Carbon Cycle Flashcards
carbon stores
function as sources (adding carbon to the atmosphere) and sinks (removing carbon from the atmosphere)
Carbon exists in different forms, depending on the store:
atmosphere: as carbon dioxide and carbon compounds, such as methane
hydrosphere: dissolved carbon dioxide
lithosphere: as carbonate in limestones, chalk and fossil fuels, as pure carbon in graphite and diamonds
biosphere: as carbon atoms in living and dead organisms
These stores vary in size, capacity and locations. The biosphere contains both terrestrial and oceanic locations
Fluxes
movements of carbon from one store to another; provide the motion in the carbon cycle
Carbon fluxes between the carbon stores of the carbon cycle are measured in either petagrams or gigatonnes of carbon per year. The major fluxes are between the oceans and the atmosphere, and between the land and atmosphere via the biological processes of photosynthesis and respiration. These fluxes vary not only in terms of flow but also on different timescales.
Formation of sedentary rocks
Sediment is deposited in layers in a low-energy environment
E.g. lake
E.g. sea bed
Further layers are deposited and sediment undergoes diagenesis
Diagenesis - /ˌdʌɪəˈdʒɛnɪsɪs/ - the physical and chemical changes that occur during the conversion of sediment to sedimentary rock
The lower layers become compressed and chemical reactions cement particles together
The conversion of loose, unconsolidated sediment into solid rock is known as lithification.
Limestone
Composed of calcium carbonate, and is 40% carbon by weight
80% of lithospheric carbon is found in limestones
Limestone is formed when calcium carbonate is deposited on the ocean floor.
2 ways rocks can be formed
There are two types of ways:
limestone formed in the oceans
The Himalayas form one of the Earth’s largest carbon stores. This is because the mountains started life as ocean sediments rich in calcium carbonate derived from crustaceans, corals and plankton. Since these sediments have been upfolded, the carbon they contained has been weathered, eroded and transported back to the oceans.
carbon derived from plants and animals in shale, coal and other rocks
these rocks were made up to 300 million years ago from the remains of organisms. These remains sank to the bottom of rivers, lakes and seas and were subsequently covered by silt and mud. As a consequence, the remains continued to decay anaerobically and were compressed by further accumulations of dead organisms and sediment. The subsequent burning of these fossil fuels has released the large amounts of carbon they contained back into the atmosphere.
3 types of carbon pump
biological pumps
physical pumps
carbonate pumps
biological pumps
Biological pumps
These move carbon dioxide from the ocean surface to marine plants called phytoplankton through photosynthesis. Phytoplankton are microscopic plants and plant-like organisms drifting or floating in the sea/freshwater along with diatoms, protozoa and small crustaceans.
This effectively converts carbon dioxide into food for zooplantic (microscopic animals) and their predators.
Most of the carbon dioxide taken up by phytoplankton is recycled near the surface. About 30% sinks into deaper waters before being converted back into carbon dioxide by marine bacteria.
Physical pumps
Physical pumps
These move carbon compounds to different parts of the ocean in downwelling and upwelling currents
Downwelling occurs in parts of the ocean where cold, denser water sinks.
These currents bring dissolved bring dissolved carbon dioxide down to the deep ocean.
Once there, it moves in slow-moving deep ocean currents, staying there for hundreds of years.
Eventually, these deep ocean currents, part of the thermohaline. circulation, return to the surface by upwelling.
The cold deep ocean water warms as it rises towards the ocean surface and some of the dissolved carbon dioxide is released back into the atmosphere.
carbonate pumps
These form sediments from dead organisms that fall to the ocean floor, especially the hard outer shells and skeletons of fish, crustaceans and corals, all rich in calcium carbonate.
Terrestrial sequestering
Plants (primary producers in an ecosystem) sequester carbon out of the atmosphere during photosynthesis. In this way, carbon enters the food chains and nutrients cycles of terrestrial ecosystems.
When animals consume plant matter, the carbon sequestered in the plant becomes part of their fat and protein. Respiration, particularly by consumer animals, returns some of the carbon back to the atmosphere.
Waste from animals is eaten by micro-organisms (bacteria and fungi) and detritus feeders (e.g. beetles).
As a consequence, carbon becomes part of these creatures. When plants and animals die and their remains fall to the ground, carbon is released into the soil.
Carbon fluxes within ecosystems vary on two timescales:
Diurnally: during the day, fluxes are positive - from the atmosphere into the ecosystem. The reverse applies at night when respiration occurs but not photosynthesis.
