Chem 40 Flashcards
(27 cards)
Carbohydrates
- Hydrates of carbon
- Main function is to provide
energy - most abundant biomolecules on Earth
________ converts more than 100 billion metric tons of CO2 and
H2O into cellulose and other plant products
Photosynthesis
a multistep process that forms carbon
dioxide, water, and a great deal of energy
oxidation of glucose
Functions of Carbohydrates
- Storehouse of chemical energy.
- Supportive structural components of plants and some animals.
- Essential components of the genetic material
- Ligands and receptors in cellular communication
Classes of Carbohydrates
- monosaccharides
- oligosacchraides
- Polysaccharides
Monosaccharides
simple sugars, consist of a single polyhydroxy aldehyde or ketone unit. The most abundant monosaccharide in nature is the six-carbon sugar D-glucose
Oligosaccharides
- consist of short chains of monosaccharide units joined by characteristic linkages called glycosidic bonds
- Disaccharides
Polysaccharides
- sugar polymers containing more than 20 or so monosaccharide units, and some have hundreds or thousands of units
- Example: Cellulose
have three to seven carbon atoms in a chain, with a carbonyl group at either the terminal carbon (C1) or the carbon adjacent to it (C2).
monosaccharides
Monosaccharides are usually drawn _______ , with the carbonyl group at
the _____
vertically; top
polar compounds with high melting points
monosaccharides
What makes monosaccharides water soluble?
presence of so many polar functional groups capable of hydrogen
bonding
Two families of monosaccharides
aldoses
ketoses
[aldose or ketose] If the carbonyl group is at an end of the carbon chain of the monosaccharide
aldose
[aldose or ketose] if the carbonyl group is at any other position of the
monosaccharide
ketose
simplest aldehyde
glyceraldehyde
simplest ketone
dihydroxyacetone
monosaccharide with 3Cs, 4C’s, 5Cs, 6Cs
triose (3)
tetrose (4)
pentose (5)
hexose (6)
[Stereoisomerism] Aldoses & ketoses
(except dihydroxyacetone) are
OPTICALLY ACTIVE
[T or F] d and l refers to the direction in which plane polarized light is rotated
True
[clockwise or counterclockwise] - D
clockwise
[clockwise or counterclockwise] - L
counterclockwise
Stereoisomers
isomers that differ in spatial arrangement of atoms, rather
than order of atomic connectivity
Anomeric carbon
carbonyl carbon (C=O)