Ch 24 Flashcards

1
Q

Dalton’s atomic theory states:

A
  • All elements are composed of atoms
  • All compounds are made of atoms from various elements
  • Atoms can’t be created / destroyed in chemical reactions
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2
Q

One amu is equivalent to

A

One dalton

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3
Q

The atomic number of an element is equal to

A

Number of protons, which is the same as the number of electrons

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4
Q

What are isotopes?

A

Different number of neutrons found in the same element

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5
Q

The mass number of an element is equal to

A

Total number of protons and neutrons

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6
Q

What is Avogadro’s number?

A

6.02 * 10^23

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7
Q

Who provided experimental evidence that an atom has a dense, positively charged nucleus?

A

Ernest Rutherford

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8
Q

Who developed the first quantum theory?

A

Max Planck

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9
Q

What does the quantum theory state

A

Matter emits energy as electromagnetic radiation in bundles called “quanta”

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10
Q

The energy value of a quantum is given by

A

E = hf

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11
Q

What is the value of h?

A

6.662 * 10^-34

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12
Q

What is the energy of an electron according to the Bohr Model?

A

E = -RH / n^2

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13
Q

How is the energy of an electron related to its orbital radius?

A

The smaller the radius, the lower the energy state of the electron

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14
Q

The Bohr model is used to explain the

A

Atomic emission spectrum and atomic absorption spectrum

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15
Q

Electrons can be excited to higher energy levels via

A

Heat or other energy

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16
Q

Electrons rapidly return to the ground state because

A

The lifetime of the excited state is brief

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17
Q

The electromagnetic energy of photons is described using what equation?

A

E = hc / wavelength

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18
Q

When electrons return to their ground states, each electron emits a

A

Photon with the wavelength characteristic of the specific transition it undergoes

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19
Q

What is a line spectrum?

A

Each line on a spectrum corresponds to a specific electron transition

20
Q

Why does each element possess a unique atomic emission spectrum?

A

Each element can have its electrons excited to different energy levels

21
Q

Describe the Lyman Series?

A

n = 1, UV spectrum

22
Q

Describe the Balmer Series?

A

n = 2, Visible and UV spectrum

23
Q

Describe the Paschen Series?

A

n = 3, Infrared spectrum

24
Q

Describe Energy between higher and lower energy:

A

E = -Rh (1/ni^2 - 1/nf^2)

25
Absorption is when
Electron jumps to a higher energy level
26
Emission is when
Electron lowers to a lower energy level
27
The excitation of electrons results in
Energy absorption
28
What can be used to identify elements present in a gas phase sample?
Absorption spectra
29
What is the Heisenberg uncertainty principle?
States that it is impossible to determine BOTH the momentum and position of an electron
30
According to the Pauli exclusion principle
No two electrons possess the same set of quantum numbers
31
What is an electron's energy state?
The position and energy of an electron via its quantum numbers
32
The principle quantum number (n) gives information about the orbital's
Size
33
The angular quantum number (l) gives information about the orbital's
Shape
34
The magnetic quantum number (ml) gives information about the orbital's
Orientation
35
The principle quantum number (n) represents
The shell where an electron is present in an atom
36
The maximum n corresponds wit the element's
Period in the table
37
The larger the value of n, the
Higher the energy level and radius of electron's orbit
38
What is the maximum number of electrons in an electron shell?
2n^2
39
How is the energy in between adjacent cells as the distance from the nucleus increases?
The energy decreases as the distance increases
40
The angular quantum number (l) tells us both the shape of the orbitals and refers to
The subshells that occur within each principle energy number
41
When l = 0, what is the subshell?
S
42
When l = 1, what is the subshell?
P
43
When l = 2, what is the subshell?
D
44
When l = 3, what is the subshell?
F
45
The maximum number of electrons found in a subshell can be given by the equation of
4l + 2