Seasonally: during winter, carbon dioxide concentrations increase because of the low levels of plant growth. However, as soon as spring arrives and plants grow, these concentrations begin to decrease until the onset of autumn.
biological sequestering
All living organisms contain carbon; the human body is about 18% carbon by weight. In plants, carbon dioxide and water are combined to form simple sugars, i.e. carbohydrates. In animals, carbon is synthesised into complex compounds, such as fats, proteins and nucleic acids.
On land, soils are the largest carbon stores. Here, biological carbon is stored in the form of dead organic matter. This matter can be stored for decades or even centuries before being broken down by soil microbes (biological decomposition) and then either taken up by plants or released into the atmosphere.
Soils store between 20% and 30% of global carbon. They sequester about twice the quantity of carbon as the atmosphere and three times that of terrestrial vegetation. The actual amount of carbon stored in some soil depends on:
climate
this dictates the rates of plant growth and decomposition; both increase with temperature and rainfall
vegetation cover:
this affects the supply of dead organic matter, being heaviest in tropical rainforests and least in tundra.
soil type:
clay protects carbon from decomposition, so clay-rich soils have a higher carbon content
land use;
cultivation and other forms of soil disturbance increase the rate of carbon loss
Atmospheric carbon
A fully functioning and balanced carbon cycle is vital to the health of the Earth in sustaining its other systems. It plays a key role in regulating the Earth’s temperature by controlling the amount of carbon dioxide in the atmosphere. This, in turn, affects the hydrological cycle. Ecosystems, terrestrial and oceanic , also depend upon the carbon cycle. All this is a consequence of the fact that the carbon cycle provides the all-important link between the atmosphere, hydrosphere, lithosphere and biosphere. But the carbon balance is being increasingly altered by human actions.
greenhouse affect
It is the increasingly concentration of carbon in the atmosphere that is causing great concern. Carbon dioxide and methane are perhaps the most important of all the greenhouse gases (GHGs). Their increasing presence in the atmosphere in the atmosphere is upsetting the Earth’s natural temperature-control system, resulting in the greenhouse effect.
The greenhouse effect:
Incoming solar radiation 343 Watt per m²
Solar radiation passes through the clear atmosphere. Net incoming solar radiation: 240 Watt per m²
Solar energy is absorbed by the Earth’s surface and warms it. 168 Watt per m²
Some solar radiation is reflected by the atmosphere and Earth’s surface. Outgoing solar radiation: 103 Watt per m²
Some of the infrared radiation passes through the atmosphere and is lost in space. Net outgoing infrared radiation 240 Watt per m²
Some of the infrared radiation is absorbed and re-emitted by the greenhouse had molecules. The direct effect is the warming of the Earth’s surface and the troposphere.
Surface gains more heat and infrared radiation is emitted again.
and is converted into heat causing the emissions of longwave (infrared) radiation back to the atmosphere.
The Earth’s climate is driven by incoming short-wave solar radiation:
31% is reflected back into space by clouds, GHGs and by the land surface
the remaining 69% is absorbed at the Earth’s surface, especially by the oceans
much of this radiation absorbed at the surface is re-radiated as long wave radiation
large amounts of this long-wave radiation are, however, prevented from returning into space by clouds and GHGs
the trapped long-wave radiation is then re-radiated back to the Earth’s surface
Photosynthesis balancing carbon
Photosynthesis by terrestrial and oceanic organisms plays an essential role in keeping carbon dioxide levels relatively constant and thereby helping to regulate the Earth’s mean temperature.
The amount of photosynthesis varies spatially, particularly with net primary productivity (NPP). (This is the amount of organic matter that is available for humans and other animals to harvest or consume). NPP is highest in the warm and wet parts of the world, particularly in the tropical rainforests and in shallow ocean waters. It is least in the tundra and boreal forests.
Soil health balancing carbon
Soil health is an important aspect of ecosystems and a key element in the normal functioning of the carbon cycle. Soil health depends on the amount of organic carbon stored in the soil. The storage amount is determined by the balance between the soil’s inputs (plant and animals remains, nutrients) and its outputs (decomposition, erosion and uptake by plant and animal growth.)
