Chemical Bonding Flashcards
(21 cards)
Atoms are being held by electrical attraction between species of opposite charge.
Atoms form bonds to completely fill their valence shells.
Dualism (Berzelius)
There are two ways by which
an atom bonds with another atom
- by gaining or losing electrons forming ionic bond
- sharing of electrons with another atom forming covalent bond
- by gaining or losing electrons
forming ionic bond
- sharing of electrons with another atom
forming covalent bond
Atoms with high ionization energy tend to _________ easily while atoms with low
electron affinity tend to ________ easily.
lose electrons , gain electrons
Atoms forming ________ share electrons to acquire the configuration of the
noble gases (octet rule).
Covalent bond
Hydrogen acquires the electron configuration of the noble gas ___________
helium
Formal Charge equation
group number - (1/2 shared e-) - number of unshared e
What is the 1st step in writing Lewis Structures
Determine the total number of valence electrons of all atoms (also equal to their
group number) = n
number of electrons located at the outermost shell of an atom
valence electron
What is the 2nd step in writing Lewis Structures
Determine the total number of electrons for each atom that will satisfy the octet
rule = m
What is the 3rd step in writing Lewis Structures
The number of bonding electrons is m-n
What is the 4th step in writing Lewis Structures
The number of electron - pair bonds is ½ (m-n)
What is the 5th step in writing Lewis Structures
Assign the correct formal charge for each atom
A molecule or an ion represented in two or more Lewis structures that differ only in the positions of electrons exhibit the property of resonance.
Resonance Theory
A molecule or an ion represented in two or more Lewis structures that differ only in the positions of electrons exhibit the property of resonance. These structures are called
resonating structures or resonating contributors
if an electron moves unexpectedly inside the matter without compromising the stability
Resonance
two types of covalent bond
sigma and pi bonds
the spaces where the probability of finding electron is highest (as it moves unexpectedly)
atomic orbitals
when atomic orbitals overlap side by side
pi bonds
when atomic orbitals overlap head by head
sigma bonds