chapter2 Flashcards

(41 cards)

1
Q

What is an atom?

A

The atom is the fundamental unit of matter, composed of protons, neutrons, and electrons.

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2
Q

What is the atomic number (Z)?

A

The atomic number (Z) is the number of protons in the nucleus.

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3
Q

What is atomic mass (A)?

A

Atomic mass (A) is the total mass of protons and neutrons.

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4
Q

What is Avogadro’s number (NA)?

A

Avogadro’s number (NA) is the number of atoms/molecules per mole: 6.022 x 10^23.

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5
Q

What is an atomic mass unit (amu)?

A

An atomic mass unit (amu) is 1/12 of the mass of a carbon-12 atom.

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6
Q

What is the approximate mass of an atom formula?

A

Mass of an atom (approx) = A * 1.66 x 10^-24 g.

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7
Q

What is the Bohr model?

A

The Bohr model describes electrons revolving in discrete orbits; energy levels are quantized.

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8
Q

What is the wave mechanical model?

A

The wave mechanical model describes electrons as probability clouds governed by quantum mechanics.

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9
Q

What are quantum numbers?

A

Quantum numbers (QNs) describe the properties of electrons in atoms.

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10
Q

What is the principal quantum number (n)?

A

The principal quantum number (n) indicates the energy level/shell (n = 1,2,3,…).

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11
Q

What is the angular momentum quantum number (ℓ)?

A

The angular momentum quantum number (ℓ) indicates the subshell shape (ℓ = 0 to n-1).

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12
Q

What are the possible values of ℓ?

A

The possible values of ℓ are: s (ℓ=0), p (ℓ=1), d (ℓ=2), f (ℓ=3).

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13
Q

What is the magnetic quantum number (mℓ)?

A

The magnetic quantum number (mℓ) indicates the orbital orientation (-ℓ to +ℓ).

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14
Q

What is the spin quantum number (ms)?

A

The spin quantum number (ms) indicates the electron spin (+½ or -½).

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15
Q

What is the formula for maximum electrons in a subshell?

A

Max electrons = 2(2ℓ + 1).

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16
Q

What is the Aufbau principle?

A

The Aufbau principle states to fill lowest energy levels first.

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17
Q

What is Hund’s rule?

A

Hund’s rule states that electrons fill degenerate orbitals singly before pairing.

18
Q

What is the Pauli exclusion principle?

A

The Pauli exclusion principle states that no two electrons can have the same four quantum numbers.

19
Q

What is the electronic configuration of Sodium (Na, Z=11)?

A

1s² 2s² 2p⁶ 3s¹.

20
Q

What is the electronic configuration of Manganese (Mn, Z=25)?

A

1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d⁵.

21
Q

What are valence electrons?

A

Valence electrons are electrons in the outermost shell that participate in bonding.

22
Q

What is ionic bonding?

A

Ionic bonding is the transfer of electrons from metal to non-metal, forming cations and anions.

23
Q

What are the properties of ionic bonding?

A

Ionic bonding is strong, nondirectional, and has high melting points.

24
Q

What is an example of ionic bonding?

A

Examples include NaCl and MgO.

25
What is covalent bonding?
Covalent bonding involves the sharing of electrons between atoms, usually non-metals.
26
What are the types of covalent bonding?
Types include polar (unequal sharing) and non-polar (equal sharing).
27
What is an example of polar covalent bonding?
An example is HCl.
28
What is an example of non-polar covalent bonding?
Examples include Cl₂ and CH₄.
29
What are multiple bonds in covalent bonding?
Multiple bonds include double bonds (e.g., O₂) and triple bonds (e.g., N₂).
30
What are the properties of covalent bonding?
Covalent bonding is directional, forms hard solids or gases, and has high melting points.
31
What are examples of covalent bonding?
Examples include SiC, CH₄, and H₂O.
32
What is metallic bonding?
Metallic bonding is described by the electron sea model, where delocalized electrons surround ion cores.
33
What are the properties of metallic bonding?
Metallic bonding is conductive, ductile, malleable, and has high melting points.
34
What are examples of metallic bonding?
Examples include Fe, Cu, and Al.
35
What are secondary bonds?
Secondary bonds, also known as Van der Waals bonds, are weaker than primary bonds.
36
What are dipole-dipole interactions?
Dipole-dipole interactions are a type of secondary bonding.
37
What is hydrogen bonding?
Hydrogen bonding is the strongest among secondary bonds, found in H₂O, NH₃, and HF.
38
What are fluctuating dipoles?
Fluctuating dipoles are temporary induced dipoles, such as in liquid H₂.
39
What are the properties of secondary bonds?
Secondary bonds are weaker than primary bonds and influence melting/boiling points and solubility.
40
What are the general material properties by bond type?
Ionic: brittle, hard, high melting point, soluble, conductive in solution; Covalent: high strength, directional, non-conductive; Metallic: conductive, malleable, ductile; Secondary: weak bonding, soft, volatile.
41
What is the key takeaway about atomic structure and bonding?
Understanding atomic structure and bonding helps explain material properties such as strength, conductivity, melting point, and chemical reactivity.