Chapter 8 And 15 Flashcards

1
Q

What does VSEPR stand for?

A

Valence-Shell Electron-Pair Repulsion

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2
Q

What is the main purpose of the VSEPR model?

A

To predict the 3D structure of molecules by minimizing repulsions

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3
Q

In VSEPR notation, what does ‘A’ represent?

A

The central atom

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4
Q

In VSEPR notation, what does ‘X’ represent?

A

Bonded atoms

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5
Q

In VSEPR notation, what does ‘E’ represent?

A

Lone pairs of electrons

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6
Q

What is the electron group geometry for AX2?

A

Linear

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7
Q

What is the molecular geometry for AX2?

A

Linear

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8
Q

What is the electron group geometry for AX3?

A

Trigonal planar

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9
Q

What is the molecular geometry for AX3?

A

Trigonal planar

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10
Q

What is the molecular geometry for AX2E1?

A

Bent

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11
Q

What is the electron group geometry for AX4?

A

Tetrahedral

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12
Q

What is the molecular geometry for AX4?

A

Tetrahedral

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13
Q

What is the molecular geometry for AX3E1?

A

Trigonal pyramidal

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14
Q

What is the molecular geometry for AX2E2?

A

Bent

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15
Q

What are the two major varieties of covalent bonds?

A

Nonpolar (Pure) Covalent and Polar Covalent

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16
Q

What characterizes a Nonpolar (Pure) Covalent bond?

A

Electronegativity difference Δx < 0.5

17
Q

What characterizes a Polar Covalent bond?

A

Electronegativity difference Δx = 0.5 - 1.4

18
Q

What is the dipole moment?

A

The vector sum of the individual bond dipoles

19
Q

What are London Dispersion Forces?

A

Short-lived attractive forces between nonpolar compounds

20
Q

How do London Dispersion Forces change with mass?

A

They tend to increase with an increase in mass

21
Q

What is polarizability?

A

The ease with which an atom/molecule can change its electron distribution

22
Q

What are Dipole-Dipole interactions?

A

Forces generated when two polar molecules interact based on dipole alignment

23
Q

What defines a Hydrogen Bond?

A

A bond between hydrogen and a very electronegative atom (N, O, or F)

24
Q

What are the major effects of Intermolecular Forces?

A

Melting Points, Boiling Points, Vapor Pressure, Solubility

25
How does IMF strength relate to melting point?
Stronger IMFs means higher melting points
26
How does IMF strength relate to boiling point?
Stronger IMFs means higher boiling points
27
How does IMF strength relate to vapor pressure?
Stronger IMFs means lower vapor pressure
28
What does 'like-dissolves-like' refer to?
Molecules with similar polarities/IMFs are more likely to be miscible
29
Fill in the blank: Molecules with dissimilar polarities/IMFs are more likely to be _______.
insoluble