Chapter 8 And 15 Flashcards
What does VSEPR stand for?
Valence-Shell Electron-Pair Repulsion
What is the main purpose of the VSEPR model?
To predict the 3D structure of molecules by minimizing repulsions
In VSEPR notation, what does ‘A’ represent?
The central atom
In VSEPR notation, what does ‘X’ represent?
Bonded atoms
In VSEPR notation, what does ‘E’ represent?
Lone pairs of electrons
What is the electron group geometry for AX2?
Linear
What is the molecular geometry for AX2?
Linear
What is the electron group geometry for AX3?
Trigonal planar
What is the molecular geometry for AX3?
Trigonal planar
What is the molecular geometry for AX2E1?
Bent
What is the electron group geometry for AX4?
Tetrahedral
What is the molecular geometry for AX4?
Tetrahedral
What is the molecular geometry for AX3E1?
Trigonal pyramidal
What is the molecular geometry for AX2E2?
Bent
What are the two major varieties of covalent bonds?
Nonpolar (Pure) Covalent and Polar Covalent
What characterizes a Nonpolar (Pure) Covalent bond?
Electronegativity difference Δx < 0.5
What characterizes a Polar Covalent bond?
Electronegativity difference Δx = 0.5 - 1.4
What is the dipole moment?
The vector sum of the individual bond dipoles
What are London Dispersion Forces?
Short-lived attractive forces between nonpolar compounds
How do London Dispersion Forces change with mass?
They tend to increase with an increase in mass
What is polarizability?
The ease with which an atom/molecule can change its electron distribution
What are Dipole-Dipole interactions?
Forces generated when two polar molecules interact based on dipole alignment
What defines a Hydrogen Bond?
A bond between hydrogen and a very electronegative atom (N, O, or F)
What are the major effects of Intermolecular Forces?
Melting Points, Boiling Points, Vapor Pressure, Solubility