Ch. 1: some important things to remember Flashcards

(35 cards)

1
Q

organic compounds

A

compounds that contain carbon

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2
Q

atomic number

A

number of protons in the nucleus

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3
Q

mass number

A

protons + neutrons

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4
Q

isotopes

A

same atomic number, but different mass numbers

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5
Q

atomic weight

A

average mass of the atoms in the element

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6
Q

molecular weight

A

sum of the atomic weights off all the atoms in the molecule

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7
Q

what does an atomic orbital tell us?

A

the volume of space around the nucleus where an electron is most likely to be found

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8
Q

minimum energy corresponds to….

A

maximum stability

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9
Q

an atom is most stable if…

A

its outer shell is either filled or contains 8 electrons

if it has no electrons of higher energy

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10
Q

EN is a measure of

A

the ability of an atom to pull its bonding electrons toward itself

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11
Q

electronic configuration describes…

A

the atomic orbitals occupied by the atom’s electrons

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12
Q

a proton is a …..
a hydride ion is…

A

positively charged hydrogen ion

negatively charged hydrogen ion

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13
Q

ionic bond

A

attraction between ions with opposite charges

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14
Q

covalent bond

A

two atoms share a pair of electrons

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15
Q

polar covalent bond

A

covalent bond between atoms with different EN

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16
Q

dipole

A

positive end and a negative end

17
Q

formal charge formula

A

FC = # valence electrons - # of electrons the atom has to itself (lone pair electrons and one half of the bonding electrons)

18
Q

lewis structures show…

A
  • which atoms are bonded
    -lone pairs
    -formal charges
19
Q

when the atom is neutral, how many bonds do C, N, O and H form?

20
Q

carbocation has a

A

positively charged carbon

21
Q

carboanion has a

A

negatively charged carbon

22
Q

sigma bonds

A

single bonds in organic compounds

23
Q

pi bonds

A

side to side overlap of parallel p orbitals

24
Q

bond strength is measured by

A

bond dissociation energy

25
a ___ bond is stronger than a __ bond
sigma, pi
26
how does carbon form four bonds?
it promotes an electron from an s orbital to an empty p orbital
27
__, __, __ ad halogens form bonds using ...
C, N, O; hybrid orbitals
28
no pi bonds =
sp3 hybridized
29
one pi bond =
sp2 hybridized
30
two pi bonds =
sp hybridized
31
a double bond consists of
one sigma bond and one pi bond
32
a triple bond consists of
one sigma bond and two pi bonds
33
the greater the electron density in the region of orbital overlap...
the stronger and shorter the bond
34
shorter bond =
stronger bond
35