ch19 - thermal physics Flashcards

(52 cards)

1
Q

kinetic model ofnmatter

A

used to describe structural e of solids, liquids and gases

describes behaviour of matter in terms of moving particles

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2
Q

solid

A

. molecules close together
. tightly bonded to neighbours
. vibrating about fixed positions

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3
Q

gas

A

. particles broken free from their neighbours
. widely seperated
. free to move within container

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4
Q

in change of state, temperature

A

is constant

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5
Q

even in constant temperature part of graph

A

energy is still being lost

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6
Q

more particles movement speed

A

more kinetic energy

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7
Q

more particles disorder

A

more electric potential energy

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8
Q

electric potential energy

A

. close, value is large and negative
. more distance, more potential energy
. complete seperation, potential energy is maximum and zero

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9
Q

change of state (flat part)

A

. must be energy input
. temperature doesn’t not change
. molecules breaking free of one another
. increasing potential energy

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10
Q

between the change of state (tilted part)

A

. input energy increases temperature
. molecules move faster
. kinetic energy increasing

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11
Q

latent heat

A

latent = hidden

energy that goes towards breaking bonds between neighboring molecules, doesn’t cause a temperature change

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12
Q

at change of state

A

no change in kinetic energy
no change in temperature

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13
Q

melting takes less energy than boiling

A

in liquid boiling, almost all molecules have to be broken free

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14
Q

evaporation

A

the process by which a liquid becomes a gas at a temperature below its boiling point

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15
Q

cooling effect of evaporated liquid

A

. most energetic molecules escape
. avergae kinetic energy of remaining molecules is less
. less temperature

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16
Q

internal energy

A

the sum of the random distribution of kinetic and potential energies of the atoms or molecules in a system

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17
Q

ways of increasing the internal energy

A

. heating a gas - molecules vibrate more, molecules kinetic energy increases

. doing work on a gas - molecules strike and bounce off wall faster, more kinetic energy

. passing electric current through gas

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18
Q
A
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19
Q

ways of decreasing internal energy of gas

A

. loses heat ti surroundings
. expands so work is done on surroundings

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20
Q

first law of thermodynamics

A

<>U = q + W

the increase in internal energy of a body is equal ti the thermal energy transferred to it by heating plus the mechanical work done on it

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21
Q

<>U = q + W

A

first law of thermodynamics

. q is energy supplied TO thr system by heating
. W is work done ON the system

22
Q

<>U

A

. postive value = internal energy increases = heat added TO the system = work done ON system

. negative value = internal energy decreases = heat taken AWAY from system = work done BY system

23
Q

in heat is added to system

A

W = 0 in <>U = q + W

24
Q

gas expands

A

work done on surroundings

25
W = p<>V
F = pA W = pAs W = p<>V work done when the volume of a gas changes at constant pressure
26
<>U = q + W for compressing gas
. don't allow heat to enter or leave a system - push piston fast, insulate the syringe . constant temperature - push piston very slowly
27
thermal energy transferred from
high to low temperature region
28
thermometer tells you
its own temperature
29
thermal energy
energy transferred from ine object to another because of a temperature difference
30
thermal equilibrium
a condition when two or more objects have the same temperature so that there is no net flow of energy between them
31
thermodynamic scale
a temperature scale in which temperature is measured in Kelvin
32
absolute zero
the temperature, 0K, at ehich a system has minimum internal energy (0 kinetic energy) = -273.15°C
33
at absolute zero, it is impossible to
remove any energy from the particles
34
K to °C
+273.15
35
thermodynamic temperature scale is
. absolute - is not affected by any property of the substance like boiling point . only certain at fixed points
36
fixed points of kelvin scale
. absolute zero, 0K . triple point of water, 273.16K (temperature at which ice, water and vapour can coexist)
37
gap between absolute zero and triple point is divided into
273.16 equal divisions
38
properties used on basis of thermometer include
. expansion of liquid column (liquid in glass thermometer) . resistance or electrical resistor/thermistor . emf produced by thermocouple . colour of electrically heated wire . volume of fixed mass at constant pressure
39
thermometer must be calibrated at
two or more known temperatures, scale divided equally
40
resistance and temperature
. metals = res increase, temp increase . thermistor = res increases fast, temp increases slow
41
thermocouple
a device consisting of wires of two different metals across which an emf is produced when the two junctions of the wires are at different temperatures more emf = more temperature
42
linearity
how accurate
43
specific heat capacity
the energy required by unit mass per unit temperature change
44
E = mc<>T
45
resistance vs thermocouple thermometer
resistance . very robust . thermistor is narrow range . resistance wire is wide range . larger size than thermocouple, slow . thermistor is highly sensitive . resistance wire is less sensitive . thermistor fairly linear over narrow range . resistance wire has good linearity . can be operated from distance thermocouple . robust . can have wide range . smaller size than resistance thermometers, fast . can be sensitive . non linear . can be operated from a distance
46
to heat a material, amount of energy required depends on
. mass of material . material itself . temperature change wished to achieve
47
specific heat capacity
J kg-1K-1
48
specific latent heat of fusion
the amount of heat energy needed per unit mass to convert unit mass of solid to liquid without change in temperature
49
specific latent heat of vaporisation
the amount of heat energy needed per unit mass to convert unit mass of liquid to has without change in temperature
50
E = mL
L is in Jkg-1
51
specifc later heat of fusion of water
330kJ kg-1
52
specific later heat of vaporisation of water
2.2MJ kg-1