Chapter 4 rxns in aqueous solutions Flashcards
(28 cards)
solution
homogeneous misture of 2 or more substances
solvent
substance with greatest quantity
solute
other substance, dissolved in the solvent
electrolyte
a substance whose aq solution contains ions
nonelectrolte
does no form ions in solutioon
solvation
helps stabilize the ions in solution and prevents cations and anions from recombing
strong electrolytes
those solutes that exist in solution completely or nearly completely as ions
weak electolytes
those solutes that exist in solution mostly in the form of neutral molecules with onlu a small fraction in the form of ions
chemical equillibrium
relative number of each type of ion or molecule in the rxn is constant over time
->
represents ionization of strong electrolytes.
water soluable ionic cmpds are strong electrolytes
precipitation rxns
rxns that result in the formation of an insoluable product
solubility
the amount of the substance that can be dissolved in a given amount of solvent
exchange (metathesis) rxns
rxn in which cations and anions appear to exchange partners.
have to check solubilities, for precip to occur, 1 product must be insoluable in water
complete ionic equation
all soluble strong electrolytes shown as ions
spectator ions
plays no direct role in the rxn, are exactly the same on both sides of the equation
net ionic equation
includes only ions and molecules directly invovled in the rxn. the sum of the ionic charges must be the same on both sides of the balanced net ionic equation.
steps on p 123
acids
substances that ionize in aq solutions to form H ions. Proton donors
bases
substances that accept (react with) H ions. produce OH- ions with dissolved in water
neutralization rxns
when a soluton of an acid and a solution of a base are mixed
salt
any ionic compound whose cations comes from a base
redox rxn
electrons are transferred from one reactant to another
oxidation
loss of elctrons, becomse + charged
reduction
gain of electrons, becomes - charged
when one substance is oxidized, another must be reduced
oxidation #s rules
- for an atom in its elemental form, the oxidation # is always 0.
- for any monatomic ion the oxidation # = the ionic charge
- nonmetals usually have negative oxidation numbers, although they can sometimes be positive.
- the oxidation # of oxygen is usually -2. EXCEPT peroxides O2, oxidation # is -1
- oxidation # of H is +1 when bonded to nonmetals and -1 when bonded to metals
- F is always -1. other halogens have an oxidation number of -1 in most binary compunds. when combined with oxygen, they have positive oxidation states - the sume of the oxidation # of all atoms in a neutral compound is 0. the sum of the oxidation #s in a polyatomic ion = the charge of the ion.