Chapter 10 Flashcards

(37 cards)

1
Q

Molecules in a gas have complete freedom of motion.
KE overcomes the attractive forces between molecules.

A
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2
Q

Molecules in a liquid have limited freedom of motion.
Have enough KE to overcome some of the forces.

A
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3
Q

Molecules in a solid have no freedom of motion.
Though they vibrate, they can’t overcome the forces.

A
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4
Q

How strong are gas IM forces?

A

Weak

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5
Q

How strong are liquid IM forces?

A

Moderate

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6
Q

How strong are solid IM forces?

A

Strong

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7
Q

One state of matter can be transformed into another
by changing the

A

temperature, pressure, or both.

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8
Q

When you change the temperature, you change the
kinetic energy of the particles

A
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9
Q

− When you change the pressure, you change the
strength of the attractions between the particles

A
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10
Q

Covalent bonds are held together by _________
forces. Are these strong or weak?

A

intramolecular, Strong

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11
Q

Intermolecular attractions exist

A

between molecules

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12
Q

Where do intermolecular attractions happen in molecules?

A

+ ion/end of polar molecule to - ion/end of polar molecule

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13
Q

Are inter or intra molecular forces stronger? Why?

A

Usually intra, greater distance=less force to break attractions

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14
Q

What determines Physical properties? EG boiling/melting points, vapor pressure, viscosity

A

Intermolecular forces

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15
Q

Stronger Intermolecular forces can be correlated to

A

Higher melting/boiling point

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16
Q

What are intermolecular forces also known as?

A

Van der Waals forces

17
Q

What are the 3 types of attractions between neutral molecules?

A

Dipole-dipole, Hydrogen bonding, London Dispersion

18
Q

What type of bonding involves ions?

A

Ion-dipole force

19
Q

Can nonpolar atoms have dipole-dipole attraction? Can nonpolar gases be liquefied?

20
Q

Who proposed London Dispersion forces?

21
Q

How do London Dispersion forces happen? How does this affect other atoms?

A

E- can end up on the same side of atom (normally try to repel each other), creating temporary polarity, which influences its neighbors. + wants to bind to -

22
Q

What are London Dispersion forces? Where are they found?

A

Attractions between an instantaneous
dipole and an induced dipole. All molecules, regardless of their polarity

23
Q

What is the trend of molecular weight and dispersion forces?

A

As MW increases, dispersion forces increase.

24
Q

Do long or short molecules have stronger London forces? Why

A

Longer, more surface area so they have more interactions

25
What molecules have dipole dipole forces? Why?
All polar molecules, because they have permanent dipole moments
26
What is a dipole?
A molecule with charged ends
27
What is a dipole dipole force?
Dipoles interacting via opposite end attraction
28
18 onward(Just highlighted stuff)
29
What is hydrogen bonding?
A type of dipole dipole force where H (H bond donor) is directly bonded to N, O, or F (H bond acceptor). This interacts with a lone pair of e- on an N, O, or F atom in another molecule.
30
What are ion dipole forces?
Solvent pulling the ions from an ionic substance from the crystal, solvating them
31
What does an anion dipole look like?
32
What does a cation dipole look like?
33
Ammonia and hydrogen fluoride both have unusually high boiling points due to _____
hydrogen bonding, because it causes have strong Intermolecular forces (which correlate to high boiling points)
34
Is hydrogen bonding inter or intra molecular?
Inter
35
What is Hydrogen bonding?
Strong intermolecular forces that happen between molecules with a very strong permanent dipole moment.
36
What are ion dipole forces, and how are they formed?
When an ionic substance dissolves in H2O, the solvent pulls ions and solvates (surrounds) them. Solvent has +/- charged ends, which are attracted to the ions.
37