chapter 1 chem Flashcards

1
Q

what is an element

A

when all the atoms are the same

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2
Q

what is a compound

A

two or more different elements chemically combined in a fixed proportion

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3
Q

what is a mixture

A

elements or compounds which are not chemically combined

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4
Q

what is a molecule

A

any elements chemically joined

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5
Q

how can you tell if something is a compound

A

as they have completely different properties form the elements they are made form

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6
Q

how do we separate mixtures

A

by using a physical separation technique e.g filtration

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7
Q

how doe we seperate compounds

A

by using chemical reactions

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8
Q

what are the physical separation techniques

A

filtration
chromatography
simple distillation
fractional distillation
crystallisation

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9
Q

what is filtration used for

A

to sperate an insoluble solid from a liquid

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10
Q

what does insoluble mean

A

a solid will not dissolve in a liquid

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11
Q

how does filtration work

A

1) pour the mixture in the filtration paper which is inside the funnel
2) the liquid will then pass through the tiny pores of the filter paper
3) the solid will stay in the filter paper as it cant pass through it

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12
Q

what is crystallisation used for

A

to sperate a soluble solid form a liquid

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13
Q

how does crystallisation work

A

1) heat a solution in an evaporating dish in a water bath
2) stop the heating as soon as the substance is at the point of crystallisation
3) leave the solution to evaporate and crystals should appear on the edge of the dish

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14
Q

when do we use simple distillation

A

to separate a liquid from a solid if we want to keep the liquid

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15
Q

how does simple distillation

A

1) we heat a solution placed in the round bottom flask
2) as we heat the liquid it starts to evaporate turning it into a vapour
3) the vapour passes into the condenser and condenses it a liquid
3) we then collect the liquid in a boiling tube

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16
Q

why does tap water continuously run through the condenser in simple distillation

A

to keep the internal glass tube (condesor) cold

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17
Q

what is fractional distillation used for

A

to separate a mixture of different liquids with different boiling points

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18
Q

how does fractional distillation used

A

1) gently heat the mixture causing both of the liquid to evaporate, the one with the lowest boiling point will evaporate more easily
2) when the vapours reach the fractionating column they condense and drip back into the flask where the liquids evaporate again
3) this repeated amount of condensation and evaporation increase the amount of the lower boiling point chemical in the fractionating column
4) as the warm vapours reaches up the column they reach the thermometer causing the temperature to rise
6) these vapours pass down the condenser and turn into a liquid, this liquid is a mixture of both chemicals however it has a higher conc of the chemical with the lower bp
7) once the temperature of the thermometer reaches the bp of the chemical with the lowest bp, that chemical then mainly passes through the condenser so this condenses and we can collect it in a new beaker
8) after a while the temp of the thermometer begins to rise again so we then start collecting both chemicals but once the tep is constant again we only recieve the other chemical

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19
Q

what is paper chromatography used for

A

to sperate substances based on their different solubilities

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20
Q

how does paper chromatography work

A

1) draw a pencil line near the bottom of the paper
2) draw a dot of the first substance on the pencil line and continue to do this with different substances until their is no room on the paper
3) place the bottom of the paper into a solvent
4) the solvent then makes its way up the paper and dissolves the substance carrying the dots up the paper as well

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21
Q

why is the paper the stationary phase in chromatography

A

as it does not move

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22
Q

why is the solvent the mobile phase in chromatography

A

as it moves

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23
Q

why does paper chromatography work

A

as each chemical in the mixture will be attracted to the stationary phase to a different extent, this means that chemicals that are strongly attracted to the stationary phase will not move very far and chemicals that are weakly attracted will move further up the paper

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24
Q

what did the ancient greeks believe about atoms

A
  • that everything is made from atoms
  • atoms are tiny spheres that cannot be divided
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25
Q

what was the plum pudding model

A

it was the model of the atom that showed that
- atoms we a ball of positive charge with negative electrons embedded in it

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26
Q

what happened in the alpha scattering experiment

A

1) the scientist took a piece of gold foil, as it could be hammered out into very thin foil
2) they then fired alpha particles at the gold
3) most of the alpha particles past straight through the gold foil without changing direction
4) sometimes the alpha particle was deflected
5) sometimes the alpha particles bounced straight back off the gold foil

