Chemical Analysis - Flashcards

1
Q

Pure substance

A

A pure substance only contains one type of element or compound throughout

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Pure / Impure
Sea Water

A

Impure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Pure / Impure
Ethanol

A

Pure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Pure / Impure
Graphite

A

Pure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Pure / Impure
Fresh mountain air

A

Impure

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Impurities result on boiling point of a compound?

A

Boiling point increases
Boil at a range of temperatures

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Same ingredients but different formulations? Explain..

A

Formulations contain specific quantities of their components. The medicines have the same ingredients, but if they’re mixed in different ratios, the formulations aren’t the same

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Everyday products that are formulations?

A

Paint, Cleaning products, fuels, medicines, cosmetics, fertilisers, alloys

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Formula for Rf value of a spot on a chromatography paper?

A

Rf = Distance travelled by substance / Distance travelled by solvent

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Insoluble component to mixture, used in chromotography?

A

Will stay on the baseline

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Pure substance melting point

A

Sharp, occurs quickly

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Mixture melting point

A

Occurs over a range of temperatures

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Chromatography:
What to draw baseline in?

A

Pencil

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Impurities effect on melting point?

A

Lower the melting point

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Examples of pure substances?

A

Water, Copper sulphate, Glucose, Oxygen Gas, Sodium Chloride

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

How to make sure that a formulation has the correct properties?

A

Chemical components must be present in exact quantities

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

mixtures of chemical components that are designed to create useful products

A

Formulations

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

2 phases in chromotography

A

Mobile phase
Stationary phase

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

What is the mobile phase?

A

Liquid or Gas that carries the the substance up the paper

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

What is the stationary phase?

A

Solid or Viscous Liquid that the mobile phase moves through

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

Why does a substance move further in chromotography?

A

It is more attracted to the mobile phase

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

Why doesn’t a substance move far in chromotography?

A

It is more attracted to the stationary phase

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

Describe solvent movement in chromotography?

A

Solvent travels up chromatography paper.
As solvent moves, picks up and transports the substances being tested in the chromatography paper.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

Higher distance travelled in chromotography?

A

Highly soluble in solvent as they are highly attracted to the mobile phase.
Minimally attracted to chromatography paper and stationary phase

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
25
Q

Reference substance

A

pure substance that is run next to tested substance to see if it’s a component in mixture

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
26
Q

What does chromatography produce which can be analysed?

A

Chromatogram

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
27
Q

Test for hydrogen?

A

Lighted splint placed at mouth of test tube with gas
Positive: Squeaky pop

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
28
Q

Why is there is squeaky pop in hydrogen test?

A

Hydrogen burns rapidly in presence of oxygen to produce H2O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
29
Q

Test for oxygen?

A

Glowing splint held at mouth of test tube with gas
Splint will relight

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
30
Q

What is limewater?

A

Calcium Hydroxide

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
31
Q

Carbon dioxide test:
What type of Calcium Hydroxide (lime water) is needed?

A

Aqueous solution

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
32
Q

What is the text for carbon dioxide?

A

Bubble lime water through gas.
If Carbon present lime water turns from clear to cloudy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
33
Q

What type of litmus paper is used to test for Chlorine?

A

Damp blue litmus paper

34
Q

What is the test for Chlorine?

A

Insert damp blue litmus paper into test tube with gas.
If chlorine present the paper is turned from red to bleached white.

35
Q

Flame tests - Potassium (K+)

A

Lilac Flame

36
Q

Flame tests - Lilac

A

Potassium (K+)

37
Q

Flame tests - Sodium (Na+)

A

Yellow flame

38
Q

Flame tests - Yellow

A

Sodium (Na+)

39
Q

Flame tests - Calcium (Ca2+)

A

Orange-red flame

40
Q

Flame tests - Orange-red

A

Calcium (Ca2+)

41
Q

Flame Tests - Copper (Cu2+)

A

Green flame

42
Q

Flame tests - Green

A

Copper (Cu2+)

43
Q

Flame Tests - Lithium (Li+)

A

Crimson flame

44
Q

Flame tests - Crimson

A

Lithium (Li+)

45
Q

Name of wire loop used in flame tests?

