Ch. 10 Gases Flashcards

(44 cards)

1
Q

Gases assume both the ____ and _____ if it’s container.

A

Shape and volume

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2
Q

Gases form _____ mixtures with one another in any proportion.

A

Homogeneous

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3
Q

The densities of gases are ____ than liquids and solids and are highly ____ depending on temperature and pressure.

A

Smaller

Variable

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4
Q

This is the force applied per unit area.

A

Pressure

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5
Q

What is the formula for pressure?

A

P=Force/area

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6
Q

What is the SI unit of force?

A

Newton (N)

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7
Q

What is the SI unit for pressure?

A

Pascal (Pa)

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8
Q
1 standard atmosphere is \_\_\_\_\_ Pa
1 standard atmosphere is \_\_\_\_ atm
1 atm=\_\_\_\_\_ mmHg
         =\_\_\_\_\_ torr
         =\_\_\_\_\_ bar
A
101,325 Pa
1 atm
760 mmHg
760 torr
1.01325 bar
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9
Q

This is pressure at seas level.

A

Standard atmosphere (atm)

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10
Q

This is barometer measurement.

A

mmHg

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11
Q

This is the name given to mmHg in honor of Torricelli the inventor of the barometer.

A

Torr

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12
Q

Same order of magnitude of atm but a decimal multiple of Pa.

A

Bar

1 bar = 1x10^5 Pa

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13
Q

A column of air with an are of 1 cm^2 has a mass of about ____.

A

1 kg

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14
Q

This is an instrument used to measure atmospheric pressure. It can be constructed with any dimensions because pressure is defined as force per area.

A

Barometer

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15
Q

This was originally defined as the pressure that would support a column of mercury exactly 760 mm high at 0 Celsius at sea level.

A

Standard atmospheric pressure

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16
Q

The pressure exerted by a column of fluid is given by:

A

P=hdg
H- height of column of fluid
D- density of fluid kg/m^3
G- acceleration due to gravity m/s^2

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17
Q

This is a device used to measure pressures other than atmospheric pressure.

A

Manometer

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18
Q

The physical state of a gas sample can be described by what 4 parameters?

A
  1. Pressure (P)
  2. Temperature (T, in kelvin)
  3. Volume (V)
  4. Number of miles of gas (n)
19
Q

If three of the four parameters are known the forth can be calculated using what?

A

Empirical gas laws.

20
Q

What are the 4 empirical gas laws?

A

Boyle’s Law
Charles and Gay Lussacs Law
Avogadro Law
The combined gas law

21
Q

The pressure volume relationship at constant n and T.

A

Boyle’s Law

22
Q

What is the formula for Boyle’s Law?

A

P1V1=P2V2

At constant n and T

23
Q

This is temperature- volume relationship at constant P and n.

A

Charles and Gay Lussacs Law

24
Q

What is the formula for Charles and Gays Law?

A

V1/T1=V2/T2
At constant n and P
Temps in kelvin

25
This is the amount volume relationship.
Avogadro Law
26
What is the formula for Avogadros Law?
V1/n1=kA=V2/n2
27
This is the pressure-temperature-amount-volume relationship.
Combined Gas Law
28
What is the formula for the Combined Gas Law?
PV/nT= constant P1V1/n1T1=P2V2/n2T2 P1V1/T1=P2V2/T2 for fixed amount of gas
29
The volume of onemore of an ideal gas at 0 degrees Celsius and 1 atm are conditions known as?
Standard temperature and pressure.
30
What is the calculation of standard temperature and pressure?
V=nRT/P V= (1mol)(.0821 L*atm/K*mol)(273.15K)/1atm =22.42L
31
In calculating the required volume of a gaseous reactant at constant pressure and temperature you should invoke what? The coefficients are used as?
Avogadros Law | Volumes
32
n=Px(V/RT) is used in determining the amount of reactant consumed using change in pressure. This can only be used when?
If there is a gaseous reactant and not a gaseous product.
33
Using a combination of stoichiometry and the _____ _____ ____, we can calculate the volume of gas that we expect to be produced in a chemical reaction.
Ideal gas equation
34
This law states that the total pressure exerted by a gas mixture is the sum of the partial pressures exerted by each component of the mixture.
Dalton’s law of partial pressure
35
Which law do you use to solve for Dalton’s partial pressures?
Ideal gas law to find each partial pressure
36
The mole fraction of a mixtures component is always ____ than 1.
Less
37
The sum of mole fractions for all components of a mixture is always _____.
1
38
The mole fraction is ______.
Dimensionless
39
The partial pressure of water is also called?
The vapor pressure of water.
40
Vapor pressure increases as _____ increases.
Temperature
41
The explains how the molecular nature of gases give rise to their macroscopic properties.
Kinetic molecular theory
42
The basic assumptions of the kinetic molecular theory are?
1. Gas is composed of particles that are separated by relatively large distances. The volume occupied by individual molecules is negligible. Gas particles are point masses. 2. Has molecules are constantly in random motion, moving in straight paths, colliding with the walls of their container and with one another in perfectly elastic collisions. Energy is transferred but not lost in the collisions. Collisions of the particles with the container walls are the cause of the pressure exerted by the gas. 3. Has molecules do not exert attractive or repulsive forces on one another. 4. The average kinetic energy of gas molecules in a sample is proportional to the absolute temperature.
43
Velocity is a vector and has both ____ and ____.
Magnitude and direction
44
Gases are ____because molecules in the gas phase are separated by large distances and can be moved closer together by decreasing the volume occupied by a sample.
Compressible