Chapter 1 Flashcards
(17 cards)
Alkanes
single bonds
methane, ethane, propane, butane
alkenes
double bonds
alkynes
triple bonds
Diols
contain two hydroxyl groups
Geminal if same carbon, vicinal if adjacent carbon
Aldehyde naming
suffix -al
prefix oxo-
Common names for methanal
formaldehyde
Common names for ethanal
acetaldehyde
Common names for propanal
propionaldehyde
Ketone naming
-one or oxo-
Common name for 2-butanone
ethylmethylketone
common name for propanone
acetone
alpha carbon
carbon adjacent to carbonyl
naming carboxylic acid
-oic acid
common names: formic acid (methanoic), acetic acid (ethanoic) propionic acid (propanic)
Ester naming
-oate or alkoxycarbonyl
Amides
replace hydroxyl of carboxylic acid with amino group that may or may not be substituted
-amide or carbamoyl-
with N- for substituents
anhydride
dehydration of 2 carboxylic acids
can be cyclic
replace acid with anhydride
Ranking priority of functional groups
carboxylic acid> anhydride > ester > amide > aldehyde > ketone > alcohol > alkene/ alkyne > alkane