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Ochem 2 > chap. 23 > Flashcards

chap. 23 Flashcards

1
Q

Reactive COOH derivatives

A

acid halide> anhydride> (ald/ketone)> Ester> Amide

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2
Q

Aminolysis

A

acid halide into anhydride

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3
Q

conversions from OH

A

acid halide: socl2, PCl3
Ester: OHR and H2SO4
amides: amide plus cooh DCC makes anyhdryde

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4
Q

Hydrolysable Groups

A

Acetal, hemiacetal, imine, enamine——aldehyde/ketone

Nitrile, ester, amide, acid halide, anhydride—–COOH

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5
Q

Malonic Ester synthesis

A

step 1-alkylation (NaOET, HOET br-r)
step 2: Hydrolysis (H3O)
Step 3 Decarb: heat

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6
Q

Acetoacetic Ester Syn

A

same steps as malonic
-if ad a br-r-br group forms a cyclo

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7
Q
A
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Ochem 2 (10 decks)

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