Chapter 9 Flashcards

(46 cards)

1
Q

What is Le Chateliers Principle?

A

If dynamic equilibrium is distributed, the position of equilibrium shifts the counter active change

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2
Q

What is the dynamic equilibrium?

A

Exist in a system composed of at least two states when the populations of the two states are constant, even though the members of the system are constantly changing from one state to another

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3
Q

What is the equilibrium constant?

A

Expresses the relationship between products & reactants at equilibrium

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4
Q

The equilibrium constant’s numerical description is between

A

Bond strengths & intermolecular forces between all the molecules in the system

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5
Q

Equilibrium favors the

A

Reactive side, which shifts to the right

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6
Q

The concentrations of solids & liquids do not

A

Appear in the equilibrium constant

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7
Q

Acids will _______ a hydrogen ion

A

Donate

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8
Q

A base will _______a hydrogen ion

A

Accept

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9
Q

An acid is a species that

A

Increases the hydronic ion H3O concentration in an aqueous solution

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10
Q

A base is a species that

A

increases the hydroxide ion OH concentration in an aqueous solution

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11
Q

In an acid-base reaction, the acid is converted into its

A

Conjugate base & the base is converted into its conjugate acid

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12
Q

What is an amphiprotic species?

A

Can behave as either an acid or a base (water)

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13
Q

A strong acid will completely

A

Ionize in an aqueous solution (completely dissociates in water)

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14
Q

A strong acid has a

A

Weak conjugate base

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15
Q

What is the strongest base?

A

Hydroxide

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16
Q

Weak bases do not

A

Completely ionize in water

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17
Q

Dynamic equilibrium is established between

A

An acid & base

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18
Q

What is a common weak acid?

A

Ammonium

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19
Q

What is a polyprotic acid?

A

Capable of losing more than a single proton per molecule

1st stage (fastest)-most easily lost

20
Q

Phosphorilic acid is a

A

A weak acid (also triprotic)

1st proton is readily donated

21
Q

There are equilibrium constants for

A

Each weak acid (Ka)

22
Q

A larger equilibrium constant means a

A

Stronger acid (Kb)- equilibrium constant for a weak base

23
Q

In pH, “p” means

A

Negative Logarithm

24
Q

The “H” in pH is

A

Hydrogen ion concentration

25
There are ______ different orders of magnitude
14
26
Logarithmic functions help
Map a range onto a smaller set, with each number differing by a factor of 10
27
Water acts as both an
Acid & base
28
The pHh of any solution will add up to
14
29
The equilibrium constant for acid & bases are presented as
pKa & pKb
30
With pKa & pKb, the "p" stands for
The power of
31
Strong acid & bases completely ionize in water, meaning every
Mole of acid falls into an equal number of hydrogen ions & every mole of base falls into an equal number of hydroxide ion
32
Acids & bases react to
Give salts
33
Salts of strong acids do not
Participate
34
Salts of weak bases & acids
Do participate
35
pH of lidocaine is slightly
Acidic Lidocaine is a weak base, so the salt will be an acid
36
A pH buffer is a solution that
Resists changes in pH
37
Solutions will contain
A weak acid & its conjugated base or weak base & conjugated acid
38
When a small amount of strong acid or base is added to a solution, the pH will
Change, but not as nearly as much as if it were non-buffered
39
A strong acid & its conjugated base have no buffer action because
The acid dissociates completely leaving no acid behind for buffer action
40
If a strong base is added to a buffer solution, the weak acid in the buffer will
React with water & weak base, which causes the pH to increase, but not by much
41
If a strong acid is added to a buffer solution, the weak base in the buffer will
React to hydrogen ion to give HA, which is a weak acid
42
What is the primary buffer system in the blood
Carbonic acid
43
The Henderson-Hasselbalch equation shows the
Relationship between pH & pOh of a solution or pKa/pKb
44
The pH of a buffer depends on the
Ratio of weak base to its conjugated acid, not the numerical value of each
45
You can dilute buffer with water &
Not change pH of the solution
46
In order to be an effective buffer, there has to be a
Concentration of both the weak acids & weak base