Chapter 5 Flashcards
(25 cards)
how many subshells does the 1st electron shell have
1 (1s)
how many subshells does the 2nd electron shell have
2 (2s,2p)
what are the letters given to the 1st 4 sub shells
s,p,d,f
what shape is the s-orbital
spherical
what shape is the p orbital
dumbbell shaped
how many orbitals does an s sub shell have
1
how many orbitals does a p sub shell have
3
how many orbitals does a d sub shell have
5
heisenbergs uncertainty principle
definition of an orbital
a region of space where there is a 95% probability of finding the electron
or
a region around the nucleus that can hold up to 2 electrons, with opposite spins
what does the pauli exclusion principle state?
-each orbital may contain no more than 2 electrons
- electrons have spin - either up or down
- the spins of electrons in the same orbital must be opposite
what is the total no. of electrons in the 1st shell
2
1s = 1 orbital x 2 electrons
= 2
how many electrons are in the 2nd shell in total
8
2s = 2 electrons x 1 orbital
2p = 2 electrons x 3 orbitals
= 2+6 = 8
how many electrons can each orbital take?
2
what is hunds rule
single electrons occupy all empty orbitals within a sub level before they start to form pairs in orbitals
what is the aufball principle
orbitals are filled from the lowest energy level upwards
*not energy shell order
what needs to be remembered when giving the elecrostatic config of a transition ion in period 4?
remove electrons from 4s orbital before 3d orbitals
what is an ionic bond
electrostatic attraction between a positive metal ion and a negative non metal ion
what structure do all ionic substances form
giant ionic lattice
what is a covalent bond
the strong electrostatic attraction between the binded pair of electrons and the nuclei of the bonded atoms
* also is directional
what is dative covalent bonding?
- also referred to as coordinate bonding
- a shared pair of electrons but both have been provided by one of the bonding atoms only
what is the octet rule
atoms need to gain, lose or share electrons when they combine with other other atoms to acquire a stable octet of electrons
exceptions:
- not enough electrons to reach octet
- expansion of octet
what determines covalent bond strength
- how much the outer atomic orbitals of the bonded atoms overlap
- how strongly the atomic nuclei are attracted to the shared electrons
how is covalent bond strength measured?
what is this known as?
the energy required to break it
average bond enthalpy
stronger bond = higher average bond enthalpy
what is a covalent bond
strong electrostatic attraction between a shared pair of electrons and the nuclei of bonded atoms