Chemical Bonding Flashcards

1
Q

what is the Noble Gas Structure

A

2 (duplet configuration) / 8 (octet configuration) valence electrons: stable electronic configuration; lack of reactivity

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2
Q

what is the octet rule

A

tendency for atoms to lose/gain/share electrons until there are 8 valence electrons

*exception to this rule applies to atoms with only 1 electron shell, requiring only 2 valence electrons for stability

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3
Q

what is an ion

A

atom or group of atoms that have electrical charges

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4
Q

what are cations and anions

A

cation: positively charged ion (lose electrons)
anion: negatively charged ion (gain electrons)

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5
Q

how are cations formed

A

atoms of metals tend to form cations by losing their valence electron(s) to attain the noble gas configuration

positive charge arises as there are now more protons than electrons

*most metals have 1-3, easier to lose 1-3 than to gain 5-7

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6
Q

how are anions formed

A

atoms of non-metals tend to form anions by gaining valence electron(s) to attain the noble gas configuration

positive charge arises as there are now more electrons than protons

*most metals have 4-7, easier to gain 1-3 than to gain 5-7

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7
Q

3 points

what is the relationship between group number and ionic charge

A

ionic charge of an ion is dependent on number of valence electrons its atom contains

elements in the same group have the same number of valence electrons

hence, they form ions of the same charges and have similar chemical properties

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8
Q

why do elements in groups 1-2, 13 form cations

A

they are metals

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9
Q

why do elements in group 18 not form ions

A

they tend to be monatomic as their atoms have stable electronic structure and do not usually form compounds

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10
Q

why do elements in groups 15-17 form anions

A

they are non-metals

*can also form covalent bonds

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11
Q

what is ionic bonding

A

ionic bond defined as the strong electrostatic forces of attraction between the positively charged ion (metals, cations) and negatively charged ion (non-metals, anions)

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12
Q

3 points

how are ionic compounds formed

A

generally occurs between atoms of metals and atoms of non-metals

involves gain/loss of electrons (transfer of electrons) to achieve stability

forms oppositely charged ions

*include legend for dot-and-cross diagrams

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13
Q

what is covalent bonding

A

covalent bond defined as the electrostatic forces of attraction between the shared electrons and the 2 positively charged nuclei of the atoms

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14
Q

3 points

how are covalent bonds formed

A

generally occurs between atoms of non-metals

involves sharing of electrons to achieve noble gas electronic configuration

forms molecules

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15
Q

what is the structural full formula of H₂O

A

H - O - H

single bond

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16
Q

what is the full structural formula of O₂

A

O = O

double bond

17
Q

what is the full structural formula of N₂

A

N ≡ N

triple bond

18
Q

2 points

why do ionic compounds have high melting and boiling points

A

they have a giant ionic crystal lattice structure

a lot of energy is needed to overcome the strong electrostatic forces of attraction between the oppositely charged ions

19
Q

2 points each

why do ionic compounds not conduct electricity in the solid state but are good conductors in the molten and aqueous states

A

in the solid state, the ions are held in their fixed positions by strong electrostatic forces of attraction
the ions are not mobile to conduct electricity

in the molten/aqueous state, the electrostatic forces of attraction are overcome
the ions are mobile to conduct electricity

20
Q

2 points

why do simple covalent/molecular substances have low melting and boiling points

A

they have a simple molecular structure

little energy is needed to overcome the weak intermolecular forces of attraction between the molecules

21
Q

1 point

why do covalent substances generally not conduct electricity at any state

A

they have no mobile charge carriers (ions/electrons) to conduct electricity