A

Nichrome

46
Q

How to clean the nichrome wire loop?

A

Dip in dilute hydrochloric acid

47
Q

Which type of flame to use in ion flame test?

A

Blue

48
Q

Hydroxide precipitate test - Aluminium (Al3+)

A

White (dissolves in excess sodium hydroxide solution)

49
Q

Hydroxide precipitate test - White (dissolves in excess sodium hydroxide solution)

A

Aluminium (Al3+)

50
Q

Colour once white precipitate (Aluminium Hydroxide) dissolves in Sodium Hydroxide solution

A

Colourless

51
Q

Sodium Hydroxide formula

A

NaOH

52
Q

Hydroxide precipitate test - Calcium (Ca2+)

A

White

53
Q

Hydroxide precipitate test - white (2)

A

Calcium (Ca2+)
Magnesium (Mg2+)

54
Q

Hydroxide precipitate test - Magnesium (Mg2+)

A

White

55
Q

Hydroxide precipitate test - Copper (Cu2+)

A

Blue

56
Q

Hydroxide precipitate test - Blue

A

Copper (Cu2+)

57
Q

Hydroxide precipitate test - Iron (II) (Fe2+)

A

Green

58
Q

Hydroxide precipitate test - Green

A

Iron (II)
(Fe2+)

59
Q

Hydroxide precipitate test - Brown

A

Iron (III)
(Fe3+)

60
Q

Hydroxide precipitate test - Iron (III) (Fe3+)

A

Brown

61
Q

Hydroxide precipitate test - 3 white precipitates

A

Calcium Hydroxide
Aluminium Hydroxide
Magnesium Hydroxide

62
Q

Test for Carbonate ions

A

Add dilute hydrochloric acid. If bubbles produced its positive.

63
Q

Carbonate ions

A

CO3^-2

64
Q

Test for Halide Ions:

A

Add dilute nitric acid
Add a few drops of silver nitrate solution

65
Q

Halide Ion test - Chloride (Cl-)

A

White

66
Q

Hailde Ion test - White

A

Chloride (Cl-)

67
Q

Halide Ion test - Bromide (Br-)

A

Cream

68
Q

Halide Ion test - Cream

A

Bromide (Br-)

69
Q

Halide Ion test - Yellow

A

Iodine (I-)

70
Q

Halide Ion test - Iodine (I-)

A

Yellow

71
Q

Why add nitric acid in halide test?

A

Removes any carbonate ions

72
Q

Test for sulphates:

A

Add dilute hydrochloric acid
Add barium Chloride
Becomes barium Sulphate
White precipitate forms (positive)

73
Q

Why add Hydrochloric acid in test for sulphates?

A

Remove carbonate ions

74
Q

Dilute Acid + Carbonate –>

A

Salt + Carbon Dioxide + Water

75
Q

Test for sulphate:
Properties of Barium Sulphate formed?

A

Insoluble
White

76
Q

Sulphates ions?

A

SO4^-2

77
Q

Disadvantages of Instrumental methods?

A
  • Need training
  • Expensive
  • Results only useful when compared to data of known substances
78
Q

Advantages of Instrumental methods?

A
  • Greater sensitivity
  • Greater accuracy
  • Able to analyse tiny samples
  • Quicker at analysing results
79
Q

Steps of Flame Emission Spectroscopy?

A
  • Place sample of metal solution being tested into flame, light will be given off
  • Light given off is captured by spectroscope and read as wavelengths
80
Q

What does Flame Emission Spectroscopy identify?

A

Metal Ions

81
Q

Spectroscopy:
Concentration of Ion?

A

Intensity of line spectra

82
Q

Reference spectra in Spectroscopy?

A

Allows to compare the ions in mixtures