chapter 12 - the periodic table Flashcards

1
Q
  • describe the periodic table
A

a method of classifying elements and its use to predict properties of elements.

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2
Q

how are elements arranged in the periodic table?

A

the are arranged according to their proton number.
thus, the elements show periodicity: elements with similar properties appear at regular intervals.
the similar elements are arranged into columns.

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3
Q

what are the columns numbered I to VIII?

A

Families called groups.

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4
Q

what are the rows numbered 0 to 7?

A

periods.

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5
Q

what is the point of the zig-zag line?

A

it separates metals from non-metals
metals to the left (except for hydrogen)
non-metals to the right

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6
Q

*describe and explain the relationship between
Group number, number of outer shell electrons
and metallic/non-metallic character

A

the group number is the same as the number of outer shell electrons in the atoms.
outer shell electrons dictate how an element behaves.
all elements in a group have similar reactions.
elements of group VIII elements have a very stable arrangement of e- —> unreactive.
groups I to III lose e- —> metals except for boron.
groups IV to VII gain e- —> non-metals.
metallic character of the elements increases as you go down a group
atoms with the same number of valency electrons react in a similar way.

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7
Q

what is another name for outer-shell electrons?

and what is valency?

A

valency electrons

valency is the number of electrons atoms of an element lose, gain or share, to form a compound.

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8
Q

what does the period of an element tell you?

A

the number of electron shells in the atoms.

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9
Q

what are artificial elements?

A

ex) neptunium (Np), lawrencium (Lr).
they have been created in a lab.
they are radioactive, their atoms break down very quickly, that is why they aren’t found in nature.

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10
Q

*describe the change from metallic to non-metallic character across a period

A

across a period there is a trend, a change from metal to non-metal.

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11
Q

what are alkali metals?

A

they are the elements of group I

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12
Q

what are the physical properties of alkali metals?

A

they are not typical metals:

  • good conductors of heat and electricity
  • softer than most metals, can be cut with a knife.
  • shiny silvery surfaces when freshly cut.
  • have low densities, float on water- while reacting with it.
  • low melting and boiling points, compared with most metals.
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13
Q

from what you’ve learnt above

*Describe lithium, sodium and potassium

A
  • they are elements of Group I

- a collection of relatively soft metals showing a trend in melting point, density and reaction with water.

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14
Q

*identify the trends in physical properties of group I

A
  • softness increases going down the group
  • density increases going down the group
  • melting and boiling point decreases going down the group.
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15
Q

describe the reactivity of alkali metals

A

alkali metals are the most reactive of all the metals.
1- they react vigorously with water. hydrogen bubble off, leaving solutions of their hydroxides which are alkalis.
2- when they react with chlorine, they burst into flame, burn brightly, forming chlorides.
3- the burn fiercely in oxygen to form oxides, which can dissolve in water to give alkaline solutions.

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16
Q

explain why alkali metals are so reactive

A
  • they need to lose only one e-, to gain a stable outer shell.
  • they have a strong drive to react with other elements and compounds, in order to give up this 1 electron.
  • form positive (1+) ions.
  • they form ionic compounds.
  • they are usually kept under oil to stop them from reacting.
17
Q

explain why alkali metals react in similar ways

A
  • lithium floats and fizzes.
  • sodium shoots across the water.
  • potassium melts with the heat of the reaction, and the hydrogen catches fire —> burns with a lilac flame.
    they react in a similar way because they have the same number of valency electrons.
18
Q

*identify the trends in chemical properties of group I

A
  • reactivity increases going down the group
19
Q

explain why reactivity of alkali metals increases going down the group

A
  • As you go down Group 1, the number of shells of electrons increases by 1 (Period number increases down the Periodic table).
  • This means that the outer electron is further away from the nucleus so there are weaker electrostatic forces of attraction.
  • This requires less energy to overcome the electrostatic forces of attraction between the negatively charged electron and the positively charged nucleus.
  • This allows the electron to be lost easily, making it more reactive as you go down the Group
20
Q

what are the halogens?

A
  • elements of group VII.

all halogens form colored gases, are poisonous, form diatomic molecules.

21
Q

from what you’ve learnt above
*Describe the halogens, chlorine, bromine and
iodine

A
  • elements of Group VII.

- a collection of diatomic non-metals showing a trend in color and density.

22
Q

*identify the trends in physical properties of group VII

A
F2 --> yellow gas
Cl2 --> green gas
Br2 --> red liquid 
I2 --> black solid
- color gets deeper going down the group
- density increases going down the group
- boiling point increases going down the group
23
Q

*identify the trends in chemical properties of group VII

A
  • reactivity decreases going down the group
24
Q

why are halogen so reactive?

A
  • their atoms need just one more e- to reach a stable outer shell.
  • they have a strong drive to react with other elements or compounds, to gain this 1 e-.
  • form negative (1-) ions.
25
Q

*state the reaction of halogens with other halide ions

A

a halogen will displace a less reactive halogen from a solution of its halide.
1- when chlorine water (solution of chlorine) is added to a colorless solution of potassium bromine, the solution turns orange.
Cl2 + 2KBr —> 2KCl + Br2
bromine is pushed out of its compound, it has been displaced.
2- chlorine water is added to a solution of potassium iodide, the solution turns red-brown.
Cl2 + 2KI —> 2KCl + I2
iodine has been displaced.

26
Q

what are the noble gases?

A

elements of group VIII

27
Q
  • describe the noble gases
A

unreactive, monoatomic, colorless gases which occur naturally in air.

28
Q

*explain why noble gases are unreactive and monoatomic in terms of electronic structure

A

their atoms already have a stable/ full outer shell.

no need to react to gain or lose electrons.

29
Q

*identify the trends in physical properties of group VIII

A
  • atoms increase in size and mass going down the group.
  • density of the gases increases going down the group
  • boiling points increase going down the group.
30
Q

*State the uses of the noble gases in providing an

inert atmosphere

A

1- argon in lamps:
filler in tungsten light bulbs.
protects metals from that are being welded.
2- helium for filling balloons and airships:
it is much lighter than air and will not catch fire.

31
Q

what are other uses of noble gases?

A

1- neon is used in advertising signs. (it glows red but its color can be changed by mixing it with other gases)
2- krypton is used in laser (for eye surgery) and in car headlamps.
3- xenon is used in lighthouse lamps, lights for hospital operating rooms and car headlamps. (gives a light like bright daylight but with a blue tinge)

32
Q

what are the transition elements?

A

the block of 30 elements in the middle of the periodic table.

33
Q

*describe the transition elements

A
  • metals.
  • have high densities
  • high melting points and
  • form colored compounds, which, as elements and compounds, often act as catalysts
  • they have variable oxidation states.
34
Q

what are the physical properties of transition elements?

A
  • hard, tough and strong.
  • high melting points.
  • high densities.
  • malleable.
  • good conductors of heat and electricity. (silver is the best conductor of electricity, copper is next)
35
Q

what are the chemical properties of transition elements?

A
  • much less reactive than alkali metals (iron is an exception –> it ruts easily).
  • no clear trend in reactivity, but those next to each other in the periodic table tend to be similar.
  • form colored compounds.