Chapter 14 Flashcards
(100 cards)
Define corrosion
Corrosion is the gradual destruction of materials, usually metals, by chemical reactions with their environment.
Corrosion can lead to significant structural and economic issues in various industries.
List and explain problems caused by corrosion
- Structural failure
- Decreased lifespan of materials
- Increased maintenance costs
- Safety hazards
- Environmental damage
Corrosion can compromise the integrity of structures and components, leading to potential accidents.
Understand why corrosion occurs
Corrosion occurs due to the electrochemical reactions between metals and their environment, often involving moisture, oxygen, and electrolytes.
Factors such as temperature and pH can influence these reactions.
Understand Galvanic series chart: know relative positions of steel, tin, magnesium, aluminum, zinc, platinum & carbon/graphite
The Galvanic series chart ranks metals based on their electrochemical activity in a specific environment, with magnesium being most active and platinum least active.
This ranking helps predict corrosion behavior when different metals are in contact.
Explain active/passive, anode/cathode
- Active: Corroding metal that loses electrons
- Passive: Metal that forms a protective layer
- Anode: Electrode where oxidation occurs
- Cathode: Electrode where reduction occurs
Understanding these terms is crucial for analyzing corrosion processes.
Know requirements for corrosion to occur
- Presence of an electrolyte
- Anode and cathode
- Electrical connection between anode and cathode
- Corrosive environment
Without these conditions, corrosion cannot take place.
Define electrolyte
An electrolyte is a substance that produces an electrically conducting solution when dissolved in water or another solvent.
Common examples include salts, acids, and bases.
Explain electrochemical corrosion process and galvanic cell
The electrochemical corrosion process involves oxidation and reduction reactions in a galvanic cell, where electrons flow from anode to cathode through an external circuit.
This flow of electrons is responsible for the corrosion of metals.
What metallurgical conditions affect corrosion, how and why?
- Alloy composition
- Microstructure
- Surface finish
- Heat treatment
These factors influence the susceptibility of metals to corrosion through changes in their electrochemical properties.
What environments affect corrosion and why?
- Moisture
- Salinity
- Temperature
- pH levels
Different environments can accelerate or inhibit corrosion based on their chemical properties.
How operating conditions can affect corrosion
- Temperature variations
- Pressure changes
- Flow rates
- Chemical exposure
These conditions can alter the rate and type of corrosion experienced by materials.
List types of corrosion as discussed in class – be able to explain
- Uniform corrosion
- Pitting corrosion
- Galvanic corrosion
- Crevice corrosion
- Stress corrosion cracking
Each type has distinct mechanisms and characteristics that impact material integrity.
Corrosion allowance and corrosion rates – how to use and determine
Corrosion allowance is the extra thickness added to materials to account for expected corrosion loss over time, while corrosion rates are measured in mils per year (mpy) to estimate material degradation.
Proper calculations help ensure safety and longevity of structures.
What is the only conditioning you need to know for this test?
Stress relieving
No special purpose surface treatments are required.
What microstructures result from hardening steels?
Martensite or martensite and cementite
How does carbon content relate to heat treatment results?
It defines microstructure in equilibrium or when hardened
What does OQT stand for?
OQT
What microstructure does OQT indicate for a low carbon steel?
Ferrite and pearlite
What microstructure does OQT indicate for a hypereutectoid steel?
Cementite and pearlite
What is a good summary for the heat treatments?
Figure 13-33
What do you need to know about the specific alloy contents for the 41xx, 43xx, and 52xxx series?
You need to know the specific alloy contents (not percentages) for these series.
What should you be familiar with regarding the groups of steels?
You should be familiar with the groups and what their purposes are.
What is carbon equivalency and how does it relate to?
Carbon equivalency relates to weldability.
What is HSLA steel?
HSLA steel is High-Strength Low-Alloy steel.