Carbon is the main component of soil organic matter and helps to give soil its moisture-retention capacity, its structure and fertility. Organic carbon is concentrated in the surface layer of the soil. A healthy soil has a large surface reservoir of available nutrients which, in their turn, condition the productivity of ecosystems. All this explains why even a small amount of surface soil erosion can have such a devastating impact on soil health and fertility.
impacts of fossil fuel consumption on climate, ecosystems and the hydrological cycle
Implications for Climate
It is estimated that about half the extra emissions of carbon dioxide since 1750 have remained in the atmosphere. The rest have been fluxed from the atmosphere into the stores provided by the oceans, ecosystems and soils. The rate of carbon fluxing has sped up.
Additional carbon dioxide in the atmosphere and its impact on the greenhouse effect that is largely responsible for a number of climate changes:
a rise in the mean global temperature
more precipitation and evaporation
sudden shifts in weather patterns
more extreme weather events, such as floods, storm surges and droughts
the nature of climate change is varying from region to region - some areas are becoming warmer and drier and others wetter
Implications for Ecosystems
These changes in climate have serious knock-on effects on:
sea level: this is rising because of melting ice sheets and glaciers; many major coastal cities around the world are under threat from flooding by the sea
ecosystems: a decline in the goods and services they provide; a decline in biodiversity; changes in the distributions of species; marine organisms threatened by lower oxygen levels and ocean acidification; the bleaching of corals etc.
Implications for the Hydrological Cycle
increased temperatures and evaporation rates cause more moisture to circulate around the cycle.
Energy security in General
Energy security is achieved when there is an uninterrupted availability of energy at a national level and at an affordable price. All countries seek to achieve this; the most secure energy situation is where the national demand for energy can be completely satisfied by domestic sources. The more a country demands on imported energy, the more it is exposed to risks of an economic and geopolitical kind. Four key aspects of energy security are:
availability
accessibility
affordability - competitively priced energy supply
reliability - uninterrupted
The importance of energy security stems from the fact that energy is vital to the functioning of a country. For example, it: powers most forms of transport, lights settlements, is used by some types of commercial agriculture; warms/cools homes and powers domestic appliances; is vital to modern communications; drives most forms of manufacturing.
Consumption
The consumption of energy is measured in two ways:
in per capita terms, i.e. as kilogrammes of oil equivalent or megawatt hours per person. In general, this measure rises with economic development
by a measure known as energy intensity, which is assessed by calculating the units of energy used per unit GDP. The fewer the units of energy, the more efficiently a country is using its energy supply. In general, energy intensity values decrease with economic development
The energy mix
The energy mix is the combination of different energy sources used to meet a country’s total energy consumption. It’s an important part of energy security, and varies from country to country. There are distinctions between:
domestic and foreign sources
primary and secondary sources
primary = found in nature, not converted/transformed. It can be renewable (water/wind/sunlight) or non-renewable (coal/oil/gas)
secondary = derived from transformation of conversion of primary sources, usually more convenient (electricity)
Factors affecting energy consumption
Factors affecting per capita energy consumption:
physical availability
cost
standard of living
environmental priorities (of governments)
for some, energy policy will be taking the cheapest route to meeting the nation’s energy needs, regardless of the environmental costs. Others will seek to increase their reliance on renewable sources of energy; wile still other will have in place policies that raise energy efficiency and energy saving
climate
Very high levels of consumption in North America, the Middle East and Australia reflect the extra energy needed to make the extremes of heat and cold more comfortable (at home, at work and in public places)
public perception
for some consumers, energy is perceived almost as a human right and therefore to be used with little or no regard for the environmental consequences. Others give priority to minimising the wastage of energy and maximising security
economic development
technology
Energy players
TNCs
The big names in the oil and gas business include Gazprom, ExxonMobil, PetroChina and Royal Dutch Shell. Nearly half of the top 20 companies are state-owned (all or in part) and, therefore, very much under government control. Because of this, strictly speaking they are not TNCs. Most are involved in a range of operations: exploring, extracting, transporting, refining and producing petrochemicals.
Organisation of the Petroleum Exporting Companies
OPEC has 14 member countries*, which between them own about two-thirds of the world’s oil reserves. Because of this, it is in a position to control the amount of oil and gas entering the global market, as well as the prices of both commodities. OPEC has been accused of holding back production in order to drive up oil and gas prices.
*Qatar left in January 2019
Energy Companies
Important here are the companies that convert primary energy (oil, gas, water, nuclear) into electricity and then distribute it. Most companies are involved in the distribution of both gas and electricity. They have considerable influence when it comes to setting consumer prices and tariffs.
