Classification Flashcards

(67 cards)

1
Q

2 classification of organic compounds

A
  1. Hydrocarbon
  2. Hydrocarbon derivatives
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2
Q

type of organic compound which is based to heteroatoms present

A

Hydrocarbon derivatives

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3
Q

type of organic compound which composed of carbon and hydrogen only

A

Hydrocarbon

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4
Q

3 types of hydrocarbon

A
  • aliphatic
  • alicyclic
  • aromatic
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5
Q

compounds whose carbon atoms are arranged in chains whether straight or branched

A

Aliphatic

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6
Q

contain single bonds

A

Alkanes (C_nH_2n+2)

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7
Q

contain double bonds

A

AIkenes (C_nH_2n)

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8
Q

contain triple bonds

A

AIkynes (C_nH_2n-2)

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9
Q

contain two double bonds

A

Alkadienes (C_nH_2n-2)

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10
Q

compounds containing carbon atoms in a ring system

A

Alicyclic

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11
Q

alkanes arranged in the form of a closed chain

A

Cycloalkanes (C_nH_2n)

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12
Q

non-conjugated alkenes in a ring system

A

Cycloalkenes (C_nH_2n-2)

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13
Q

compounds containing carbon atoms with conjugated double bonds in a ring system

A

Aromatic

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14
Q

4 types of hydrocarbon derivatives organic compound

A
  • derivatives containing oxygen
  • derivatives containing halogen
  • derivatives containing sulfur
  • derivatives containing nitrogen
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15
Q

7 types of hydrocarbon derivatives

A
  • alcohol and phenols
  • acid anhydride
  • aldehydes and ketones
  • epoxide
  • esters
  • ethers
  • carboxylic acids
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16
Q

hydrocarbons with one or more hydrogen atom replaced by -OH group

A

Alcohols (R-OH) and Phenols (Ar-OH)

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17
Q

attached to oxygen
hydrocarbon derivatives with two hydrocarbon groups

A

ethers (ROR)

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18
Q

cyclic ethers in which the oxygen is included in a three-membered
ring

A

epoxide

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19
Q

hydrocarbons with one or two
alkyl groups attached to C=O

A

Aldehydes (RCHO) and Ketones (RCOR)

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20
Q

an alkane missing one hydrogen

A

alkyl

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21
Q

hydrocarbons with the carboxyl group, COOH

A

Carboxylic Acids (RCOOH)

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22
Q

organic, functional group consisting of a carbon atom that’s double-bonded to an oxygen atom and singly bonded to a hydroxyl group.

A

carboxyl (COOH)

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23
Q

carboxylic acid derivatives with the hydrogen atom
replaced by an alkyl group

A

Esters (RCOOR)

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24
Q

carboxylic acid derivatives with the hydrogen atom
replaced by RC=0

A

Acid Anhydride

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25
hydrocarbons with the hydrogen atom replaced by one or more halogens
Alkyl Halides and Aryl Halides
26
2 Derivatives containing Sulfur
thiols and disulfides
27
hydrocarbon derivatives with hydrogen atom replaced with -SH
thiols
28
hydrocarbon derivatives with general formula R-S-S-R
disulfides
29
2 Derivatives containing nitrogen
amides and amine
30
carboxylic acid derivatives with hydrogen atom replaced with - NH_2, -NHR', -NR'R"
amides
31
organic derivative of NH_3
amine
32
also called paraffins
alkanes
33
contains sp^3 hybridized carbon
alkanes
34
source of alkanes
fractional distillation of petroleum
35
physical state of C_1 to C_4 at room temperature
gases
36
physical state of C_5 to C_17 at room temperature
liquids
37
physical state of C_18 to C_n at room temperature
solids
38
alkanes are insoluble in ________ due to non-polar character and inability to form _________ bond
water, hydrogen
39
alkanes are soluble in (3)
benzene, chloroform, and carbon tetrachloride
40
boiling point of alkanes increase as the length of carbon ______________ and ___________ due to branching
increases, decreases
41
In naming, choose the _________ and the parent name is named according to the number of carbon present.
longest continuous carbon chain (CH_3)
42
In naming, Number the chain in such a way that the substituents present are assigned with the ____________
lowest number
43
In naming, for identical substituents present more than once, the carbon numbers for which the substituents are attached and the prefixes di, tri, tetra, etc. are written before the ____________
name of the substituents.
44
In naming for _____________, the number is used twice and the prefix di is attached before the name of the substituent
two identical substituents (3,3 dimethylpentane)
45
In naming, for __________ different alkyl substituents, names are written in alphabetical order giving no consideration on the prefixes.
two or more
46
In alkyl substituent, 1 CH3 is
methyl
47
In alkyl substituent, 2 CH3 is
ethyl
48
In alkyl substituent, 4 CH3 is
butyl
49
In alkyl substituent, 3 CH3 is
propyl
50
In alkyl substituent, 5 CH3 is
pentyl
51
preparation of alkanes
1. Grignard Synthesis using Alkyl Halide 2. Hydrogenation of Alkene 3. Reduction of Alkyl Halide 4. Wurtz Synthesis (coupling reaction)
52
reactions of alkanes
1. halogenations 2. combustion
53
also called olefins
alkenes
54
contains sp^2 hybridized carbon
alkenes
55
In dehydrogenation of alkyl halides, the alkene formed is the one that is more alkyl substituted
saitsev's rule
56
preparation of alkenes
1. dehydration of alcohol 2. dehydrogenation of alkyl halides 3. debromination of dibromides
57
reaction of alkenes
1. hydrogenation 2. halogenation 3. addition of HX 4. hydroxylation 5. ozonolysis 6. oxidation 7. acid-catalyzed hydration 8. oxymercuration-demercuration 9. hydroboration-oxidation 10. halohydrin formation
58
In the addition of HX in alkenes reaction, the halogen attaches to the carbon that is more alkyl substituted thus producing a higher order alkyl halide
markovnikoff's rule
59
anti-markovnikoff's addition of _____ in the presence of organic peroxides
HBr
60
in halohydrin formation, the _______ attached to carbon with more alkyl substituent
water
61
also called as acetylenes
alkynes
62
contains sp hybridized carbon
alkynes
63
preparation of alkynes
1. reaction of sodium acetylide with alkyl halides 2. dehydrohalogenation of vicinal dihalides 3. dehalogenation of tetrahalides
64
reaction of alkynes
1. hydrogenation 2. halogenation 3. addition of HX 4. hydration 5. oxidation
65
Alcohols are named as
alkanol
66
contain the functional group -OR
ethers
67
in naming ethers,
alphabetic order + ether