Chapters 4-6 (Exam 2) Flashcards

(87 cards)

1
Q

How is the periodic table ordered?

A

In increasing atomic number values

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2
Q

What is a many electron system?

A

Atoms with more than one electron

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3
Q

What does the Pauli exclusion principle state

A

No two eletrons in an atom in the gorund state can have the same four quantum numbers; If they have the same n, l, and ml values, the ml, or spin, must be differetn./

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4
Q

What is the Aufban princible

A

building the periodic table of elemtnets and determining their electron configurations by steps.

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5
Q

What is Hund’s rule

A

The most stable arrangement of electrons in orbitals of equal energy is the one in which the number of electrons with the same spin is maximized

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6
Q

What are paired electrons called?

A

Diamagnetic

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7
Q

What are unpaired electrons called?

A

Paramagnetic

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8
Q

Diamagnetic substances are ______ by magnetic fields

A

Repelled

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9
Q

Paramagnetic substances are _____ by magnetic fields

A

Attractred

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10
Q

What are the core electrons

A

The electrons that make up the noble gas core

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11
Q

What are the valence electrons

A

The electrons in the outermost occupied shell

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12
Q

What is Nuclear charge (and its symbol)

A

(Z)It is the number of protons in the nucleus of an atom

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13
Q

What is Effective Nuclear Charge

A

(Zeff) the actual magnitude of positive charge that is “experienced” by an electron in the atom.

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14
Q

Effective nuclear charge formula

A

Zeff = Z - o

where o is the shielding constant, greater than zero but smaller than Z.

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15
Q

What is metallic radius

A

Half the distance between the nuclei of two adjaent, identical metal atoms.

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16
Q

What is covalent radius

A

Half the distance between adjacent, identical nuclei that are connected by a chemical bond

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17
Q

What is Ionization energy

A

the minimum energy required to remove an electron from an atom in the gas phase

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18
Q

What is a cation and when does it appear

A

an ion with a net positive charge, it appears when an electron is lost

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19
Q

What is easier to remove, an electron in an s orbital or one in a p orbital

A

The p orbital is easier to remove, and the s orbital is harder to remove

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20
Q

What’s easier to remove, an electron in a singly-occupied orbital, or an electron in a doubly occupied orbital.

A

An electron in a doubly occupied orbital is easier to remove, and an electron in a singly occupied orbital is harder to remove

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21
Q

What is electron affinity

A

Energy released when an atom in the gas phase accepts an electron

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22
Q

How much energy is accepted when a mole of gaseous chlorine atom accepts a mole of electrons

A

349.0 kJ/mol

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23
Q

What is an anion

A

An ion whose net charge is negative due to an increase in the number of electrons

