy storage roles of polysaccharides?
- Starch (a-amylose and amylopectin) - Glycogen
50
What are examples of structural roles of polysaccharides?
- Cellulose - Chitin
51
What are the biological roles of polysaccharides?
- Energy storage - Structural - Glycosaminoglycans - Proteoglycans
52
What is a mixture of amylose and amylopectin?
Starch
53
Unbranched polymer of 100-1000 D-glucose in α 1-4 glycosidic bond
amylose
54
Branched polymer of α 1-4 and α 1-6 glycosidic bond
amylopectin
55
What is α-amylase?
An endoglycosidase found in human saliva but also in plants that randomly hydrolyzes the α 1-4 bond of amylose and amylopectin