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27
Q

What did scientist find out from the results of the alpha particle experiment

A

1) as most of the alpha particle went straight through the foils showed that atoms were mainly made out of empty space
2) as some of the alpha particles we deflected it meant that the centre f the atom must have a positive charge, as the alpha particles that came close to it were repelled and changed direction
3) as some particles bounced straight back it meant that the centre of an atom contained a great deal of mass

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28
Q

what is shown in the nuclear model after the alpha particle experiment

A

in the centre there is a positive charged nucleus
lots of empty space
negative electrons all around the edge

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29
Q

what is shown in the nuclear model after the alpha particle experiment

A

in the centre there is a positive charged nucleus
lots of empty space
negative electrons all around the edge

30
Q

what did niels bohr suggest

A

that electrons orbit the nucleus at specific distances otherwise they would spiral inwards

31
Q

what does the nuclear model look like

A
  • has energy levels containing electrons at specific distances from the nucleus
  • the nucleus contains protons and neutrons
  • has lots of empty space
32
Q

who discovered the electron

A

JJ thompson

33
Q

what did james chadwick discover

A

the neutron

34
Q

what is the radius of an tom

A

0.1 nm
(1x10^-10m)

35
Q

what is the radius if a nucleus

A

1 x 10^-14 m

36
Q

what is the relative charge of a proton

A

+1

37
Q

what is the relative charge of a neutron

A

0

38
Q

what is the relative charge an electron

A

-1

39
Q

what is the relative mass of a proton

A

1

40
Q

what is the relative mass of a neutron

A

1

41
Q

what is the relative mass of an electron

A

very small

42
Q

why do atoms have no overall charge

A

as they have the same number of electrons and protons so the positive charge on the protons are cancelled by the negative charge of the electrons

43
Q

why do atoms have no overall charge

A

as they have the same number of electrons and protons so the positive charge on the protons are cancelled by the negative charge of the electrons

44
Q

where is the atomic number found on an element

A

at the bottom

45
Q

where is the mass number found on an element

A

at the top

46
Q

what is the atomic number

A

the number of protons

47
Q

what is the atomic mass number

A

the total number of protons and neutrons

48
Q

what are isotopes

A

atoms of an elements with different numbers of neutrons

49
Q

what are ions

A

atoms with an overall charge

50
Q

rules when finding the mass number and the atomic number of IONS

A

add an electron if the ion is negative
take away the electrons if the ion is positive

51
Q

what is the relative atomic mass

A

the average if the mass numbers of different isotopes

52
Q

how to work out the relative atomic mass

A

(mass of isotope 1 x percentage abundance of isotope 1) + (mass of isotope 2 x percentage abundance of isotope 2) /100

53
Q

how many electrons can the first shell hold

A

2

54
Q

how many electrons can the second and third shell hold

A

8

55
Q

how many electrons can the 4th shell hold

A

18

56
Q

what did newlands do

A

he arranged elements in their atomic weight and noticed that every eight element reacted in a similar way, this was known as the law of octaves

57
Q

what was the problem o the law of octaves

A
  • by always sticking to the exact order of the atomic weight sometimes the elements were grouped together when they had different properties
58
Q

what did Mendeleev do

A

he arranged all the elements in order of atomic weight, and he then switched the order of specific elements so they fitted the pattern of other elements in the same group he also realised that some elements have not been discovered so he left gaps in his periodic table where he thought an element was missing and predicted the properties of the undiscovered elements based of other elements in the same group

59
Q

why did people accept Mendeleev periodic table

A
  • the new elements matched mendeleevs prediction
60
Q

difference between the modern periodic table and mendeleevs periodic table

A

Modern
- arranged in atomic number
- has noble gases
Mendeleev’s
- arranges in atomic weight
- does not have noble gases as they were not discovered

61
Q

why did Mendeleev arranged his periodic table in atomic weight and what was the problem of it

A

he arranged it in atomic as protons were not discovered, however this caused elements to appear in the wrong order due to the presence of isotopes

62
Q

characteristics of noble gases

A
  • very unreactive
63
Q

what is a noble gases atomic structure

A

they have a full number of outer electrons

64
Q

what makes noble gases unreactive

A

as they have a full outer energy level

65
Q

trend of noble gases

A

the boiling point increases as the relative atomic mass increases

66
Q

what are the boiling point of gases

A

below room temp

67
Q

what are the boiling points of solids

A

above room temp

68
Q

melting point of liquids

A

below room temp

69
Q

meelting point of solids

A

above room temp

70
Q

boiling point of liquids

A

above room temp

71
Q

melting point of gases

A

below room temp