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24
Q

Atomic radius ______ from left to right, and _______ from up to down

A

decreases, increases, largest is bottom left

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25
Whats easier to add, an electron to an s orbital or an electron to a p ortbital
It is easier to add a electron to an s orbital, and harder to add an electron to a p orbital
26
Whats easier to add, an electron to a empty occupied orbital, or an electron to a single occupied orbital
It is easier to add an electron to an empty orbital, and it is harder to add an electron to a singurly occupied orbital.
27
Metals tend to:
- be shiny and malleable and ductile - be good conductors of heat and electricity - Have low ionization energies (commonly form cations)
28
Nonmetals tend to:
- vary in color and lack shininess - Be brittle - Be poor conductors of heat or electricity - Have high electron affinities (commonly form anions)
29
Metallic characteristics _____ from left to right and _______ from top to bottom
decreases, increases
30
Why do some elements share properties with the elements located down and to the right diagonal to them?
The charge of the densities of their cations are comparable, which would mean they have similar properties.
31
What is the formula for Coulomb's law?
F = (Q1 x Q2) / d^2
32
How can you find out the number of anions in a some groups
Most of the anions that form from elements in Groups 14-17 have charges equal to their groups last digit minus 8
33
What is an isoelectronic series
A series of two or more species that have identical electron configurations, but different nuclear charges.
34
In an isoelectronic series, the species with the smallest nuclear change (smallest atomic number, Z) will have the ______ radius
largest
35
In an isoelectronic series, the species with the largest nuclear change (largest atomic number, Z) will have the ______ radius
smallest
36
What are degenerate electrons
Electrons that match each others energy
37
Electron affinity ______ from left to right and _______ from top to bottom
increases, decreases, highest is top right
38
Ionization energy ______ from left to right and _______ from top to bottom
Increases, decreases, highest top right
39
Ionization ____ an electron and Electron affinity ____ an electron
removes, adds
40
which can be separated into similar substances by a physical process?
mixtures, but not compounds
41
What types of elements form an ionic compound?
cations and anions
42
What is a binary compound?
An ionic compound consisting of one metal and one non metal
43
What is the ion of Na.
Na^+ + e^-
44
What is the structure of an ion compouned called and look like
lattice and it is a three dimensional network of alternation cations and anions
45
What does ionization do and what does it look like?
it removes an electron and is represented by a plus sign
46
What does electron affinity do and what does it look like?
it adds an electron and is represented by a minus sign
47
What is Lattice energy
the amount of energy needed to convert a mole of ionic solid to its ions in the gas phase, it is a measure of how stable the ionic compound is.
48
How do you name a cation (positive charge) and what is K and K+
You add ion to the end. One is potassium and the other is a potassium ion
49
With ions with different charges, use _____
Roman numerals
50
How do you name an anion (negative charge)
add "-ide ion" to the end | ex: chloride
51
How do you figure out how much
you take the value of the charge and use it for the amount of the other element
52
correct wording for FeCl2
Iron (II) Chloride
53
What is a covalent bond
when electrons are shared
54
What is a molecule?
A neutral combination of at least two atoms in a specific arrangement held together by bonds
55
What are molecules containing more than two atoms referred to
Polyatomic molecules
56
What is it called when both atoms are the same in a molecule
homonuclear diatomic molecule
57
What is it called when both atoms are different in a molecule
hetero diatomic molecule
58
What is a molecular formula
a formula that shows the exact number of atoms of each element in a molecule.
59
What is an allotrope
one of two ore more distinct forms of an element | - Ex: O2 and O3
60
What a structural formula
A visual representation of the general arrangement of atoms
61
What is the empirical formula
It tells what elements are present in a molecule and in what whole number ratio they are combined - EX: molecular formula is H2O2 but the empirical formula is HO
62
Greek prefixes for numbers | 1, 2, 3, 4, 5, 6, 7, 8, 9, 10
``` Mono - 1 Di - 2 Tri - 3 Tetra - 4 Penta - 5 Hexa - 6 Hepta - 7 Octa - 8 Nona - 9 Deca - 10 ```
63
When naming mixtures, would it be pentoxide or pentaoxide
Pentoxide because the -o and -a are usually omitted from the greek prefixes
64
Hydrogen compounds: What is the name of B2H6
Diborane
65
Hydrogen compounds: What is the name of SiH4
Silane
66
Hydrogen compounds: What is the name of NH3
Ammonia
67
Hydrogen compounds: What is the name of PH3
Phosphine
68
Hydrogen compounds: What is the name of H2O
Water
69
Hydrogen compounds: What is the name of H2S
Hydrogen Sulfide
70
What is an acid
A substance that produces hydrogen ions when dissolved in water
71
What is the formula for naming acids
1. Change hydrogen to hydro- 2. take the second element and take out -ide and add -ic 3. add acid
72
What is an inorganic compound
compounds that do not have carbon
73
What is an organic compound
compounds that have carbon and hydrogen, and sometimes other elements
74
What are the simplest organic compounds that contain only carbon and hydrogen called?
Hydrocarbons
75
What do you do when naming acids and there are 2 elements after the hydrogen
You take out the hydro. | - Ex: H2SO4 is Sulfuric acid
76
If there is a OH in the element what do you name it
Hydroxide at the end
77
What is a hydrate compound
A compound that has a specific number of water molecules in it.
78
How to find the molecular mass, or molecular weight, of a compound
You multiply the quantity of an element with the atomic mass of the elements and add it all up, for compounds its called the formula mass or formula weight
79
How do you find the percent compositon of compounds for each element?
(n x atomic mass of element) / (formula mass of compound) all times 100%
80
What is 1 amu
1.661 x 10^-24 g
81
What is the conversion trick for particles, moles, and mass.
Mass - Moles - Particles Divide when going in, multiply when going out
82
How do you find the empirical formula from the molecular formula
You can divide the molar mass of the formula by the empirical formula of the other and figure out the ratio of elements.
83
What are Polyatomic molecules
molecules containing more than two atoms referred to
84
What is a homonuclear diatomic molecule
What is it called when both atoms are the same in a molecule
85
What is the octet rule?
Atoms will lose, gain, or share electrons to achieve a noble gas electron configuration
86
What are leftover electrons called in Lewis structure
lone pairs
87
The shorter distance the molecules are together, the _____ the bond
stronger