CC16 - fuels Flashcards

(44 cards)

1
Q

what is a hydrocarbon

A

a compound of only hydrogen and carbon

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2
Q

what is crude oil

A

natural resource a complex mixture of hydrocarbons
an important source of fuel and feedstock for petrochemical industry

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3
Q

why is crude oil a finite resource

A

takes so long to make it is being used faster than made and will one day run out

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4
Q

where does crude oil come from

A

formed underground at high temp and pressure over millions of years from plant and animal remains

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5
Q

what is crude oil made up of

A

lots of different hydrocarbons of different lengths

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6
Q

what can crude oil be separated into

A

fractions: simpler more useful mixtures containing hydrocarbons of similar lengths

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7
Q

what are the fractions of crude oil

A
  • gases
  • petrol
  • kerosene
  • diesel
  • fuel oil
  • bitumen
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8
Q

what is feedstock

A

raw materials

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9
Q

how are the fractions in crude oil separated

A

fractional distillation:
shorter hydrocarbons have lower boiling separate near top of column where it is cooler and vise versa

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10
Q

what are gases used for

A

domestic heating and cooking

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11
Q

what is petrol used for

A

fuel in cars

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12
Q

what is kerosene used for

A

fuel in planes

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13
Q

what is diesel used for

A

fuel in some cars and larger vehicles such as trains

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14
Q

what is fuel oil used for

A

fuel for large ships and some powerstations

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15
Q

what is bitumen used for

A

surface roads and roofs

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16
Q

what do the physical properties of crude oil depend on

A

how big the hydrocarbons in the fraction are

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17
Q

how does boiling point change in fractions of hydrocarbons

A

increases as hydrocarbon chains get longer. shorter chain have weaker intermolecular forces of attraction

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18
Q

how does ignition change in fractions of hydrocarbons

A

shorter chain hydrocarbons ignite easier

19
Q

how does viscosity change in fractions of hydrocarbons

A

longer chain hydrocarbons are more viscous

20
Q

how does colour change in fractions of hydrocarbons

A

longer chain hydrocarbons tend to be darker in colour

21
Q

how many bonds does a carbon atom form

22
Q

how many bonds does a hydrogen atom form

23
Q

what is an alkane

A

single covalent bond between all carbon atoms (saturated)
formula: C(n)C(2n+2)

24
Q

what is an alkene

A

have atleast one double covalent bond between carbon atoms (unsaturated)
formula: C(n)H(2n)

25
what is a homologous series
a series of compound that: - same general formula - differ by CH2 of neighbouring compounds - similar chemical properties - gradual variation of physical properties
26
what do oil fractions mostly contain
alkanes
27
what is complete combustion
reaction between hydrocarbon and O2 when theres a plentiful supply of oxygen is an exothermic reaction
28
general formula for complete combustion
hydrocarbon + oxygen ----> carbon dioxide + water
29
when does incomplete combustion occur
limited supply of oxygen (in appliances such as boilers)
30
products of incomplete combustion
water, carbon dioxide, carbon monoxide, carbon (less O2)
31
problems of carbon monoxide
- colourless, odorless gas - binds to haemoglobin in RBC limiting O2 in blood stream - result in fainting, coma, even death
32
problems of carbon (incomplete combustion)
soot: blacken buildings, clog pipes, reduce air quality, cause breathing problems
33
acid rain
- sulfur impurities in hydrocarbons oxidise and form sulfur dioxide when burnt - sulfur dioxide dissolves in water in clouds sulfuric acid that falls as acid rain
34
effects of acid rain
- corrodes metal and limestone weakening buildings - damages crops, plants and trees - kills fish (rivers and lakes too acidic to survive) and insects
35
oxides of nitrogen
- nitrogen and O2 from air react under high temperatures in car engines
36
effects of oxides of nitrogen
harmful pollutants cause photochemical smog air pollution: difficulty breathing, headaches
37
advantages of using hydrogen as a fuel
- only waste product is water - renewable (obtained from water)
38
disadvantages of using hydrogen as a fuel
- hard to store - not widley avaliable - expensive to manufacture - special, expensive engine required
39
what is cracking
taking a long chain hydrocarbon (alkane) and breaking it down into shorter more useful hydrocarbons (alkane and alkene)
40
what are the two types of cracking
thermal and catalytic
41
what is catalytic cracking
- use high temp and a catalyst - catalyst speeds up the reaction - covalent bonds break and reform
42
why are alkenes useful
- used to make polymers - used as a starting material for useful chemicals - useful as feedstock for petrochemical industry
43
thermal cracking
- uses high temperatures of up to 750°c
44
reasons for cracking
- shorter chain hydrocarbons more useful and in higher demand but in less supply - longer chain hydrocarbon that there are more of in less demand can be cracked to meet supply of shorter chain hydrocarbons