Chapter 4: Light and Electronic Structure Flashcards

(35 cards)

1
Q

electromagnetic radiation

A

energy traveling in waves from charged particles

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2
Q

electromagnetic spectrum

A

the complete range of electromagnetic waves placed in order of increasing frequency

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3
Q

visible spectrum

A

small band of electromagnetic radiation we perceive as light

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4
Q

wavelength (𝜆)

A

distance between two consecutive wave points; measured in meters or nanometers

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5
Q

frequency (𝜈)

A

number of waves passing a point per second

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6
Q

hertz (Hz)

A

the unit of frequency, equal to one cycle per second; 1s^-1

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7
Q

wavelength and frequency relationship

A

inversely related to each other; as the wavelength decreases, the frequency increases & vice versa

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8
Q

speed of light (c)

A

𝜆𝜈, equal to 3.00 × 10^8 m/s

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9
Q

photon

A

small packet of light energy

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10
Q

energy of a photon (E)

A

E = hν or E = hc/λ

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11
Q

Planck’s constant (h)

A

6.63 × 10^-34 J·s, relates energy and frequency

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12
Q

line spectra

A

the emission of light only at specific wavelengths

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13
Q

Niels Bohr

A

physicist who proposed that electrons orbit the nucleus in the same way that planets orbit around the sun, orbits that were closer to the nucleus were lower in energy; he also proposed that electrons can jump from one energy level to another by absorbing light

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14
Q

Bohr model

A

model explaining emission spectra with energy levels

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15
Q

energy levels

A

discrete levels where electrons reside

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16
Q

quantum model

A

model that describes electrons as both particles and waves; indicates where electrons are most likely to be found

17
Q

uncertainty principle

A

the idea put forth by Werner Heisenberg that the behavior of subatomic particles is uncertain; it is impossible to know the exact velocity and location of a particle

18
Q

principal quantum number (n)

A

whole number indicating energy level of electrons

19
Q

sublevel

A

energy levels divided into s, p, d, f

20
Q

orbital

A

region where electrons are likely found

21
Q

Aufbau Principle

A

electrons fill lowest energy levels first

22
Q

Pauli Exclusion Principle

A

no more than two electrons per orbital

23
Q

Hund’s Rule

A

single electrons occupy orbitals before pairing

24
Q

electron configuration

A

arrangement of electrons in an atom’s orbitals

25
noble gas shorthand
abbreviated electron configuration using noble gases
26
valence electrons
electrons in the outermost shell involved in bonding
27
inner electrons
electrons not involved in bonding, lower energy
28
outer electrons
electrons beyond the noble gas configuration
29
octet rule
atoms prefer to have eight electrons in valence shell
30
energy level 1 (n=1)
contains one s sublevel, holds 2 electrons
31
energy level 2 (n=2)
contains one s and one p sublevel, holds 8 electrons
32
energy level 3 (n=3)
contains one s, one p, and one d sublevel - holds 18 electrons
33
energy level 4 (n=4)
contains one s, one p, one d, and one f sublevel - holds 14 electrons
34
ion electron configuration
adjust configuration based on ion charge
35
relative energy levels
energy increases in the order s