Consumers
An all-embracing term, but probably the most influential consumers are transport, industry and domestic users. Consumers are largely passive players when it comes to fixing energy prices.
Governments
They can play a number of different roles; guardians of national energy security and can influence the sourcing of energy for geopolitical reasons.
Mismatch between supply and demand
Coal
Oil
Supply
31% Middle East
20% North America
12% Russia
Demand
34% Asia (12% China)
24% North America
20% Europe (4% Russia)
There is a large mismatch between supply and demand because oil is essential for transport. Petrol/diesel is the main energy source for cars, rail, ships and aircraft.)
Gas
Supply
18% North America
15% Middle East
13% Russia
Demand
27% North America (22% USA)
16% Asia
11% Russia
10% Middle East
Energy pathways- Russia-Europe
Energy pathways are a key aspect of energy security but can be prone to disruption, especially as conventional fossil fuels have to be moved over long distances from sources to markets. Russia is currently the second largest producer of gas. Most of its gas exports go to European countries (Germany, Italy, UK, France, Spain). Russian gas is delivered to Europe mainly through five pipelines:
Countries getting 100% of gas from Russia:
Finland
Estonia
Latvia
Lithuania
66-99%
Bulgaria, Poland, Czech Republic, Slovakia
Geopolitically significant is that three of those pipelines cross Ukraine, a country from which Russia annexed Crimea in 2014. It now occupies parts of eastern Ukraine. Clearly, Ukraine might be in a position of strength here, it could increase the charges for allowing Russian gas to pass through it. It could even stop the gas flows altogether. This potential threat seems to leave Russia with two options:
reduce delivery of gas through these threatened pipelines and export more through two northern pipelines that run through Finland and Poland
annexe the whole of Ukraine
Given the history of strained political relations between Russia and Western Europe, it would appear strategically unwise for EU countries to become heavily reliant on Russian gas. Although the UK still obtains most of its gas from Qatar, it has recently substantially increased its imports of Russian gas in order to offset the declining output of gas from its North Sea gas fields.
Unconventional fossil fuels
Tar Sands
A mixture of clay, sand, water and bitumen (a heavy, viscous oil)
Tar sands have to be mined and then injected with steam to make the tar less viscous so that it can be pumped out.
Oil Shale
Oil-bearing rocks that are permeable enough to allow the oil to be pumped out directly.
Either mined, or shale is ignited so that the light oil fractions can be pumped out.
Shale gas
Natural gas that is trapped in fine-grained sedimentary rocks.
Extracted by fracking: pumping in water and chemicals forces out the gas.
Deepwater oil
Oil and gas that is found well offshore and at considerable oceanic depths.
Drilling takes place from ocean rigs; already underway in the Gulf of Mexico and off Brazil.
Social costs and benifits for the carbon cycle
Social costs and benefits, implications for the carbon cycle, and consequences for the resilience of fragile environments.
It is important to note that exploitation of these unconventional sources has a downside:
they are all fossil fuels, so their use will continue to threaten the carbon cycle and contribute to global warming
extraction is costly and requires a high input of complex technology, energy and water
they all threaten environmental damage, from the scars of opencast mines and land subsidence to the pollution of groundwater and oil spills. Certainly, the resilience of fragile environments will be sorely tested.
this leads to social costs
However, there may also be social benefits, such as energy companies investing in improving local infrastructure in return.
Renewable energy
The global drive to reduce carbon dioxide emissions must involve increasing reliance on alternative sources of ‘clean’ energy, so decoupling economic growth from dependence on fossil fuels. Basically, this means widening the energy mix to include substantial inputs from both renewable and recyclable energy sources.
The main sources of renewable energy today are hydro, wind, solar, geothermal and tidal. The contribution made by these sources to the national energy budget varies from country to country.
Not all countries have renewable energy to exploit for geographic reasons:
not all countries have coasts, strongly flowing rivers or climates with either long sunshine hours or persistently strong winds
Partly because of this, there are very few, if any, countries where renewables might completely replace all the energy derived from fossil fuels.
Other factors reinforcing this include:
the relative financial costs of using non-renewable and renewable energy sources. When oil and gas prices are low, renewables become a more expensive option.
the harnessing of renewables is not without environmental costs. River valleys have to be drowned to create HEP reservoirs, and large areas of land/the offshore zone are covered by solar or wind farms.
While the majority of people believe that we should make greater use of renewable sources, most suddenly go off the idea when constructing a wind or solar farm near them is proposed (NIMBYism)