carbohydrates Flashcards

(37 cards)

1
Q

What is raffinose ?

A

trisaccharide : galactose, glucose and fructose

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2
Q

What is stachyose ?

A

glucose, fructose and two galactose

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3
Q

When you want to make a caramel flavor, you use a ___ solution

A

sucrose

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4
Q

When you want to make a caramel color, you use a ___ solution

A

glucose

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5
Q

2 aminoketones will give a ___

A

pyrazine

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6
Q

the more a sugar is ____ the more it will be sweet

A

soluble

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7
Q

how can you mix prevent the crystallization

A

mix the sugars

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8
Q

****what can you do if you want to minimize the browning you use ____ in your maillard reaction

A

sucrose

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9
Q

T or F : the sugar alcohol are more sweet than sucrose or glucose

A

false, they are less sweet

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10
Q

what is the only sugar alcohol with a sweetness comparable to sucrose

A

xylitol

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11
Q

the ____ is hydrogenated to form xylitol

A

xylose

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12
Q

___ is the polymer of xylose

A

xylan

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13
Q

In amylopectine, every ____ glucoses molecules, there will be a a glucose that has two glycosidic bonds (one in the 1-4 and one in the 1-6)

A

12-20

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14
Q

____ (starch) is more soluble in water

A

amylopectin

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15
Q

Loss of granular integrity generally occurs between _____ gelatinization temperature is a function of the starch source.

A

60˚C and 70˚C

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16
Q

why is the invert sugar called inverted sugar

A

because of the rotation of the solution from +66 to -39˚C.

17
Q

What is the general formula of carbohydrates

18
Q

What are the two optical isomers of glucose

A

glucose-D and L-glucose

19
Q

what is the only carbon at which isomers are not considered to be different sugars ?

A

the n-1 carbon

20
Q

fructose has a hemiketal or a hemiacetal

21
Q

glucose has a hemiketal or a hemiacetal?

22
Q

T or F : in the pyranose form, the fructose has a hemiacetal

23
Q

Beta and alpha glucose are two ____

24
Q

the crystaline form of thre sugars is always ____

25
In solutions, there is a dynamic equilibrium between ___ \_\_\_and \_\_
alpha, beta, open chain.
26
the alpha-glucopyranose has an optical roation of \_\_\_\_\_
112˚
27
the beta glucopyranose has an optical rotation of \_\_\_\_
19˚
28
the active aldehyde form is the _____ form
open-chain
29
T or F : all aldehydes are reducing sugars
true, because they have a free ketone or a free aldehyde
30
What is the most common test of reducing sugars
the fehling's test (cuII in copper tartate (blue) to cuI oxide (red))
31
What are the two ways water can be eliminated from a sugar molecule
1. by forming a glycosidic bond with another sugar (random polymerization) 2. Elimination of water from within a sugar molecule leading to unsaturated molecule.
32
how many water molecules are lost to make HMF
3
33
what is the key intermidiate in the following reactions : Caramelization Maillard Reaction
Caramelization : HMF Maillard reaction : amadori compound
34
How are sugar alcohol produced?
produced by reducing the aldehyde group by an hydroxyl group (hydrogenation).
35
what is the effect of the presence of sugars in the gel formation
retard the gel formation and retrogradation because they compete for available water and interfere with starch to starch.
36
surfactants forms complex with starch, it is more noticeable for \_\_\_\_\_
amylose
37