Chapter 9 General Properties of Aqueous solutions Flashcards

(53 cards)

1
Q

solution

A

a homogenous mixture

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

solute

A

the analyze of interest

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

solvent

A

the medium in which the solute is dissolved or dispersed

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Aqueous solutions

A

a solution in which the water is the solvent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

solubility

A

the maximum amount of substance that will dissolve into a solvent at a given temperature

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

saturated solution

A

a solution that contains the maximum amount of dissolve solid

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

electrolytes vs. non-electrolytes

A

once dissolved, different substances may behave differently and results in different types of solutions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

electrolyte

A

substance that dissolve in water to form solutions that conduct electricity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

non-electrolytes

A

substances that dissolve in water to form solutions that do not conduct electricity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

electrolytes form ions there are two ways ion can be formed:

A

Dissociate: to separate, upon dissolving to form separate ions

ionize:the process in which a. molecular compound formed an ion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

strong electrolytes

A

substances that dissociate or ionize completely

soluble salts, strong acids, strong bases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

weak electrolytes

A

substances that partially dissociate or ionize

slightly soluble slats, weak acids, weak bases

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

conductivity

A

non-electrolytes: no ions-does not conduct electricity

molecular compounds(not acid/base)

strong electrolyte: lots of ions-conducts electricity very well

soluble salts

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Soluble

A
  1. compounds containing an alkali metal cation(Li+,Na+,K+,Rb+,Cs+) or the ammonium ion(NH4+)
  2. compounds containing the nitrate ion(NO3-), acetate ion(C2H3O2-) or chlorate ion(ClO3-)
  3. compounds containing the chloride ion (Cl-), bromide ion(Br-), or iodide ion(I-)
    exceptions: compound that contains Ag+,Hg2^2+,Pb2+
  4. compounds containing the sulfate ion(SO4^2-)
    exceptions: compound that contains Ag+,Hg2^2+,Pb2+,Ca2+,Sr2+ or Ba2+
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

insoluble

A
  1. compounds containing the carbonate ion(CO3^2-) phosphate ion(PO4^3-) chromate ion(CrO4^2-) or sulfide ion(S2-)
    exception: Li+, Na+,K+,Rb+,Cs+ or NH4+
  2. compound containing the hydroxide ion (OH-)
    exception: Li+,Na+,K+,Rb+,Cs+,Ba+
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

molecular equation

A

the chemical equation that treats all species as molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

total ionic equation

A

the chemical equation that explicitly shows the ions

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

spectator ion

A

ions that do not participate in the ration they appertains on both sides of the total ionic equation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

acids

A

ability to dissolve metals. sour taste. turns litmus red

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

bases

A

slippery feel, bitter taste, turns litmus blue

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

acids

A

substances that contain H in the chemical formula and produces H+ ions when dissolved in water

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

bases

A

substances that contains OH in the chemical formula and produces OH- ion when dissolved in water

23
Q

Limitations

A
  1. restricts all acid-base reactions to water

2. excludes NHg and amines as bases

24
Q

acids

A

a proton donor

25
bases
a proton acceptor
26
Hydronium
H+ does not exist in the aqueous solution, in water, the H+ attaches to eater. H+ can be used for convenience, but it is H3O+
27
Acid nomenclature
acidic compounds are named as acids if it is in solution. acids are named based on whether it contains oxygen or not. no oxygen hydro-anion-ic acid with oxygen anion acid -ite anion-ous acid -ate anion-ic acid
28
polyphonic acid
acid with more than one ionizable proton
29
monoprotic
acids with one ionizable proton
30
diprotic
acids with two ionizable protons
31
bronzed-lowry definition
proton accepts hydroxide compounds, metal oxides, ammonia ana amines
32
strong acids
acids, that ionized completely
33
strong bases
bases that ionize completely
34
acid-base reactions
since acids are H+ donors and bases are H+ acceptors they are made to react together.
35
Redox reactions
a chemical reaction in which electrons are transferred from one substance to another
36
corrosion
the unwanted oxidation | 4Fe + 3O2--->2Fe2O3
37
combustion reactions
2C8H8+25O2---->16CO2+18H20
38
metabolic process
C6H12O6+6O2--->6CO2+6H2O+ATP
39
voltaic cells
batteries | Zn+MnO2+H2O--->ZnO+Mn(OH)2
40
matallurgy
extraction of metals from ore | Fe2O3+3CO--->2Fe+3CO2
41
oxidation states
the hypothetical charge an atom would have if all bonds were ionic
42
rules for oxidation states
1. the sum of the oxidation states must equal the net charge 2. for lone elements the os=charge 3. for ionic compounds, the charge of the ions are the os. 4. in compounds a. F is alway -1 b. H is usually +1 c.O is usually -2 except: hydride, peroxide's, superoxides
43
os
the hypothetical charge an atom would have if all bonds were ionic
44
reduce agent
a substance that causes another compound to be reduced, therefore itself is oxidized
45
oxidizing agent
a substance that cause another compound to be oxidized, therefore itself is reduced
46
Concentration of solutions
the amount of solute in solution can vary. one way of expressing this amount is through the unit of molarity Molarity, M: amount of solute, mol/ volume of solution L
47
Dilutions
C1V1=C2V2. M1V1=M2V2 C1:mol/L V1: L=mol initially the amount of solute does not change when a solvent is added to dilute the solutions. but since the volume of solutions increases the concentration must decrease
48
pH scale
in many applications the concentration of H+ ions is important often the concentration is small. pH=-log[H+]
49
auto ionization of water
process is driven by hydrogen bonding
50
Gravimetric analysis
analytical technique based on masses requires reactions to be completed
51
tritration
an analytical technique for precisely determine the concentration or amount of solute in a sample by reacting it with a standard of known concentration
52
equivalence point
the point in the titration in which the number of moles of titrant and moles of analyze are in stoichiometric equivalence
53
end point
the point in the titration in which the indicator changes color indicating the stoppage of the titration