Chem Flashcards

(60 cards)

1
Q

% composition

A

mass in 1 mole / molar mass

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2
Q

4 examples of nucleophiles

A

Hydroxide
Ammonia
Water
Cyanide

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3
Q

Are salts soluble or insoluble

A

Soluble

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4
Q

4 examples of salts

A

nitrates
sulphates
phosphates
chlorides

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5
Q

are bases soluble or insoluble

A

insoluble

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6
Q

3 types of bases

A

carbonates
hydroxides
oxides

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7
Q

what happens to s orbitals as energy levels increase

A

get larger

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8
Q

test for carbonates

A

nitric acid - add until bubbling stops
limewater - goes cloudy

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9
Q

test for sulfates

A

barium nitrate - forms white ppt

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10
Q

test for halides

A

silver nitrate
Cl- white
Br- cream
I- yellow

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11
Q

ammonium test

A

warm with dilute NaOH to produce ammonia
red litmus turns blue

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12
Q

acid test

A

blue litmus turns red

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13
Q

alkali test

A

red litmus turns blue

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14
Q

no. particles

A

moles x avogadros

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15
Q

salt def

A

H+ in an acid is replaces by an ion

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16
Q

Silver ion

A

Ag+

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17
Q

Zinc ion

A

Zn2+

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18
Q

Lead ion

A

Pb2+

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19
Q

what are the two non octet molecules

A

S8 P4

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20
Q

What is Le Chatiliers principal

A

if dynamic equilibrium is disturbed the position of equilibrium shifts to counteract it

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21
Q

cm3 to m3

A

cm / 1 000 000

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22
Q

general formula for dienes

A

CnH2n-2

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23
Q

what does IR radiation do to covalent bonds

A

makes them vibrate more

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24
Q

nucleophile def

A

an electron pair accepter attracted to low electron density

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25
ionisation enthalpy def
the enthalpy required to remove one mole of electrons from one mole of atoms in gaseous form
26
what happens to ionisation energy across the period
increases
27
why does ionisation energy increase across the period (3)
atomic radius decreases nuclear charge increases nuclear attraction increases
28
why does atomic radius decrease across the period (3)
nuclear charge increases electrons fed into same principal shell no increase in shielding
29
what happens to ionisation energy down the group (4)
decreases: atomic radius increases shells increase increased shielding outer electron further away
30
electronegativity def
the ability of an atom to withdraw an electron pair across a covalent bond
31
ionic bonding def
the electrostatic attraction between a positive and negative ion
32
aliphatic
branches or unbranched or non-aromatic rings
33
alicyclic
rings with or without branches but non-aromatic
34
aromatic
benzene rings
35
sigma bond def
an overlap of orbitals directly between bonding atoms
36
Pi bond
the sideways overlap of p orbitals above and below bonded atoms
37
Standard conditions pressure temp conc
100kPa 298K 1 mol dm-3
38
standard enthalpy change of reaction
the energy change associated with a stated equation with all reactants and products in their standard states
39
st enthalpy change combustion
the enthalpy change taken place during the complete combustion of 1 mole of a substance under standard conditions
40
st enthalpy change formation
the enthalpy change when 1 mole of a substance is formed from its elements under standard conditions
41
st enthalpy change neutralisation
the enthalpy change that accompanies the formation of 1 mole of water from neutralisation under standard conditions
42
2 bond pairs name angle
linear 180
43
3 bond pairs name angle
trigonal planar 120
44
2 bond pairs, 1 lone pairs name angle
non-linear 117.5
45
4 bond pairs name angle
tetrahedral 109.5
46
3 bond pairs, 1 lone pairs name angle
pyramidal 107
47
2 bond pairs, 2 lone pairs name angle
non-linear 104.5
48
5 bond pairs name angle
trigonal bipyramidal 90 120
49
6 bond pairs name angle
octahedral 90
50
4 bond pairs, 2 lone pairs name angle
square planar 90
51
what can hydrogen bonds form between
O N F
52
alkane to haloalkane
alkane + halogen UV
53
alkene to alkane
alkene + H2 Ni catalyst 150'
54
alkene to alcohol
alkene + water H3PO4 high temp and pressure
55
haloalkane to alcohol
haloalkane + NaOH/water reflux
56
alcohol to alkene
alcohol conc H2SO4 reflux
57
1alcohol to aldehyde
alcohol + [O] acidified potassium dichromate distil
58
1alcohol to carboxylic acid
alcohol + 2[O] acidified potassium dichromate reflux
59
2 alcohol to ketone
alcohol + [O] acidified potassium dichromate reflux
60
alcohol to ester
alcohol + carboxylic acid/conc H2SO4 reflux